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This paper presents a new method of dielectric capacitance cell as a proposed device for measuring the impedance of pure sand artificially contaminated with four heavy metals. Dielectric constant and loss factor of clean and contaminated sand at various levels were calculated from the measured sand impedances. The advantages and benefits of using the proposed dielectric capacitance cell were its low cost, simple calculation, calibration procedures, portable and lightweight, and easy to modify the electrodes to suit testing in the field. Pure sand was saturated with water artificially polluted in the lab with Pb, Cd, Fe, and Zn at heavy metal contents 0, 7.5, 15, 22.5, and 30 mg/kg of sand. The dielectric properties of polluted sand were evaluated at a frequency range from 100 kHz to 1000 kHz. The polluted sand exhibit different dielectric constants and loss factors from the unpolluted sand. The results also indicate that the dielectric constant decreases with increasing pollution level for all heavy metals. This may attribute to the polarization mechanism change with existing heavy metal. The loss factor of sand increases with the increasing pollution level. This may be explained by the increase of ionic conductivity of pore water with heavy metal in the sand. Sand polluted with heavy metal with higher resistivity and density possess a higher dielectric constant and lower loss factor than other polluted metals. Evaluation of the dielectric characteristics of polluted sand could have the potential to monitor heavy metal pollution. Even with promising results obtained with the proposed dielectric device, it is necessary to explore several other factors affecting the measurements such as sand water content, soil texture, and type of soil. Also, testing polluted soil near industrial pollution is needed.

In this study, a method for determining the setting time and the porosity of fly ash-based geopolymer binders (FAGPBs) has been established. This method permits a real-time monitoring of the geopolymerisation and hardening progressions. A parallel plate capacitor cell technique was used to determine the dielectric constant e r ' and dielectric loss factor e r ' ' of fresh and hardened mixes. Equivalent model-circuits of the measurement system were developed, and the accuracy of the system was verified. The dielectric properties were monitored at different ages until 56 days over a frequency range of 0.1–60 MHz. The alkaline solution to fly ash ratio, sodium silicate to alkaline solution ratio, and sodium hydroxide solution molarity were varied to study their effects on the dielectric properties. It was found that dielectric properties can provide valuable information when measured in the frequency range of 10–25 MHz. In this range, the dielectric values responded well to the variations with age and with mix properties. The relationships between the dielectric properties and the different physical states and constituent materials of FAGPBs could be used for quality control applications. The e r ' and e r ' ' time plots were effectively utilized to determine the setting time and the rate of geopolymerisation of FAGPBs. Measurements showed a strong correlation between e r ' and porosity; the e r ' values decreased 2.3-fold over a porosity range of 3–15%. The proposed regression models can be further used in determining the porosity of FAGPBs at a high accuracy level.

In this study, different types of plasticizers were used to investigate their effects on the fresh and hardened properties of high calcium fly ash geopolymers (HCFA). Modified polycarboxylate polymers (G3) and lignin-based polymers (G1) were used as plasticizing admixtures and the results were compared to the effect of tap water addition. The results showed that all the admixtures used are effective in increasing the workability of the HCFA geopolymers mixtures and the workability increased by 25-48% compared to the control mixtures. However, the use of G3 has adversely affected the strength by a reduction of 20%. While the use of G1 reduced the final setting time by 7% which is critical in the case of HCFA geopolymers where the final setting time occurs within 70 minutes. Water can be considered as the best admixture in terms of cost, setting time, and effect on compressive strength and it can be used where medium workability enhancement is required.

In this paper, the near- and far-field microwave methods used in this study indicate that the microwave reflections and dielectric properties are useful parameters for the detection of chloride in concrete material. Furthermore, the amount of chloride present in concrete at the time of mixing can also be determined. The reflection coefficients, dielectric constant and loss factor in the X-band microwave frequencies increase with increasing chloride content in concrete materials and can be used to monitor the hydration process. A linear relationship between the microwave properties of concrete and chloride content were established.

Geopolymers are novel binding materials produced by the alkaline activation of rich aluminosilicate materials. Geopolymer binders are considered as green building materials that have increasing potential to replace the ordinary Portland cement in the concrete industry. This study investigated the alkali solution effects on the physical and mechanical properties of the high calcium fly ash based geopolymers. The parameters involved in this study were the NaOH solution molarity and the Na 2 SiO 3 /NaOH ratio. Three NaOH concentrations (8, 10, and 12 molars) were investigated. The Na 2 SiO 3 /NaOH ratio was varied between 1 and 2.5. The results showed that the studied parameters significantly affected the properties of the produced geopolymer mortars. The workability and setting time were found to decrease by increasing the NaOH concentration or by increasing the Na 2 SiO 3 /NaOH ratio. The influence of the NaOH concentration was higher on the workability and setting time while the Na 2 SiO 3 /NaOH ratio highly affected the compressive strength. The initial setting time was in the range of 45-105 minutes while the final setting occurred quickly after that within 70-115 minutes. Oven curing method resulted in high strength at early ages where all of the mixes were able to achieve more than 75% of the 28 days strength within the first 3 days. The 28-days compressive strength ranged between 60-85 MPa, which promotes the use of the high calcium fly ash for the production of early high strength geopolymer concrete.

Eight large-scale reinforced self-compacted engineered cementitious composite (R-SC-ECC) beams with different steel reinforcement ratios have been designed, prepared, cast, cured, and tested to failure at the age of 28 days. The experimental results have been compared with theoretical values predicted using EC2, RILEM, and VecTor2 models. Results show that failure modes in flexure and shear of R-SC-ECC beams are comparable to that of normal reinforced concrete beam. Nevertheless, contrary to VecTor2, models of EC2 and RILEM are not suitable for predicting reasonable ultimate moments for the beams, while results using VecTor2 model have successfully predicted the failure modes and load-deflection curves for all R-SC-ECC beams. It has been concluded that R-SC-ECC fall in the category of ductility class medium to high which gives advantages of using R-SC-ECC beams in regions susceptible to seismic activities.

Geopolymer binders offer a possible solution for several problems that facing the current cement industry. These binders exhibit similar or better engineering properties compared to cement and can utilize several types of waste materials. This paper presents the recent research progress regarding the structural behaviour of reinforced geopolymer concrete members including beams, columns and slabs. The reported results showed that the structural behaviour of the reinforced geopolymer concrete members is similar to the known behaviour of the ordinary reinforced concrete members. In addition, the currently available standards have been conservatively used for analysis and designing of reinforced geopolymer concrete structures. On the other hand, the main hurdles facing the spread of geopolymer concrete was the absence of standards and the concerns about the long-term properties. Other issues included the safety, cost and liability.

This study aimed to present the current state of research about the terminology, chemical reactions, mechanisms, and microstructure modelling of geopolymer binders. Modelling the structure of the geopolymerization products is essential for controlling the product properties. The currently available models have shown some limitations in determining the rate of geopolymerization and setting time of the gel. There is a need for deeper knowledge regarding the physicochemical analysis of geopolymer binders. Most of the available models have used pure material like metakaolin; however, the less pure materials are expected to have different mechanisms. The FTIR and MAS-NMR analysis are considered as effective tools in providing information on the molecular deviations during geopolymerization. However, XRD analysis is not effective because most of the changes take place in amorphous phases. Also, the role of the iron oxides and some of the other impurities still not clear where none of the previous method of investigation can be used to detect the molecular changes of the iron compounds. This issue is very relevant hence the iron oxides are existed in substantial amounts in most of the waste materials that are suitable to be used as geopolymer source materials.