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Constraining the past sea ice variability in the Nordic Seas is critical for a comprehensive understanding of the abrupt DansgaardOeschger (D-O) climate changes during the last glacial. Here we present unprecedentedly detailed sea ice proxy evidence from two Norwegian Sea sediment cores and an East Greenland ice core to resolve and constrain sea ice variations during four D-O events between 32 and 41 ka. Our independent sea ice records consistently reveal a millennial-scale variability and threshold response between an extensive seasonal sea ice cover in the Nordic Seas during cold stadials and reduced seasonal sea ice conditions during warmer interstadials. They document substantial and rapid sea ice reductions that may have happened within 250 y or less, concomitant with reinvigoration of deep convection in the Nordic Seas and the abrupt warming transitions in Greenland. Our empirical evidence thus underpins the cardinal role of rapid sea ice decline and related feedbacks to trigger abrupt and large-amplitude climate change of the glacial D-O events.

17 pags., 4 figs., 2 tabs., Sea ice plays a pivotal role in Earth's climate and its past reconstruction is crucial to investigate the connections and feedbacks with the other components of the climate system. Among the available archives that store information of past sea ice are marine and ice cores. Recent studies on the IP biomarker extracted from marine sediments has shown great skill to infer past changes of Arctic sea ice. In ice matrixes, sodium, bromine and iodine have shown potential to store the fingerprint of sea ice presence. The development of an unambiguous sea ice proxy from ice cores, however, has proven to be a challenging task especially in the Arctic realm. In this work we analyze the sodium, bromine and iodine records in the RECAP ice core, coastal eastern Greenland, to investigate the sea ice variability in the northern North Atlantic Ocean through the last 11,000 years of the current interglacial, i.e. the Holocene. We compare the RECAP records with marine sea ice proxy records available from the northern North Atlantic. We suggest that RECAP sodium concentrations can be associated with variability of sea ice extent, while the bromine-to-sodium ratios and iodine are associated respectively with seasonal sea ice and bioproductivity from open ocean and fresh sea ice surfaces. According to our interpretation, we find that sea ice was at its lowest extent and seasonal in nature during the early Holocene in all regions of the North Atlantic. Increasing sea ice signals are seen from ca. 8–9 ka b2k, in line with long-term Holocene cooling. The increasing sea ice trend appears uninterrupted in the Fram Strait and North Iceland while reaching a maximum ca. 5 ka b2k in the East Greenland region. Sea ice modifications during the last 5000 years display great variability in East Greenland with intermediate conditions between the early and mid Holocene, possibly associated with local fjord dynamics. The last sea ice maximum was reached across all regions 1000 years b2k., The RECAP ice coring effort was financed by the Danish Research Council through a Sapere Aude grant, the NSF through the Division of Polar Programs, the Alfred Wegener Institute, and the European Research Council under the European Community's Seventh Framework Programme (FP7/2007e2013)/ERC grant agreement The RECAP ice coring effort was financed by the Danish Research Council through a Sapere Aude grant, the NSF through the Division of Polar Programs, the Alfred Wegener Institute, and the European Research Council under the European Community's Seventh Framework Programme (FP7/2007e2013)/ERC grant agreement 610055 through the Ice2Ice project. Additional funding support for the paper has been provided by the Centre for Climate Dynamics at the Bjerknes Centre. through the Ice2Ice project. Additional funding support for the paper has been provided by the Centre for Climate Dynamics at the Bjerknes Centre.

Biomass burning influences global atmospheric chemistry by releasing greenhouse gases and climate-forcing aerosols. There is controversy about the magnitude and timing of Holocene changes in biomass burning emissions from millennial to centennial time scales and, in particular, on the possible impact of ancient civilizations. Here we present a 5 kyr record of fire activity proxies levoglucosan, black carbon and ammonium measured in the RECAP ice core, drilled in the coastal East Greenland and therefore affected by processes occurring in the High North Atlantic Region. Levoglucosan and ammonium fluxes show high levels from 5 to 4.5 kyr followed by an abrupt decline, possibly due to monotonic decline in Northern Hemisphere summer insolation. Levoglucosan and black carbon show an abrupt decline at 1.1 kyr BP (before 2000 AD), suggesting a decline in wildfire regime in the Icelandic territory due to the extensive land clearing caused by Viking colonizers. A minimum is reached at 0.5 kyr BP for all fire proxies, after which levoglucosan and ammonium fluxes increase again, in particular over the last 200 years. We find that the fire regime reconstructed from RECAP fluxes seems mainly related to climatic changes, however over the last millennium human activities might have had a substantial influence controlling the occurrence of fire.

41 pags., 25 figs., 5 tabs. 1 app., As the intricacies of paleoclimate dynamics are explored, it is becoming understood that sea-ice variability can instigate, or contribute to, climate change instabilities commonly described as “tipping points”. Compared to ice sheets and circulating ocean currents, sea-ice is ephemeral and continental-scale changes to sea ice cover occur seasonally. Sea-ice greatly influences polar albedo, atmosphere-ocean gas exchange and vertical mixing of polar ocean masses. Major changes in sea ice distribution and thickness have been invoked as drivers of deglaciations as well as stadial climate variability described in Greenland climate records as “Dansgaard-Oeschger” cycles and described in Antarctic climate records as “Antarctic Isotopic Maxima”., The role of halogens in polar atmospheric chemistry has been studied intensively over the past few decades. This research has been driven by the role of bromine, primarily as gas-phase bromine monoxide (BrO), which exerts a key control on polar tropospheric ozone concentrations. Initial findings led to the discovery of boundary-layer self-catalyzing heterogeneous bromine reactions fed by sunlight and ozone, known as bromine explosions. First-year sea-ice and blowing snow have been identified as key components for this heterogeneous bromine recycling in the polar boundary layer. This understanding of polar halogen chemistry – supported by an expanding body of observations and modeling – has formed the basis for investigating quantitative links between halogen concentrations in the polar atmospheric boundary layer and sea-ice presence and/or extent. Despite the clear importance of sea-ice in paleoclimate research, the ice core community lacks a conservative and quantitative proxy for sea-ice extent. The most commonly applied proxy, methanesulphonic acid (MSA), is volatile and has not been demonstrated reliably for ice core records extending beyond the last few centuries. Sodium has also been applied to reconstruct sea-ice extent in a semi-quantitative manner although the effects of meteorological transport noise are significant. Contrary to a priori expectations, the halogens bromine and iodine appear to be stable in polar snow and ice over millennial timescales, addressing the temporal limitations of MSA records. Unfortunately, transport and meteorological variability influence sodium deposition as well as the deposition of halogens and the many other ionic impurities found in ice cores. The atmospheric chemistry of halogens is more complex than those of sodium or MSA due to the mixed-phase (gas and aerosol) nature of halogen photochemistry. Thus the application of halogen records in ice cores to sea-ice reconstruction overcomes some challenges posed by existing proxies, but also opens new challenges specific to halogens. Challenges common to all sea-ice proxies include the deconvolution of changes in emission source locations and changes in transport efficacy, particularly those occurring during climate transitions combining changes in sea-ice and atmospheric circulation, such as stadial/interstadial or glacial/interglacial climate variability., In this review, we describe the rationale and available evidence for linking the halogens bromine and iodine found in polar snow and ice to sea-ice extent. Reported measurements of bromine and iodine in polar snow and ice samples are critically discussed. We also consider aspects of halogen transport and retention in polar snow and ice that are still poorly understood. Overall, there is a growing body of evidence supporting the application of bromine to sea-ice reconstructions, and the use of iodine to reconstruct marine biological activity mediated in part by sea-ice extent. These halogens complement existing sea-ice proxies but most crucially, offer the capacity to greatly extend the temporal and spatial coverage of ice core-based sea-ice reconstructions. We identify knowledge gaps existing in the current understanding of spatial and temporal variability of halogen distributions in the polar regions. We suggest areas where polar halogen chemistry can contribute to a better understanding of the halogen records recovered from ice cores. Finally, we propose future steps for establishing reliable and constructive sea-ice reconstructions based on bromine and iodine as observed in snow and ice cores., This research has received funding from the European Research Council under the European Community's Seventh Framework Programme (FP7/2007–2013)/ERC grant agreement 610055 as part of the ice2ice project. We would like to acknowledge the essential contribution of the Inuit Windsled Project, consisting of Ross Edwards, Hermenegildo Moreno, Jens Jacob Simonsen and Ramon Larramendi, in providing snow samples collecting during the 2017 Kangerlussuaq-EGRIP traverse., The GV7 surface sampling was support by the MIUR (Italian Ministry of University and Research) - PNRA (Italian Antarctic Research Programme) program through the IPICS-2kyr-It project (International Partnership for Ice Core Science, reconstructing the climate variability for the last 2kyr, the Italian contribution). The IPICS-2kyr-It project is carried out in cooperation with KOPRI (Korea Polar Research Institute, grant No. PE15010). The Dome C surface snow sampling was supported by the Programma Nazionale per la Ricerca in Antartide (PNRA, project 650 number 2013/AC3.03 PEA 2013–2015, PI Warren Cairns). The Talos Dome-Dome C traverse and associated analyses was supported by the Programma Nazionale per la Ricerca in Antartide (PNRA), project A2 number PNRA0016_295 “Bromine and mercury, cycles and transport processes on the Antarctic plateau”. We thank the CNR Dirigibile Italia Arctic station and the Department of Earth systems science and environmental technologies for logistical support in Svalbard.

21 pags, 10 figs., 1 tab., 4 apps.-- Open Access funded by Creative Commons Atribution Licence 4.0, Although it has been demonstrated that the speed and magnitude of the recent Arctic sea ice decline is unprecedented for the past 1450 years, few records are available to provide a paleoclimate context for Arctic sea ice extent. Bromine enrichment in ice cores has been suggested to indicate the extent of newly formed sea ice areas. Despite the similarities among sea ice indicators and ice core bromine enrichment records, uncertainties still exist regarding the quantitative linkages between bromine reactive chemistry and the first-year sea ice surfaces. Here we present a 120 000-year record of bromine enrichment from the RECAP (REnland ice CAP) ice core, coastal east Greenland, and interpret it as a record of first-year sea ice. We compare it to existing sea ice records from marine cores and tentatively reconstruct past sea ice conditions in the North Atlantic as far north as the Fram Strait (50-85° N). Our interpretation implies that during the last deglaciation, the transition from multi-year to first-year sea ice started at ~17.5 ka, synchronously with sea ice reductions observed in the eastern Nordic Seas and with the increase in North Atlantic ocean temperature. First-year sea ice reached its maximum at 12.4-11.8 ka during the Younger Dryas, after which open-water conditions started to dominate, consistent with sea ice records from the eastern Nordic Seas and the North Icelandic shelf. Our results show that over the last 120 000 years, multi-year sea ice extent was greatest during Marine Isotope Stage (MIS) 2 and possibly during MIS 4, with more extended first-year sea ice during MIS 3 and MIS 5. Sea ice extent during the Holocene (MIS 1) has been less than at any time in the last 120 000 years., The RECAP ice coring effort was financed by the Danish Research Council through a Sapere Aude Grant, the NSF through the Division of Polar Programs, the Alfred Wegener Institute, and the European Research Council under the European Community’s Seventh Framework Programme (FP7/2007- 2013)/ERC grant agreement 610055 through the Ice2Ice project and the Early Human Impact project (grant agreement 267696). This study has also received funding from the European Research Council Executive Agency under the European Union’s Horizon 2020 Research and Innovation programme (Project ERC-2016- COG 726349 CLIMAHAL).

Although it has been demonstrated that the speed and magnitude of recent Arctic sea ice decline is unprecedented for the past 1,450 years, few records are available to provide a paleoclimate context for Arctic sea ice extent. Here we present a 120 kyr record of bromine enrichment from the RECAP ice core, coastal East Greenland, and reconstruct past sea ice conditions in the North Atlantic as far north as the entrance of the Arctic Ocean (50–85° N). Bromine enrichment has been previously employed to reconstruct first-year sea ice (FYSI) in the Canadian Arctic over the last glacial cycle. We find that during the last deglaciation, the transition from multi-year sea ice (MYSI) to FYSI started at ∼ 17.6 kyr, synchronous with sea ice reductions observed in the eastern Nordic seas (Müller and Stein, 2014; Hoff et al., 2016) and with the increase of North Atlantic ocean temperature (Dokken and Jansen, 1999). FYSI reached its maximum extent at 12.4–11.8 kyr, after which open-water conditions started to dominate, as supported by sea ice records from the eastern Nordic seas and the North Icelandic shelf. Our results show that over the last 120,000 years, sea ice extent was greatest during Marine Isotope Stage (MIS) 2 and MIS4, with decreased levels during MIS3 and the onset of the last glacial period (late-MIS5). Sea ice extent during the last 10 kyr (Holocene/MIS1) has been less than at any time in the last 120 kyr.

The Law Dome site is ideal for the evaluation of sea ice proxies due to its location near to the Antarctic coast, regular and high accumulation throughout the year, an absence of surface melting or remobilization, and minimal multiyear sea ice. We present records of bromine and iodine concentrations and their enrichment beyond seawater compositions and compare these to satellite observations of first-year sea ice area in the 90-130°ĝ€E sector of the Wilkes coast. Our findings support the results of previous studies of sea ice variability from Law Dome, indicating that Wilkes coast sea ice area is currently at its lowest level since the start of the 20th century. From the Law Dome DSS1213 firn core, 26 years of monthly deposition data indicate that the period of peak bromine enrichment is during austral spring-summer, from November to February. Results from a traverse along the lee (western) side of Law Dome show low levels of sodium and bromine deposition, with the greatest fluxes in the vicinity of the Law Dome summit. Finally, multidecadal variability in iodine enrichment appears well correlated to bromine enrichment, suggesting a common source of variability that may be related to the Interdecadal Pacific Oscillation (IPO).

Reconstructing the past variability of Arctic sea ice provides an essential context for recent multi-year sea ice decline, although few quantitative reconstructions cover the Holocene period prior to the earliest historical records 1,200 years ago. Photochemical recycling of bromine is observed over first-year, or seasonal, sea ice in so-called >bromine explosions> and we employ a 1-D chemistry transport model to quantify processes of bromine enrichment over first-year sea ice and depositional transport over multi-year sea ice and land ice. We report bromine enrichment in the Northwest Greenland Eemian NEEM ice core since the end of the Eemian interglacial 120,000 years ago, finding the maximum extension of first-year sea ice occurred approximately 9,000 years ago during the Holocene climate optimum, when Greenland temperatures were 2 to 3 °C above present values. First-year sea ice extent was lowest during the glacial stadials suggesting complete coverage of the Arctic Ocean by multi-year sea ice. These findings demonstrate a clear relationship between temperature and first-year sea ice extent in the Arctic and suggest multi-year sea ice will continue to decline as polar amplification drives Arctic temperatures beyond the 2 °C global average warming target of the recent COP21 Paris climate agreement.