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The relationship between the spatial variability of soil elements, weathering and erosion rates can be very complex. Topography, abruptly-changing elevation gradients and slopes of varying geological composition exert an important influence on weathering trajectories and erosion. This complex interconnectivity is only rarely addressed in weathering studies. The main objectives of this investigation are, therefore, to relate weathering and erosion to various and geomorphic units in a dry-alpine and threshold landscape having steep slopes (Kan catchment, Tehran Province, Iran). A number of common weathering indices were tested using a genetic algorithm. The best indices are the (K + Na)/Ti ratio, the WIP (weathering index according to Parker), and the PI (product index according to Ruxton). However, the recently suggested 4Si-M+-R2 and M-F-Wmin systems discriminate weathering trends more accurately. Our results show that these soils have a low to moderate weathering stage. Weathering trajectories point to the active formation of kaolinite and oxyhydroxides. River sediments are slightly more weathered and contain the most-weathered topsoils and suggest erosion in the catchment is predominantly due to topsoil removal. Chemical weathering is influenced by the dominant geomorphic units (unconsolidated deposits of the Quaternary and solid bedrock) and landform features (combination of altitude and slope). Aspect does not appear to have a significant impact on weathering. Denudation (~erosion) rates were determined using meteoric 10Be since the fluvial sediments did not contain enough quartz for in situ 10Be analyses. This procedure has higher uncertainties due to difficulties in estimating the depositional flux of meteoric 10Be. Due to tectonic uplift, the erosion rates are very high. To maintain a soil layer, soil production rates must be also high. Although annual precipitation is relatively low, slope and soil dynamics seem particularly high, which leads to a fast turnover of the soil material and maintains the weathering intensity at a rather low to intermediate level.

Vast areas in the Mediterranean are characterised by evaporite deposits of the Messinian crises (c. 6–5.3 Ma BP). During this period, large deposits were built up in shallow lagoon-like systems and are now found in southern Italy, Albania, Cyprus and Turkey. So far, soil formation on evaporites has been studied predominantly in subarid to arid environments. Although the formation of soils has received new significance, little is known about the evolutional trajectories on evaporites of the Mediterranean. We therefore studied soil formation in the Caltanissetta basin (Sicily) where evaporites are most widespread. The lithologies included the sequence: marine clay deposits, laminated marl (diatomite; Tripoli sediments), Calcare di Base (limestone), detritic deposits, gypsum (selenite). The chemical signature (immobile elements, rare earth elements) indicated that they all have a similar origin. Surprisingly, both an increasing Corg and carbonate content in the soils caused a decrease in the δ 13C signal in carbonates and in part in the bulk soil. The low δ 13C and δ 18O values of carbonates in the parent material indicate a high rock-water (or meteoric water) interaction that has occurred during sedimentation and diagenesis. Organic matter was oxidised into the shallow lagoon-like systems and its carbon incorporated in the limestone. Elemental leaching from silicates during pedogenesis was most intense in the soils that developed on clays and Tripoli sediments. Vertisols and Mollisols have evolved, together with a high amount of oxyhydroxides (non-crystalline and crystalline forms) and kaolinite. Only weak soil formation was recognisable at sites having gypsiferous parent material. The presence of a high amount of selenite hindered a more advanced evolution. The soils developed on detritic and gypsiferous material exhibited some palygorskite that was inherited from the parent material. At sites having selenite or limestone, shallow Aridisols or Mollisols are found. Weathering is weakly pronounced, e.g. indicated by a high proportion of trioctahedral minerals. Besides inheritance from the parent material, smectite and kaolinite are also actively formed in the soils with increasing weathering. Plagioclase and mica are the main sources of smectite and K-feldspar is a main source of kaolinite neo-formation. The evaporite deposits vary greatly within short distances causing a high spatial diversity of soils. Consequently, soil quality strongly varies, which challenges agricultural use. Well-developed soil profiles and advanced weathering stages are only possible when marine clays, Tripoli sediments or detritic deposits are the parent material. Limestone (Calcare di Base) and gypsiferous sediments (selenite) strongly limit soil formation and mineral transformation.

Soil chronosequences in Alpine areas have often been applied to trace physical, mineralogical and chemical soil properties over time. How the soil pore system of undisturbed soils evolves, however, has not yet been clarified. We therefore investigated two soil chronosequences in the Swiss Alps spanning a time period from a few decades up to the Early Holocene/Late Pleistocene. One soil sequence developed on siliceous parent material in the Sustenpass (proglacial area of the Stein glacier), with soils aged from 30a to 10 ka while the second developed on calcaric parent material in the Klausenpass, with soils aged from 110a to 14 ka (proglacial area of the Griess glacier). We hypothesised that the overall pore size of the topsoil and consequently the relative proportion of macropores decrease with increasing soil age. The pore size characteristics were determined by using X-ray computed tomography. Independent of the parent material (calcareous vs siliceous), macroporosity decreased with time. The greatest changes seemed to occur between the Little Ice Age (LIA) and about 3–4 kyr of soil evolution. Vegetation composition and the functional richness of the plant community exert an influence on soils that developed on siliceous parent material by giving rise to more small pores. Besides pore sizes, pore characteristics also changed with time. In general, the tortuous structure of the soils became more complex with time. The evolution of the pore characteristics such as tortuosity, number and length of pore networks seem also to be related to biologic factors such as root properties, plant species and soil organic matter composition. It remains, however unanswered how these time-dependent biologic factors interact with and influence in detail the pore network. This aspect certainly merits investigation in greater detail in the future.

Recent studies have demonstrated that soils formed on pyroclastic ash deposits are much more common in the Mediterranean area than previously assumed. These soils are an important key to understanding past volcanic events and landscape evolution. Chronological information in soils of Quaternary volcanic events, however, remains still poorly understood in southern Italy. Using a multi-method forensic approach, we explore the origin and age of volcanic deposits (soils) in Sicily and Calabria. The geochemical signature of the soil was compared to the chemical fingerprint of the magmas of potential source areas of southern Italian volcanoes. The results indicate that the investigated soils on the Nebrodi (Sicily) and Sila (Calabria) mountains were both impacted by materials having a high-K calc-alkaline series volcanism. The Aeolian Islands (in particular Lipari and Vulcano) are the most likely source of origin, but contributions also from the Etna (particularly the Biancavilla ignimbrites and Plinian eruptions) occurred. Weathering and leaching processes, along with a potential contribution from the underlying non-volcanic bedrock, has altered the main chemical composition of soils, often precluding direct relation to potential source areas. Immobile elements and their ratios (e.g. the Nb/Y vs Zr/Ti plot) or trace elements (Co, Th) and rare earth elements (laser ablation ICP-MS analyses of glass particles, volcanic clasts and pumice-like materials) gave precious hints of the origin of the volcanic deposits. Radiocarbon dating of the H2O2 resistant soil organic fraction indicates a minimum age of 8–10 ka of the soils. The weathering index WIP (weathering index according to Parker) and the chemical composition of volcanic glasses and clasts were tested as proxies for the age of the volcanic deposits and time for soil formation. The soils and landscape are characterised by multiple volcanic depositional phases for the last about 50 ka in the Sila mountains and about 70 ka or more in the Nebrodi mountains. Chemical-mineralogical analyses enabled the detection of deposition phases during the Pleistocene and also Holocene. The multi-method approach enabled the identification of potential source areas, provided a tentative age estimate of the start (and in part duration) of ash deposits and therefore improved our understanding of volcanic landscape evolution.

At mid-latitudes, the transition from the Pleistocene to the Holocene was characterised by distinct and partially abrupt climatic changes. Also during the Holocene, climatic perturbations, with sometimes cold-dry conditions, have occurred. How land surfaces and soil development processes in high-mountains respond to these climatic oscillations is so far only poorly known. We traced the responses of surfaces in the alpine settings of the Wind River Range (Wyoming, US) by using a large mire as natural archive. This enabled us to reconstruct environmental conditions and ecosystem changes during the Holocene in this montane area. Although adjacent moraine deposits display 10Be exposure ages from the Last Glacial Maximum up to MIS16 or even older, the accessible sediment deposits covered only the Holocene (via radiocarbon dating). By applying a geoforensic approach and deriving sedimentation rates, major climatic signals were detected. A higher deposition (and consequently erosion) rate and thus a higher rate of geomorphic activity was measured for the known cold periods 9.4–10.2 ka BP, 4.2 ka BP and 2.5 ka BP. During the LIA, especially rapid aggradation of organic matter organic matter took place here. Rates of chemical weathering and soil formation seem to have been relatively low until about 5–6 ka BP but have since increased during the Late Holocene. This would fit previous observations of increasing moisture conditions after the mid-Holocene aridity period. In contrast to several other studies, no clear signs of major disturbances (erosion, weathering) during the 8.2 ka event could be observed. Together with the low levels of chemical weathering found here, we do not see any evidence that the climate was more humid during this period. Compared to previous findings, more humid conditions seemed to have returned earlier, i.e. about 5 kyr BP. In general, this landscape displayed a patchy pattern of reaction to environmental changes, as all events were not recorded in each mire profile., Geomorphology, 371, ISSN:0169-555x, ISSN:1872-695X

The European Alps are a geomorphologically active region and experience a number of gravity-driven hillslope processes. Soil and landscape formation in the Alps has consequently undergone several minor and major traceable changes of developmental trajectories during the Holocene. Soil development is hypothesised to be often non-linear with time and characterised by stages of progressive and regressive evolution caused by upbuilding (formation, profile deepening) and erosion (profile shallowing). Several cold and warm climate phases are identified during the Holocene but it is largely unknown which effects these might have had on slope processes. By using datable moraines ( 10 Be) and mires ( 14 C), we have constructed a temporal framework for these processes. Using the geochemical imprint of mires in the Alpine setting of the Goschener-valley of the Central Swiss Alps, we reconstructed general (mostly erosional) landscape processes for the last ca. 10 ka. As this is the type locality for the Goschener cold phase, we assumed that this phase (Goschener cold phase I and II ~ 1.5 and ~ 2.5 ka BP) should have left easily recognizable traits. After deglaciation (11–12 ka BP), soil evolution was progressive. Beginning around 8 ka BP, we detect a distinct increase in erosion here, together with a vegetation change (towards tundra vegetation) and the highest measured rates of carbon sequestration. Other phases of high geomorphic activity were recognised ca. 5–6 ka BP, 4 ka BP and, to a lesser extent, 1–3 ka ago. The cold phase at 5–6 ka BP corresponds to a less distinct change in vegetation and lessened erosion. Human impact is increasingly obvious since about 2.4 ka BP which overlaps with the Goschener cold phase. Nonetheless, erosion processes were not extraordinarily high during this period and a climate effect cannot be distinguished. We detect evidence of increasing human disturbance (regressive soil evolution) for about the last 1 ka. We also detect an increase in dust flux during the last ca. 4–5 ka, presumably due to the landscape change(s) in the Sahara during this time.

Purpose: The present work focuses on cold alpine soils of the Altai Mountains (Siberia, Russia). Permafrost is widespread and often occurs at a depth of about 100cm. The area is characterised by extremely cold winters and cool summers: the aim was consequently to find out whether weathering could be more intense on thermally less unfavoured conditions or whether the abundance of water could be a more important factor. Materials and methods: We investigated 10 soils in a very small area close to a local glacier tongue. Five of the investigated soils were south-facing and the other five north-facing. The soils have the same parent material (mica-rich till), altitude, topography and soil age. The vegetation is alpine grassland that is partially intersected with some juniper and mosses. Soil chemical properties such as organic C, N, soil organic matter quality (using DRIFT), pH value, (oxy)hydroxides, total elemental contents (XRF) and soil micromorphology and mineralogy (using diagnostic treatments and XRD) were determined. The age constraint of the site was given by geomorphic studies together with 14C dating of a nearby peat bog and the stable organic matter fraction of the soils. Results and discussion: The soils have a Holocene age. The results showed astonishingly clearly—similarly to the European Alps—that the north-facing soils have a higher weathering state. This is expressed by lower pH values, higher oxalate and dithionite extractable Fe, Al, Mn and Si contents, higher C and N concentrations and stocks when compared to the south-facing sites. No statistically significant differences with respect to weathering indexes could be detected. The geochemical evolution of the soils seems to be enhanced at north-facing sites, even though very severe climatic conditions prevail. Furthermore, biodegradation seems to be less pronounced on north-facing compared to south-facing sites as poorly degraded organic matter is accumulated. This gives rise to more organic ligands that promote metal binding and their subsequent eluviation along the soil profile. Conclusions: We consequently must assume that weathering is not limited by low temperatures in the active layer but is rather controlled by soil moisture that seems to be higher during the warmer period in the north-facing soils.

Only scarce information is available on how organic C is incorporated into the soil during the decay and how (micro) climate influences this process. Therefore, we investigated the effect of exposure and elevation on the organic litter decomposition and C-stabilisation in acidic soils of an Alpine environment. An experiment with artificially 13C labelled Norway spruce needles was carried out at north- and south-exposed sites between 1200 and 2400 m a.s.l. in the Italian Alps using mesocosms. After 1 year, the 13C recoveries of the bulk soil were 18.6% at the north-facing slopes and 31.5% at the south-facing slopes. A density fractionation into a light (LF; ≤1.6 g cm−3) and a heavy fraction (HF; >1.6 g cm−3) of the soil helped to identify how the applied substrate was stabilised. At the northern slope, 10.5% of the substrate was recovered in the LF and 8.1% in the HF and at the south-facing slope 22.8% in the LF and 8.1% in the HF. The overall 13C recovery was higher at the south-facing sites due to restricted water availability. Although the climate is humid in the whole area, soil moisture availability becomes more important at south-facing sites due to higher evapotranspiration. However, at sites >1700 m a.s.l, the situation changed, as the northern slope had higher recovery rates. At such altitudes, temperature effects are more dominant. This highlights the importance of locally strongly varying edaphic factors when investigating the carbon cycle.

Due to the large size (e.g. sections of tree trunks) and highly heterogeneous spatial distribution of deadwood, the timescales involved in the coarse woody debris (CWD) decay of Picea abies (L.) Karst. and Larix decidua Mill. in Alpine forests are largely unknown. We investigated the CWD decay dynamics in an Alpine valley in Italy using the chronosequence approach and the five-decay class system that is based on a macromorphological assessment. For the decay classes 1–3, most of the dendrochronological samples were cross-dated to assess the time that had elapsed since tree death, but for decay classes 4 and 5 (poorly preserved tree rings) radiocarbon dating was used. In addition, density, cellulose, and lignin data were measured for the dated CWD. The decay rate constants for spruce and larch were estimated on the basis of the density loss using a single negative exponential model, a regression approach, and the stage-based matrix model. In the decay classes 1–3, the ages of the CWD were similar and varied between 1 and 54 years for spruce and 3 and 40 years for larch, with no significant differences between the classes; classes 1–3 are therefore not indicative of deadwood age. This seems to be due to a time lag between the death of a standing tree and its contact with the soil. We found distinct tree-species-specific differences in decay classes 4 and 5, with larch CWD reaching an average age of 210 years in class 5 and spruce only 77 years. The mean CWD rate constants were estimated to be in the range 0.018 to 0.022 y−1 for spruce and to about 0.012 y−1 for larch. Snapshot sampling (chronosequences) may overestimate the age and mean residence time of CWD. No sampling bias was, however, detectable using the stage-based matrix model. Cellulose and lignin time trends could be derived on the basis of the ages of the CWD. The half-lives for cellulose were 21 years for spruce and 50 years for larch. The half-life of lignin is considerably higher and may be more than 100 years in larch CWD. Consequently, the decay of Picea abies and Larix decidua is very low. Several uncertainties, however, remain: 14C dating of CWD from decay classes 4 and 5 and having a pre-bomb age is often difficult (large age range due to methodological constraints) and fall rates of both European larch and Norway spruce are missing.

In this study we compare newly-developed chemical weathering data with previously published data from soils developed along two chronosequences of glacial deposits in the European Alps and the Rocky Mountains (Wind River Range, USA). By combining these chronosequences, we are able to present a comprehensive dataset that represents a time period of > 1 Ma. We describe weathering trends of important elements using a number of weathering indices (e.g., K + Ca/Ti ratio, the weathering ‘index B’ of Kronberg and Nesbitt (1981) and the open mass transport function). Further, we describe the accumulation of Al, Fe, Si and Mn oxyhydroxides (including partially organic phases) as a function of time, and derive the corresponding accumulation rates. We calculated pedogenetically formed oxyhydroxides using an approach based on immobile elements. Our study represents one of only a few studies that describe rates of soil chemical weathering over a period as long as ~ 1 Ma. Results show that rates of chemical weathering clearly decrease along the chronosequences with increasing age of the soils. We find weathering rates are nearly four orders of magnitude lower in the 1 Ma-old soils than in the young soils. Our results suggest that the older soils may be reaching a steady state for these chemical properties in their present environments. A power function best explains the measured time-trends of the ‘index B’ and (K + Ca)/Ti) ratios in the soils. The best time-trend model for pedogenic weakly- to poorly crystalline phases and the relative losses/gains (based on the open-system mass transport function) were obtained with an exponential decay model function. In terms of the soil system, the decreases in the accumulation rate of the oxyhydroxides appears to be influenced not only by the factor of time but by climate as well (increased precipitation at higher altitudes slows the decrease in weathering rate over time). Thus, our ~ 1 Ma chronosequences also become pedogenic gradients since we describe variations in soil properties along biogenic gradients.

Peat and lake sediments as well as a nearby soil catena were sampled to reconstruct the environmental history of a small infilled lake basin (mire) in the central alpine foreland of Switzerland. Soil evolution is best regarded as discontinuous over time and conceptualised by ‘progressive’ or ‘regressive’ process phases. We analysed the surrounding soils and used corresponding pedosignatures in the mire sediments to characterise notable phases of erosion and deposition. We assumed that the mire sediments would reflect these phases, that elemental composition (major and minor compounds) and rare earth elements (REEs) would allow us to differentiate past processes and that progressive and regressive phases of soil development can be discerned. Although radiocarbon ages are equivocal, it appears from pollen analyses that a lake was present here by c. 45 ka BP. After the retreat of the glacier from this area following the LGM, continuous sedimentation occurred until a mire developed during Pleistocene–Holocene transition. This transition period was accompanied by more intense erosion, as characterised by chemical signatures. A stable phase developed between c. 10–5 ka BP giving rise to progressive soil evolution. Between 5 and 4 ka BP, evidence appears for several erosional phases, predominantly detectable at the margin of the mire. These erosion phases, coupled with accumulation in the mire, are even more evident after 4 ka BP and especially after 2.1 ka BP. Based on soil investigations, elemental fluxes are detected along the slopes with distinct accumulations at the footslope. Evidence for anthropogenic influences and subsequent regressive soil formation phases appear in this pre-alpine landscape about 5 ka BP (Neolithic/Early Bronze Age), which appears to intensify after 2.1 ka BP (Roman period to present). Multi-elemental signatures enabled us to identify the important geochemical processes that have occurred here. Together with radiocarbon and pollen analyses, we placed these processes in a logical temporal context. The use of lacustrine (lake or mire) sediments has great potential to decipher and detail the surrounding landscape history and soil evolution of this region of Switzerland.

At middle to high latitudes, many alpine valleys have been shaped by glaciers associated with periods of Pleistocene glaciation. Present glaciated valleys are characterised by broadened valley floors and U-shaped cross sections, continuously formed by glacial activity from initially V-shaped, fluvial cross sections. Sinks Canyon (Wind River Range, USA) is a glaciated valley characterised by a typical U-shaped cross section, containing till from several glacial advances over a range of at least 1 Ma. The morphostratigraphic records indicate a fourfold difference in ice surface elevation between the youngest and oldest glacial periods, which is not easily explained by the present-day valley topography. To assess possible evolution scenarios of Sinks Canyon, we modelled the palaeovalley topography using a geographic information system (GIS) filtering technique in combination with temporal reference points from relative and numerically dated glacial deposits. Ice thicknesses were calculated using the shallow ice approximation. In our model, the valley became shallower and the topography smoother with increasing years back in time. The results suggest that valley topography with ages between 640 and 1000 ka can clearly be distinguished from the present-day topography. Surfaces with ages of 130–200 ka (attributable to MIS 6; Bull Lake glaciation) still could be discerned from present-day topography, but with relatively high uncertainties. The method did not work for topography less than ~ 100 ka or older than ~ 1 Ma. Erosion depths were calculated using the differences between present-day elevation and the modelled surfaces. Calculated erosion rates were within the range of reference values for glacial erosion (0.001 to 1 mm a− 1). Glacial erosion appears to have removed 0.52 to 0.72 mm a− 1 of rock within a time frame of 1 Ma, assuming 200 ka of aggregated glacial flow. If the glacial occupation was longer or the impact of fluvial erosion was not negligible (as assumed), then the calculated rate is lower. If the model assumes a less extended time of glacial flow (< 100 ka), the rate exceeds 1 mm a− 1. The method used for surface reconstruction and erosion rates calculation is highly dependent on (i) the reliability of the temporal anchor points and (ii) the assumption of physical glacier conditions (basal shear stress).

Soil organic matter (SOM) can directly be affected by wildfires, both in terms of quantity and quality. The combustion is often incomplete, leading to the formation of pyrogenic organic matter (PyOM), a highly heterogeneous material with prevailing aromatic nature. Focusing our attention on PyOM, we investigated an altitudinal soil sequence on Mount Etna, Italy, ranging from 500 m to 1800 m asl, where the fire frequency is assumed to have been higher at lower elevations due to a warmer and drier climate. We evaluated the effect of fire on the chemical and physical characteristics of SOM along the altitudinal sequence. At two sites at a similar altitude but having a different recent fire history, we also examined the effect of fire frequency on SOM. Chemical oxidation of SOM with acid dichromate was used to evaluate the contribution of pyrogenic organic carbon to total SOC. Furthermore, four SOM density fractions were separated and characterised for principal composition, spectroscopic properties by Diffuse Reflectance Infrared Fourier Transform (DRIFT) and Nuclear Magnetic Resonance (NMR), and particle morphology by Scanning Electron Microscopy (SEM). The stocks of C and N as well as the chemical oxidation resistant carbon (COREC) increased with decreasing altitude, hence supporting the hypothesis of higher fire frequency at lower altitudes. The highest C concentrations were found in the density fraction 1.0–1.6 g cm − 3 . At the lower sites, a considerable amount of aromatics, and hence a significant part of COREC, was found in the density fraction 1.0–1.6 g cm − 3 except for (macro)charcoal that occurs in the lightest fraction ( − 3 ). The properties of this latter density fraction seemed to be well related to vegetation characteristics. The dichromate oxidation procedure, however, has methodological restrictions. This procedure resulted here to be poorly specific for PyOM in the investigated soils, since it isolated a fraction rich in lipids. The lack of specificity for PyOM is most likely due to the rather low content of aromatics in SOM, although fire frequency was relatively high.

Current climatic conditions and the occurrence of discontinuous and sporadic permafrost in the Alps result in a low turnover rate and therefore accumulation of organic matter (OM) in soils. Alpine soils are thus highly sensitive to global warming that potentially promotes the mineralisation of soil organic matter (SOM). This process might increase the release of CO2 to the atmosphere. Our aim was to investigate the potential effect of permafrost thawing by the analysis of the physical–chemical soil properties of permafrost versus non-permafrost sites. Specifically, we i) quantified the SOM stocks at such sites, ii) characterised SOM and its physical and chemical fractions and iii) estimated the age range of the bulk soil and stable C-fraction (radiocarbon dating). In south-eastern Switzerland, two areas above the timberline and one below the timberline (where isolated permafrost was verified) were investigated in detail. At each site, the experimental set-up consisted in the comparison of nearby soils that were either influenced or not by permafrost. The C-stocks (down to the C horizon or rock surface) did not show a significant difference between permafrost and non-permafrost soils and were in the same range of 10–15 kg/m2 in alpine (grassland) and subalpine (forest) sites. Above the timberline, the bulk SOM showed a distinct higher age at permafrost sites compared to non-permafrost sites. This higher age was even more evident in the stable C-fraction (resistant to an H2O2 treatment), where ages of up to 11 ky in permafrost soils were recorded. The highest age obtained in the stable C-fraction in non-permafrost soils was around 4 ky. Consequently, climatic conditions and the occurrence of discontinuous permafrost resulted in a very low turnover rate of SOM. At the subalpine site, the difference between permafrost and non-permafrost sites was less. At both sites (alpine and subalpine), DRIFT (Diffuse Reflection Infrared Fourier Transform) was used to determine the functional groups in the bulk soil and in the stable C-fraction. In general, the stable C-fraction had a different composition compared to the bulk SOM at non-permafrost sites; this was mostly not the case at the permafrost sites. This confirms that different decomposition processes occur between permafrost and non-permafrost sites. Furthermore, permafrost sites accumulated more the low-density physical fractions of SOM that are potentially easily degradable. The obtained results suggest that a warmer climate may not necessarily lead to an increased CO2 release from SOM-degradation in permafrost soils compared to non-permafrost soils. High-alpine soils and OM furthermore integrate a multi-facetted response to the past and ongoing surrounding conditions. The melting of permafrost will most likely enhance vegetation growth, which to a certain degree will probably compensate for carbon losses on the long-term.

A comparison was made between two soil climosequences on north- and south-facing slopes in northern Italy to determine the influence of slope aspect on soil processes. The climosequences span an elevational gradient ranging from moderate (1200 m a.s.l.) to high alpine (2420 m a.s.l.) climate zones on surfaces having an age of about 15 000 years. The soils were investigated with respect to organic C, oxalate and dithionite extractable Fe, Al and Si, elemental losses (Ca, Mg, K, Na, Fe, Al, Si, Mn) and clay minerals. The stocks of soil org. C as well as of oxalate-extractable Fe and Al was greatest in the subalpine zone near the timberline. There are no clear differences in organic C content between the soils on north- and south-facing sites. Fe-oxalate and to a lesser extent Alo-stocks were, however, greater on north-facing sites, indicating that weathering is greater there. Eluviation and illuviation of Al and Fe within the soil profile, typical for podzolisation, was more distinctly expressed on the N slopes. The probability of ITM (Imogolite-type-material) formation in the soil seemed to be greater on south-facing sites. On the north-facing sites, element leaching was most intense in the subalpine zone close to the timberline while on the south-facing sites this was only the case for the base cations. The N slopes exhibited higher leaching of elements which generally indicates a higher weathering intensity. On south-facing sites, typical podzolisation processes were measurable only above 2000 m a.s.l. The development of smectites is also a reflection of the weathering intensity; smectite was discernible in the surface horizon at all sites on N slopes but the highest amount was detected in the sub-alpine climate zone. For the south-facing sites only in the alpine climate zone could smectite be detected. Higher temperatures and an increased number of freeze-thaw cycles on south-facing slopes should theoretically enhance rates of chemical weathering. This could, however, not be confirmed with our measurements. The degree of chemical weathering increases from the south- to the north-facing sites that are characterised by lower temperatures, lower evapotranspiration and consequently by a higher humidity. Although precipitation in Alpine regions is abundant, the availability and flux of water through the soil is the prime factor in weathering intensity.