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The microstructure of single crystal superalloy with and without tin layer on the surface of as-cast and heat-treatment state was investigated by optical microscope (OM) and scanning electron microscopy (SEM). The composition of different regions on the surface was tested by energy dispersive X-ray (EDS). The reaction intermetallic compound (IMC) formed in the heat treatment process was confirmed by X-ray diffraction (XRD). The orientations of different microstructure in samples as heat treatment state were determined by electron back-scattering diffraction (EBSD) method. The porosity location in the interdendritic region was observed by X-ray computed tomography (XCT). The experiment results showed that the remained Sn on the surface of the superalloy reacted with Ni, and then formed Ni 3 Sn 4 in the as-cast state. Sn enriched by diffusion along the porosity located in the interdendritic region and γ + γ′ (contain a little of Sn) eutectic and Ni 3 Sn 2 formed in single crystal superalloy during heat treatment, and the recalescence behaviors were found. Ni 3 Sn 2 nucleated independently in the cooled liquid at the front of (γ + γ′) (Sn) eutectic. The nucleation and growth mechanism of the eutectic and Ni 3 Sn 2 IMC during heat treatment was discussed in the present paper. [ABSTRACT FROM AUTHOR]