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Organic photovoltaic (OPV) cells, with highly tunable light‐response ranges, offer significant potential for use in driving low‐power consumption off‐grid electronics in multi‐scenarios. However, development of photoactive layer materials that can meet simultaneously the requirements of diverse irradiation conditions is a still challenging task. Herein, a low‐cost fully non‐fused acceptor (denoted as GS60) featuring well‐matched absorption spectra with solar, scattered light and artificial light radiation was designed and synthesized. Systematic characterizations revealed that GS60 possessed outstanding photoelectron properties and ideal morphology, which resulted in reduced voltage loss and suppressed charge recombination. By blending with a non‐fused ring polymer PTVT−T, the as‐obtained GS60 based OPV cells achieved a good power conversion efficiency (PCE) of 14.1 %, a high value for the cells based on non‐fused ring bulk heterojunction. Besides, manufactured large‐area OPV modules based on PTVT−T:GS60 yielded PCEs of 11.2 %, 11.8 %, 12.1 %, 23.1 %, and 20.3 % under irradiation of AM 1.5G, natural light of cloudy weather, natural light in shadow, laser and indoor, respectively. The PTVT−T:GS60 devices exhibited considerable potential in terms of improving photostability and reducing material cost. Overall, this work provides novel insight into the molecular design of low‐cost non‐fused ring acceptors, and extended potential of medium band gap acceptors based OPV cells used in various application scenarios. [ABSTRACT FROM AUTHOR]