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1. Structure and cation ordering in spinel-type TcCo2O4. An example of a trivalent technetium oxide.

Author

Thorogood, Gordon J., Zhang, Zhaoming, Hester, James R., Kennedy, Brendan J., Ting, Jimmy, Glover, Chris J., and Johannessen, Bernt

Subjects
*TECHNETIUM compounds, *CHEMICAL structure, *OXIDES, *X-ray diffraction, *NEUTRON diffraction, *ABSORPTION spectra
Abstract

The structure of TcCo2O4has been determined using a combination of synchrotron X-ray and neutron powder diffraction methods. It has an inverse spinel structure where the Tc occupies the octahedral sites. Both the refined Tc–O distance and X-ray absorption spectra suggest the Tc is predominantly trivalent. [ABSTRACT FROM AUTHOR]

Published
2011
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