1. Studies on a novel Ho3+:KBGM crystal toward the ∼2 μm laser applications.
- Author
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Yu, Yi, Niu, Chonghui, Shao, Kai, Dan, Mingjie, Wang, Zhibin, Wang, Yingying, Chen, Jie, and Luo, Jiani
- Subjects
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CRYSTALS , *QUANTUM efficiency , *ABSORPTION spectra , *CRYSTAL structure , *MOLECULAR spectra - Abstract
• A Ho3+:KBGM crystal with good quality and large size was successfully grown by using TSSG method. • Crystal structure, polarized absorption and emission spectra were extensively studied. • The crystal has wide absorption and emission bandwidth with large absorption and emission cross-sections. • The lifetime was investigated and result indicated a relatively high quantum efficiency in this crystal. A Ho3+:KBGM crystal with good quality and large size was successfully grown via TSSG method. The crystal's structure, ambient-temperature polarized absorption and emission spectra and fluorescence lifetime were studied. The J-O theory was adopted to analyze the absorption spectra and results show that crystal exhibits relatively large intensity parameters Ω 2 and spectroscopic quality factor which is up to 3.12. At 453 nm, the absorption band is the strongest, and the corresponding cross-sections are 21.94 × 10–20 cm2, 26.66 × 10–20 cm2 and 18.56 × 10–20 cm2 for the - X , - Y and - Z polarizations, respectively. The emission spectra also demonstrate the broad and strong emission band at 2030 nm. The FWHMs and cross-sections are 74 nm, 0.37 × 10−20 cm2, 50 nm, 0.68 × 10−20 cm2, and 49 nm 0.52 × 10−20 cm2 for the three polarizations, respectively. In addition, the crystal has a superior quantum efficiency which is as high as 97.1%. Taking all the analyses into account, it is reasonable to assert that the Ho3+:KBGM crystal an ideal candidate for ∼2 µm laser applications in many areas. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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