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This study aimed to explore the effect of induced electric field (IEF) treatment on acid hydrolysis of corn starch by altering the connection modes of sample coils of a 4-reactor IEF system. Results suggested that IEF treatment could enhance the hydrolysis of corn starch and series connection (1. RRRR, η = 16 E Si 2 P in 4 Z Si + Z load ) exhibited higher energy efficiency than parallel (9. (RRRR), η = 4 E Si 2 P in Z Si + 4 Z load ), thus contributing to more extensive hydrolysis. Although no new functional group was formed, the starch granules were partially cracked into pieces and the crystallinity was slightly increased after IEF-assisted hydrolysis. Differential scanning calorimetry results indicated that IEF-assisted hydrolysis increased the gelatinization temperatures but decreased the enthalpy of starch, with a greatest variation was observed by series connection. Rapid visco-analysis showed that IEF-assisted hydrolysis greatly decreased the pasting viscosity of corn starch and also series connection showed the strongest reduction. The obtained results could provide a theoretical guide for the applications of IEF technology in biomaterial processing. [Display omitted] • Induced electric field (IEF) could enhance the acid hydrolysis of corn starch. • IEF-assisted hydrolysis highly depends on the energy efficiency of IEF system. • Series connection of IEF reactors showed the highest energy efficiency. • IEF-assisted hydrolysis largely decreased the pasting viscosity of corn starch. • IEF-assisted hydrolysis increased gelatinization temperatures but decreased enthalpy. [ABSTRACT FROM AUTHOR]

• Innovative contactless thermal effect on starch hydrolysis was investigated. • Starch acidolysis solution acts as the coils of a transformer for heating treatment. • Innovative inner heating method accelerated corn starch acid hydrolysis. • The treated starch had increased solubility and swelling power. • Thermal effect of induced electric field altered the physicochemical properties of starch. Growing attention has been focused on modifications of starch using electric field, but electrode corrosion and metal contamination remain unavoidable during the process. To solve these problems, the magneto-induced electric field was used to assist corn starch hydrolysis due to its thermal effect. Results indicated that the method accelerated corn starch acid hydrolysis and decreased the treatment time. The reducing sugar content increased to 0.59 g/L after a 60 s treatment, which was 353.44 % higher than the 20 s treatment, while the average degree of polymerization reached a minimum. The treated starch showed increased solubility and swelling power, as well as decreased freeze-thaw stability. X-ray diffraction, fourier transform infrared spectroscopy, and scanning electron microscopy results suggested that the physicochemical changes of corn starch were due to the thermal effect of the induced electric field. This study is expected to provide an important basis for applying new electric field hydrolysis technology to starch modification. [ABSTRACT FROM AUTHOR]