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1. Synthesis and characterization of an amethyrin-uranyl complex displaying aromatic character.

Author

Brewster, James T., Aguilar, Apolonio, Anguera, Gonzalo, Zafar, Hadiqa, Moore, Matthew D., and Sessler, Jonathan L.

Subjects
URANYL compounds, ULTRAVIOLET spectroscopy, CYCLIC voltammetry, NUCLEAR magnetic resonance spectroscopy, PYRROLES
Abstract

The reaction between amethyrin and non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2) under anaerobic conditions affords a bench-stable uranyl complex. UV-vis spectroscopy, cyclic voltammetry, as well as proton NMR spectroscopic analyses provide support for the conclusion that all six pyrrole subunits participate in coordination of the uranyl dication and that, upon complexation, the amethyrin-core undergoes a 2-electron oxidation to yield a formal 22 π-electron aromatic species. [ABSTRACT FROM AUTHOR]

Published
2018
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