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The mathematical modeling of the activation energy and binary chemical reaction system with six distinct types of nanoparticles, along with the magnetohydrodynamic effect, is studied in this paper. Different types of hybrid nanofluids flowing over porous surfaces with heat and mass transfer aspects are examined here. The empirical relations for nanoparticle materials associated with thermophysical properties are expressed as partial differential equations, which are then interpreted into ordinary differential expressions using appropriate variables. The initial shooting method converts the boundary condition into the initial condition with an appropriate guess and finally finds out an accurate numerical solution by using the Runge–Kutta method with numerical stability. Variations in nanoparticle volume fraction at the lower and upper walls of porous surfaces, as well as the heat transfer rate measurements, are computed using the controlling physical factors. The effects of the flow-related variables on the axial velocity, radial velocity, temperature, and concentration profile dispersion are also investigated. The Permeable Reynolds number is directly proportional to the regression parameter. The injection/suction phenomenon associated with the expanding/contracting cases, respectively, have been described with engineering parameters. The hybrid nanoparticle volume fraction (1–5%) has a significant effect on the thermal system and radial velocity. [ABSTRACT FROM AUTHOR]