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Satellite-based observations of carbon dioxide (CO2) are sensitive to all processes that affect the propagation of radiation in the atmosphere, including scattering and absorption by atmospheric aerosols. Therefore, accurate retrievals of column-averaged CO2 (XCO2) benefit from detailed information on the aerosol conditions. This is particularly relevant for future missions focusing on observing anthropogenic CO2 emissions, such as the Copernicus Anthropogenic CO2 Monitoring mission (CO2M). To fully prepare for CO2M observations, it is informative to investigate existing observations in addition to other approaches. Our focus here is on observations from the NASA Orbiting Carbon Observatory -2 (OCO-2) mission. In the operational full-physics XCO2 retrieval used to generate OCO-2 level 2 products, the aerosol properties are known to have high uncertainty but their main objective is to facilitate CO2 retrievals. We evaluate the OCO-2 product from the point of view of aerosols by comparing the OCO-2 retrieved aerosol properties to collocated Moderate Resolution Imaging Spectro-radiometer (MODIS) Aqua Dark Target aerosol products. We find that there is a systematic difference between the aerosol optical depth (AOD, τ) values retrieved by the two instruments, such that τOCO−2 ∼ 0.4τMODIS. We also find a dependence of the XCO2 on the AOD difference, indicating an aerosol-induced effect in the XCO2 retrieval. In addition, we find a weak but statistically significant correlation between MODIS AOD and XCO2, which can be partly explained by natural covariance and co-emission of aerosols and CO2 but is partly masked by the aerosol-induced XCO2 bias. Furthermore, we find that issues in the OCO-2 aerosol retrieval may lead to misclassification of the quality flag for a small fraction of OCO-2 retrievals. Based on MODIS data, 4.1 % of low AOD cases are incorrectly classified as high AOD (low quality) pixels, while 16.5 % of high AOD cases are erroneously classified as low AOD (high quality) pixels. Finally, we investigate the effect of an AOD threshold on the fraction of acceptable XCO2 data. We find that relaxing the MODIS AOD threshold from 0.2 to 0.5 (at 550 nm), which is the goal for the CO2M, increases the fraction of acceptable data by 14 percentage points globally, and by 31 percentage points for urban areas. [ABSTRACT FROM AUTHOR]

The Atmospheric Carbon Observations from Space (ACOS) retrieval algorithm has been delivering operational column-averaged carbon dioxide dry-air mole fraction (XCO2 ​​​​​​​) data for the Orbiting Carbon Observatory (OCO) missions since 2014. The ACOS Level 2 Full Physics (L2FP) algorithm retrieves a number of parameters, including aerosol and surface properties, in addition to atmospheric CO 2. Past analysis has shown that while the ACOS retrieval meets mission precision requirements of 0.1 %–0.5 % in XCO2 , residual biases and some sources of error remain unaccounted for. Forward model and other errors can lead to systematic biases in the retrieved XCO2 , which are often correlated with these additional retrieved parameters. The characterization of such biases is particularly essential to urban- and local-scale emissions studies, where it is critical to accurately distinguish source signals relative to background concentrations. In this study we explore algorithm-induced biases through the use of simulated OCO-3 snapshot area mapping (SAM) mode observations, which offer a unique window into these biases with their wide range of viewing geometries over a given scene. We focus on a small percentage of SAMs in the OCO-3 vEarly product which contains artificially strong across-swath XCO2 biases spanning several parts per million, related to observation geometry. We investigate the causes of swath bias by using the timing and geometry of real OCO-3 SAMs to retrieve XCO2 from custom simulated Level 1b radiance spectra. By building relatively simple scenes and testing a variety of parameters, we find that aerosol is the primary driver of swath bias, with a complex combination of viewing geometry and aerosol optical properties contributing to the strength and pattern of the bias. Finally, we seek to understand successful mitigation of swath bias in the new OCO-3 version 10 data product. Results of this study may be useful in uncovering other remaining sources of XCO2 bias and may help minimize similar retrieval biases for both present missions (GOSAT, GOSAT-2, OCO-2, OCO-3, TanSat) and future missions (e.g., MicroCarb, GeoCarb, GOSAT-GW, CO2M). [ABSTRACT FROM AUTHOR]

The Atmospheric Carbon Observations from Space (ACOS) retrieval algorithm has been delivering operational column-averaged carbon dioxide dry-air mole fraction (XCO2) data for the Orbiting Carbon Observatory (OCO) missions since 2014. The ACOS Level 2 Full Physics (L2FP) algorithm retrieves a number of parameters, including aerosol and surface properties, in addition to atmospheric CO2. Past analysis has shown that while the ACOS retrieval meets mission precision requirements of 0.1-0.5% in XCO2, residual biases and some sources of error remain unaccounted for (Wunch et al., 2017; Worden et al., 2017; Torres et al., 2019). Forward model and other errors can lead to systematic biases in the retrieved XCO2, which are often correlated with these additional retrieved parameters. The characterization of such biases is particularly essential to urban- and local-scale emissions studies, where it is critical to accurately distinguish source signals relative to background concentrations (Nassar et al., 2017; Kiel et al., 2021). In this study we explore algorithm-induced biases through the use of simulated OCO-3 Snapshot Area Mapping (SAM) mode observations, which offer a unique window into these biases with their wide range of viewing geometries over a given scene. We focus on a small percentage of SAMs in the OCO-3 vearly product which contain artificially strong across-swath XCO2 biases spanning several parts per million, related to observation geometry. We investigate the causes of swath bias by using the timing and geometry of real OCO-3 SAMs to retrieve XCO2 from custom simulated L1b radiance spectra. By building relatively simple scenes and testing a variety of parameters, we find that aerosol is the primary driver of swath bias, with a complex combination of viewing geometry and aerosol optical properties contributing to the strength and pattern of the bias. Finally, we seek to understand successful mitigation of swath bias in the new OCO-3 version 10 data product. Results of this study may be useful in uncovering other remaining sources of XCO2 bias, and may help minimize similar retrieval biases for both present missions (GOSAT, GOSAT-2, OCO-2, OCO-3, TanSat) and future missions (e.g. MicroCARB, GeoCarb, GOSAT-GW, CO2M). [ABSTRACT FROM AUTHOR]

The Orbiting Carbon Observatory-2 (OCO-2) was launched in 2014 with the goal of measuring the column-averaged dry-air mole fraction of carbon dioxide (XCO2) with sufficient precision and accuracy to infer regional carbon sources and sinks. One of the primary sources of error in near-infrared measurements of XCO2 is the scattering effects of cloud and aerosol layers. In this work, we study the impact of ingesting better informed aerosol priors from the Goddard Earth Observing System Model, Version 5 (GEOS-5) into the OCO-2 ACOS V8 retrieval algorithm with the objective of reducing the error in XCO2 from real measurements. Multiple levels of both aerosol setup complexity and uncertainty on the aerosol priors were tested, ranging from a mostly unconstrained aerosol optical depth (AOD) setup to ingesting full aerosol profiles with high confidence. We find that using co-located GEOS-5 aerosol types and AODs with low uncertainty results in a small improvement in the retrieved XCO2 against the Total Carbon Column Observing Network relative to V8. In contrast, attempting to use modeled vertical information in the aerosol prior to improve the XCO2 retrieval generally gives poor results, as aerosol models struggle with the vertical placement of aerosol layers. To assess regional differences in XCO2 , we compare our results to a global CO2 model validation suite. We find that the GEOS-5 setup performs better than V8 over northern Africa and central Asia, with the standard deviation of the XCO2 error reduced from 2.12 to 1.83 ppm, due to a combination of smaller prior AODs and lower prior uncertainty. In general, the use of better informed aerosol priors shows promise but may be restricted by the current accuracy of aerosol models. [ABSTRACT FROM AUTHOR]

The Orbiting Carbon Observatory-2 (OCO-2) was launched in 2014 with the goal of measuring the column-averaged dry-air mole fraction of carbon dioxide (XCO2) with sufficient precision and accuracy to infer regional carbon sources and sinks. One of the primary sources of error in near-infrared measurements of XCO2 is the scattering effects of cloud and aerosol layers. In this work, we study the impact of ingesting intelligent aerosol priors from the Goddard Earth Observing System Model, Version 5 (GEOS-5) into the OCO-2 ACOS V8 retrieval algorithm with the objective of reducing the error in XCO2 from real measurements. Multiple levels of both aerosol setup complexity and uncertainty on the aerosol priors were tested, ranging from a mostly unconstrained aerosol optical depth (AOD) setup to ingesting full aerosol profiles with high confidence. We find that using co-located GEOS-5 aerosol types and AODs with low uncertainty results in a small improvement in the retrieved XCO2 against the Total Carbon Column Observing Network relative to V8. In contrast, attempting to use modeled vertical information in the aerosol prior to improve the XCO2 retrieval generally gives poor results, as aerosol models struggle with the vertical placement of aerosol layers. To assess regional differences in XCO2, we compare our results to a global CO2 model validation suite. We find that the GEOS-5 setup performs better than V8 over Northern Africa and Central Asia, with the standard deviation of the XCO2 error reduced from 2.12ppm to 1.83ppm, due to a combination of smaller prior AODs and lower prior uncertainty. In general, the use of more intelligent aerosol priors shows promise but is currently restricted by the accuracy of aerosol models. [ABSTRACT FROM AUTHOR]

This work describes the radiometric calibration of the short-wave infrared (SWIR) bands of two instruments aboard the Greenhouse gases Observing SATellite (GOSAT), the Thermal And Near infrared Sensor for carbon Observations Fourier Transform Spectrometer (TANSO-FTS) and the Cloud and Aerosol Imager (TANSO-CAI). Four vicarious calibration campaigns (VCCs) have been performed annually since June 2009 at Railroad Valley, NV, USA, to estimate changes in the radiometric response of both sensors. While the 2009 campaign ( VCC2009) indicated significant initial degradation in the sensors compared to the prelaunch values, the results presented here show that the stability of the sensors has improved with time. The largest changes were seen in the 0.76 μm oxygen A-band for TANSO-FTS and in the 0.380 and 0.674 μm bands for TANSO-CAI. This paper describes techniques used to optimize the vicarious calibration of the GOSAT SWIR sensors. We discuss error reductions, relative to previous work, achieved by using higher quality and more comprehensive in situ measurements and proper selection of reference remote sensing products from the Moderate Resolution Imaging Spectroradiometer used in radiative transfer calculations to model top-of-the-atmosphere radiances. In addition, we present new estimates of TANSO-FTS radiometric degradation factors derived by combining the new vicarious calibration results with the time-dependent model provided by Yoshida (2012), which is based on analysis of on-board solar diffuser data. We conclude that this combined model provides a robust correction for TANSO-FTS Level 1B spectra. A detailed error budget for TANSO-FTS vicarious calibration is also provided. [ABSTRACT FROM PUBLISHER]

Japan's Greenhouse Gases Observing Satellite (GOSAT) was successfully launched into a sun-synchronous orbit on January 23, 2009 to monitor global distributions of carbon dioxide ( \CO2) and methane (\CH4). GOSAT carries two instruments. The Thermal And Near-infrared Sensor for carbon Observation Fourier-Transform Spectrometer (TANSO-FTS) measures reflected radiances in the 0.76 \mu\m oxygen band and in the weak and strong \CO2 bands at 1.6 and 2.0 \mu\m. The TANSO Cloud and Aerosol Imager (TANSO-CAI) uses four spectral bands at 0.380, 0.674, 0.870, and 1.60 \mu\m to identify clear soundings and to provide cloud and aerosol optical properties. Vicarious calibration was performed at Railroad Valley, Nevada, in the summer of 2009. The site was chosen for its flat surface and high spectral reflectance. In situ measurements of geophysical parameters, such as surface reflectance, aerosol optical thickness, and profiles of temperature, pressure, and humidity, were acquired at the overpass times. Because the instantaneous field of view of TANSO-FTS is large (10.5 km at nadir), the spatially limited reflectance measurements at the field sites were extrapolated to the entire footprint using independent satellite data. During the campaign, six days of measurements were acquired from two different orbit paths. Spectral radiances at the top of the atmosphere were calculated using vector radiative transfer models coupled with ground in situ data. The agreement of the modeled radiance spectra with those measured by the TANSO-FTS is within 7%. Significant degradations in responsivity since launch have been detected in the short-wavelength bands of both TANSO-FTS and TANSO-CAI. [ABSTRACT FROM PUBLISHER]