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In response to the dual carbon policy, the proportion of clean energy power generation is increasing in the power system. Energy storage technology and related industries have also developed rapidly. However, the life-attenuation and safety problems faced by energy storage lithium batteries are becoming more and more serious. In order to clarify the aging evolution process of lithium batteries and solve the optimization problem of energy storage systems, we need to dig deeply into the mechanism of the accelerated aging rate inside and outside the lithium ion from the perspective of the safety and stability of a lithium battery in view of the complex and changeable actual working conditions during the operation of the battery. This paper takes a lithium-iron phosphate battery and a lithium-ion battery as examples to analyze. According to the specific scene of lithium battery operation, the actual operating conditions of lithium battery environmental impact factors and attenuation mechanisms are described in detail. The damage to the internal structure of lithium batteries was systematically analyzed. Furthermore, the correlation between the external influencing factors and the aging rate of lithium batteries under the coupling effect of internal failure mechanisms is analyzed. Finally, future energy storage failure analysis technology is anticipated, hoping to play a positive role in promoting the development of energy storage and lithium battery failure analysis technology. [ABSTRACT FROM AUTHOR]