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The COVID-19 pandemic and the corresponding lockdown measures have been confirmed to reduce the air pollution in major megacities worldwide. Especially at some monitoring hotspots, NO 2 has been verified to show a significant decrease. However, the diffusion pattern of these hotspots in responding to COVID-19 is not clearly understood at present stage. Hence, we selected Beijing, a typical megacity with the strictest lockdown measures during COVID-19 period, as the studied city and attempted to discover the NO 2 diffusion process through complex network method. The improved metrics derived from the topological structure of the network were adopted to describe the performance of diffusion. Primarily, we found evidences that COVID-19 had significant effects on the spatial diffusion distribution due to combined effect of changed human activities and meteorological conditions. Besides, to further quantify the impacts of disturbance caused by different lockdown measures, we discussed the evolutionary diffusion patterns from lockdown period to recovery period. The results displayed that the difference between normal operation and pandemic operation firstly increased at the cutoff of lockdown measures but then declined after the implement of recovery measures. The source areas had greater vulnerability and lower resilience than receptors areas. Furthermore, based on the conclusion that the diffusion pattern changed during different periods, we explored the key stations on the path of diffusion process to further gain information. These findings could provide references for comprehending spatiotemporal pattern on city scale, which might be help for high-resolution air pollution mapping and prediction. [Display omitted] • Propose a complex network model to reveal NO 2 spatiotemporal diffusion on city scale. • Assess the impacts of lockdown measures in responding to COVID-19 on NO 2 diffusion pattern. • Identify significant hotpots on NO 2 diffusion through receiving, spillover and control ability. [ABSTRACT FROM AUTHOR]