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In this paper, the Photoacoustic Aerosol Absorption Spectrometer (PAAS-4 λ) is introduced. PAAS-4 λ was specifically developed for long-term monitoring tasks in (unattended) air quality stations. It uses four wavelengths coupled to a single acoustic resonator in a compact and robust set-up. The instrument has been thoroughly characterized and carefully calibrated in the laboratory using NO 2 /air mixtures and Nigrosin aerosol. It has an ultimate 1σ detection limit below 0.1 Mm -1 , at a measurement precision and accuracy of 3 % and 10 %, respectively. In order to demonstrate the PAAS-4 λ suitability for long-term monitoring tasks, the instrument is currently validated at the air quality monitoring station Pallas in Finland, about 140 km north of the Arctic circle. A total of 11 months of PAAS-4 λ data from this deployment are presented and discussed in terms of instrument performance. Intercomparisons with the filter-based photometers of a continuous soot monitoring system (COSMOS), the Multi-Angle Absorption Photometer (MAAP), and Aethalometer (AE33) demonstrate the capabilities and value of PAAS-4 λ , as well as for the validation of the widely used filter-based instruments. [ABSTRACT FROM AUTHOR]

The Pan-Eurasian Experiment (PEEX) Science Plan, released in 2015, addressed a need for a holistic system understanding and outlined the most urgent research needs for the rapidly changing Arctic-boreal region. Air quality in China, together with the long-range transport of atmospheric pollutants, was also indicated as one of the most crucial topics of the research agenda. These two geographical regions, the northern Eurasian Arctic-boreal region and China, especially the megacities in China, were identified as a "PEEX region". It is also important to recognize that the PEEX geographical region is an area where science-based policy actions would have significant impacts on the global climate. This paper summarizes results obtained during the last 5 years in the northern Eurasian region, together with recent observations of the air quality in the urban environments in China, in the context of the PEEX programme. The main regions of interest are the Russian Arctic, northern Eurasian boreal forests (Siberia) and peatlands, and the megacities in China. We frame our analysis against research themes introduced in the PEEX Science Plan in 2015. We summarize recent progress towards an enhanced holistic understanding of the land–atmosphere–ocean systems feedbacks. We conclude that although the scientific knowledge in these regions has increased, the new results are in many cases insufficient, and there are still gaps in our understanding of large-scale climate–Earth surface interactions and feedbacks. This arises from limitations in research infrastructures, especially the lack of coordinated, continuous and comprehensive in situ observations of the study region as well as integrative data analyses, hindering a comprehensive system analysis. The fast-changing environment and ecosystem changes driven by climate change, socio-economic activities like the China Silk Road Initiative, and the global trends like urbanization further complicate such analyses. We recognize new topics with an increasing importance in the near future, especially "the enhancing biological sequestration capacity of greenhouse gases into forests and soils to mitigate climate change" and the "socio-economic development to tackle air quality issues". [ABSTRACT FROM AUTHOR]

Black carbon is emitted from the incomplete combustion of carbonaceous fuels and will detrimentally affect air quality, climate and human health. In this study, equivalent black carbon (eBC) concentrations were measured by using an aethalometer (AE33) at three different locations in the Helsinki metropolitan area, Finland from October 2015 to May 2017. One sampling site was located in an urban street canyon (SC, sampling period 18 months) and two of the sampling sites were located in suburban detached house (DH) areas (DH1, 13 months and DH2, 5 months). Based on the campaign averages, the eBC concentration levels were higher at the street canyon site (1690 ± 1520 ng/m 3 ) than at the residential detached house areas (DH1 = 880 ± 1500 ng/m 3 and DH2 = 1040 ± 2130 ng/m 3 ). The contribution of eBC from fossil fuel (BC FF ) and wood burning (BC WB ) were estimated based on the spectral dependence of light absorption of different sources. The spectral behavior is described using absorption Ångström exponent (α) values for both fossil fuel (α FF ) and wood burning (α WB ) that were determined using concurrent wood burning tracer (levoglucosan) measurements. Based on the source apportionment, the contribution of BC WB to eBC was clearly higher at the detached house area sites DH1 (41 ± 14%) and DH2 (46 ± 15%) than at the urban street canyon site (15 ± 14%). A distinct seasonal dependency was observed in the eBC concentration levels at the detached house areas. The highest concentrations were detected during the cold seasons due to residential wood combustion. On the opposite, at the SC site, the concentration levels of eBC were rather constant throughout the campaign, being dominated by the BC FF emissions from close-by vehicular traffic. Substantial temporal and spatial variability in eBC concentrations and sources were observed within the Helsinki metropolitan area. eBC is shown to be closely tied to the characteristics of the measurement site, season, meteorological conditions and the time of the day. [ABSTRACT FROM AUTHOR]

Currently, only the mass of sub 2.5 μm and sub 10 μm particles (PM 2.5 , PM 10) in ambient air is regulated and monitored closely, but the same increase in PM 2.5 can cause different degrees of health effects in different cities (sometimes more harmful effects per unit mass in less polluted cities) (Li et al., 2019). In addition to mass concentration, other measurement metrics are needed to connect particle pollution data and health effects. In our measurements made in traffic-influenced environments in Helsinki, Finland (a relatively clean city), and Delhi-National Capital Region (Delhi-NCR), India (a polluted area), we noted a large difference in the median particle size for lung-deposited surface area (LDSA). In Helsinki, the median size was 80 nm, corresponding to soot particles emitted from diesel engines. However, the median size increased to 190 nm during a long-range transport event of air mass. In Delhi-NCR, surprisingly, the median size was even larger, 410 nm. These larger particles were likely to originate from regional sources rather than local traffic. The LDSA to PM 2.5 ratio for particles in Helsinki was 2–4 times the amount in Delhi-NCR, potentially linked with the higher toxicity of a unit of particulate mass in Helsinki. • LDSA particle size distributions compared between Delhi-NCR and Helsinki. • Particles contributing to LDSA were up to five times larger in Delhi-NCR. • Size differences indicate different sources and different chemical composition. • Results may explain reported discrepancies in PM 2.5 toxicity between the cities. [ABSTRACT FROM AUTHOR]