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Promoting the activity of catalyst, achieving high CO2 conversion and increasing light olefins yield are important in CO2 hydrogenation to olefin. Herein, SiO2 was doped in CuO‐ZnO‐ZrO2 to form multi‐oxides of CuO‐ZnO‐ZrO2‐SiO2 by co‐precipitation method, and the multi‐oxides was mixed with SAPO‐34 molecular sieves mechanically to form a composite catalyst of CuO‐ZnO‐ZrO2‐SiO2/SAPO‐34. Compared with CuO‐ZnO‐ZrO2, doping of SiO2 increases the dispersion and thermal stability of metal oxides, provides more sites for CO2 activated, and delays the aggregation of metal particles at higher temperature. Doped SiO2 can also adsorb the water from hydrogenation process to improve the olefins yield and hinder the formation of CO from reverse water gas shift. Thus, under the condition of reaction temperature at 420 °C, pressure of 3.0 MPa, space velocity of 1800 mL gcat−1 h−1, CO2/H2 (molar ratio) of 1 : 3 and the mass ratio of CuO‐ZnO‐ZrO2‐SiO2 (containing 8 % SiO2) to SAPO‐34 of 1 : 1, the direct CO2 hydrogenation to light olefins on CuO‐ZnO‐ZrO2‐SiO2/SAPO‐34 shows that the conversion of CO2 is 53.9 % and the selectivity of light olefins is 52.9 %, while the CO selectivity is only 13.6 %. [ABSTRACT FROM AUTHOR]

Propane dehydrogenation to propene is an endothermic reaction and CO2 hydrogenation to light olefins is an exothermic reaction. Using the CO2 hydrogenation reaction to consume the hydrogen from the propane dehydrogenation reaction, which is more favorable to propylene formation. A new method for coupling propane and CO2 to propylene is presented. The V–Fe modified KIT-6 was prepared by the ultrasonic-assisted impregnation method and used for coupling reaction of propane with CO2 to propylene. Exploring the relationship between catalytic properties and physicochemical characteristics through several characterization methods. As the appropriate amounts of V and Fe species were introduced into the framework of KIT-6, V–Fe modified KIT-6 performed large specific surface area, a highly ordered mesoporous structure and highly dispersed V and Fe active sites. The catalysis performance of V–Fe modified KIT-6 zeolites for production of propylene by propane dehydrogenation, CO2 hydrogenation and coupling reaction of C3H8 with CO2 was compared. Under the conditions of C3H8/CO2/N2 = 1:4:5, total flow rate = 20 mL/min, the temperature at 580 °C, the reaction pressure at 0.1 MPa, V/Fe molar ratio = 2 and the catalyst mass of 0.2 g, the propane conversion, propylene selectivity and yield are 37.8%, 87.0% and 32.9%, respectively. [ABSTRACT FROM AUTHOR]

To understand the relationship between the catalytic performance, crystallite size, and acidity of SAPO-34 zeolites better, a series of SAPO-34 zeolites were prepared by hydrothermal crystallization using palygorskite as silicon and partial aluminum source, and selecting two kinds of triethylamine, morpholine and tetraethylammonium hydroxide as dual templates. The obtained SAPO-34 zeolites were characterized via the methods of XRD, SEM, N2-adsorption–desorption, NH3-TPD, FTIR, XRF, 29Si MAS NMR, 27Al MAS NMR and TG. The properties of the templates affected the crystal growth rate that triethylamine and morpholine can cause a larger crystallite size while tetraethylammonium hydroxide can form small crystallite size particles. The number of acid sites of SAPO-34 zeolites first decreased and then increased with the increase of morpholine. The formation of Si islands can enhance the number of acid sites of SAPO-34 zeolites. The catalytic performance of SAPO-34 zeolites in methanol-to-olefins (MTO) reaction was investigated in a fixed bed reactor. Under reaction conditions, when the reaction temperature was 400 °C, the feed WHSV was 2.0 h−1, the mass of the catalyst was 0.5 g, at atmospheric pressure, the sample with an amount of acid sites of 0.85 mmol g−1 and crystallite size of 0.84 μm exhibited the optimum catalytic performance with methanol conversion at 100%, light olefin selectivity at 97.15% and catalytic lifetime at more than 1050 min. [ABSTRACT FROM AUTHOR]

The dehydrogenation of propane to propylene is endothermic reaction will generate hydrogen, while the hydrogenation of CO2 to light olefins is exothermic reaction with hydrogen as reactant. Using the CO2 hydrogenation reaction to consume the hydrogen from the propane dehydrogenation reaction, which is more beneficial to propylene generation. Thus, a promising approach of coupling propane with CO2 to produce propylene was proposed. A simple wetness impregnation method was used to prepare the In/HZSM‐5 composite catalyst for this coupling reaction. It was characterized by means of XRD, SEM, TEM, H2‐TPR, NH3‐TPD, XPS, TG, and N2 isothermal adsorption‐desorption. Effects of indium loading, feed volume ratio of propane to CO2, reaction pressure and temperature on the coupling of propane with CO2 to propylene were investigated in a fixed‐bed reactor. When the mass content of indium is 12%, the feeding volume ratio of propane to CO2 is 1 : 4, the reaction pressure is 0.3 MPa and the reaction temperature is 580 °C, the propylene selectivity is 71.41%, as well as the conversion per pass of propane and CO2 is 17.74% and 5.08%, respectively. [ABSTRACT FROM AUTHOR]

Abstract: The role of various carboxylic acids (substituted/unsubstituted acetic, benzoic and salicylic acids) with various electron donating and/or withdrawing substituents on the Na2WO4/H2WO4-catalysed, biphasic epoxidations of cyclooctene and 1-octene, using H2O2 as terminal oxidant has been investigated. The presence of the different acids in catalytic amounts widely affects the catalytic activity of the above system depending on the nature of their substituents. The results obtained have been discussed in the light of the stereo/electronic effects of these substituents. It has been observed that the added substituted/unsubstituted acetic and benzoic acids generally enhance the rate of the epoxidation while salicylic acids significantly decrease the catalyst activity, under the same conditions, most likely due to the additional deactivating hydroxy moiety. [Copyright &y& Elsevier]