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Start Over Author "Tian, Si-Wei" Topic alkylation
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1. K2S2O8‐Mediated Radical Cascade Alkylation/Cyclization of Ynones: Access to Oxoalkyl‐Substituted Indenones.

Author

Tian, Si‐Wei, Xiong, Fang‐Ting, Xiong, Bi‐Quan, Zhong, Long‐Jin, Tang, Ke‐Wen, and Liu, Yu

Subjects
*RADICALS (Chemistry), *ALKYLATION, *RING formation (Chemistry), *ANNULATION, *ORGANIC chemistry, *KETONE derivatives, *ARYLATION
Abstract

A simple and efficient oxidative‐promoted radical cascade annulation of ynone derivatives with ketones for the construction of a series of oxoalkyl‐substituted indenones in moderate to good yields is described. The control experiment results indicate that the oxidative acetmethylation/arylation of ynone derivatives involves a radical cascade cyclization process. This is an operationally simple and efficient protocol which will be attractive in organic synthesis chemistry. [ABSTRACT FROM AUTHOR]

Published
2023
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