1. Bis(isonicotinamide-κN)silver(I) trifluoromethanesulfonate acetonitrile disolvate
- Author
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Hadi D. Arman, Rafael A. Adrian, and Sara J. Ibarra
- Subjects
crystal structure ,Crystallography ,Nitrile ,isonicotinamide ,Ligand ,Hydrogen bond ,Methane sulfonate ,Medicinal chemistry ,acetonitrile ,chemistry.chemical_compound ,silver atom ,chemistry ,trifluoromethanesulfonate ions ,polymeric structure ,QD901-999 ,Amide ,Pyridine ,Isonicotinamide ,Acetonitrile - Abstract
The central AgI atom of the title salt, [Ag(INAM)2](CF3SO3)·2CH3CN, where INAM is isonicotinamide (C6H6N2O), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear molecular geometry. The formation of polymeric chains {[Ag(INAM)2]+} n , held together by discrete hydrogen bonds through the amide group of the INAM ligand leaves voids for non-coordinating acetonitrile molecules that interact the silver metal center via regium bonds.
- Published
- 2021