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Start Over Author "Moumne, Roba" Topic amino acids
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1. Efficient synthesis of beta2-amino acid by homologation of alpha-amino acids involving the Reformatsky reaction and Mannich-type imminium electrophile.

Author

Moumne R, Lavielle S, and Karoyan P

Subjects
Amination, Bromine chemistry, Esters chemical synthesis, Esters chemistry, Fluoroacetates chemistry, Mannich Bases chemistry, Methylation, Molecular Structure, Stereoisomerism, Amino Acids chemical synthesis, Amino Acids chemistry, Electrons, Quaternary Ammonium Compounds chemistry
Abstract

Development of new methods for the synthesis of beta-amino acids is important as polymers of these compounds are promising peptidomimetic candidates in medicinal chemistry. We report here our findings on a new and highly efficient general strategy for the synthesis of beta2-amino acids by homologation of alpha-amino acids, involving the Reformatsky reaction and Mannich-type imminium electrophile.

Published
2006
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