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1. Solvothermal synthesis and characterization of a new ZnII-PMIDA phosphonate.

Author

Kui-Rong, Ma, Yu-Lan, Zhu, and Qi-Fan, Yin

Subjects
PHOSPHONATES, X-ray diffraction, ANIONS, HYDROGEN bonding, METAL ions, PHOSPHONIC acids
Abstract

A new Zn(II) phosphonate, (NH4)[Zn(HPMIDA)(H2O)2] (1) (H4PMIDA = N-(phosphonomethyl)iminodiacetic acid), has been solvothermally synthesized and characterized by elemental analysis, IR, TGA fluorescence, and X-ray single-crystal diffraction. Compound 1 is an example of a six-coordinate Zn-carboxylate-phosphonate and possesses a 3-D supramolecular structure built from mononuclear anions [image omitted] through hydrogen bonding. Compound 1 exhibits a solid-state fluorescent emission band at 593 nm under excitation of 413 nm. [ABSTRACT FROM AUTHOR]

Published
2009
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