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1. {Mo24Fe12} Macrocycles: Anion Templation with Large Polyoxometalate Guests.

Author

Fang, Xikui, Hansen, Laura, Haso, Fadi, Yin, Panchao, Pandey, Abhishek, Engelhardt, Larry, Slowing, Igor, Li, Tao, Liu, Tianbo, Luban, Marshall, and Johnston, David C.

Subjects
MACROCYCLIC compounds, POLYOXOMETALATES, COORDINATION compounds, HYDROGEN bonding, ANIONS, CHEMICAL research
Abstract

POM and circumstance: Nanometer‐sized polyoxometalates (POMs) bring a new direction to anion‐templated supramolecular chemistry. The Keggin (left) and Dawson‐type (right) polyoxoanions direct the assembly of giant metallomacrocycles through an array of weak hydrogen‐bonding interactions. The concerted action of multiple hydrogen bonds keeps the templating guests embedded within the hosts, even in the solution state. [ABSTRACT FROM AUTHOR]

Published
2013
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