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By replacing absolute ethanol, water was used as a ubiquitous and low-cost solvent to dissolve metal nitrates and organic additives to obtain a precursor solution that showed long-term stability and reproducibility. This precursor solution was used to deposit a CuMn 2 O 4 ceramic film on a stainless steel substrate using the convenient and inexpensive sol-gel dip-coating technique. The X-ray diffraction (XRD) profile of the ceramic film annealed for 1 h at 450 °C was found to coincide with that of crystalline CuMn 2 O 4 in the JCPDS database. The CuMn 2 O 4 ceramic film obtained at an annealing temperature of 500 °C exhibited excellent solar absorptance ( α s =0.905) and thermal emittance ( ε 100 =0.120). By optimizing the deposition parameters, we systematically investigated the effect of the chemical components, surface texture, and thickness of the ceramic film on its optical properties. Subjected to a thermal stability test at 252 °C, the CuMn 2 O 4 ceramic film showed good thermal stability with performance criterion (PC) values below 0.05. [ABSTRACT FROM AUTHOR]

Spinel Cu 1.5 Mn 1.5 O 4 thin films were fabricated by one step sol-gel dip-coating method using aqueous solution. The effect of deposition parameters on thickness, surface feature, and optical property of thin films was systematically studied. The results revealed that the increased withdrawal speeds and high concentration of metal ions in precursor were conducive to obtaining thicker films which exhibited excellent solar absorptance. Furthermore, the surface feature derived from the different concentrations of metal ions had a significant effect on optical behavior of the thin film. Consequently, excellent spectral selectivity of the thin film would be achieved by tuning those deposition parameters. [ABSTRACT FROM AUTHOR]