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Groundwater in several parts of the world, particularly in developing countries, has been contaminated with Arsenic (As). In search of low-cost As removal methods, the biological oxidation of As(III) and Fe(II) followed by co-precipitation requires detailed investigation for the practical implementation of this technology. The present study investigated the biological oxidation of As(III) and Fe(II) through a combination of laboratory experiments and reactive transport modeling. Batch experiments were conducted to evaluate the As(III) oxidation by Fe-oxidizing bacteria, mainly Leptothrix spp. A fixed-bed down-flow biological column containing inexpensive and readily available coconut husk support media was used to evaluate the combined removal of As(III) and Fe(II) from synthetic groundwater. Oxidation and co-precipitation processes effectively reduced the concentration of As(III) from 500 μg/L to < 10 μg/L with a hydraulic retention time of 120 min. A one-dimensional reactive transport model was developed based on the microbially mediated biochemical reactions of As(III) and Fe(II). The model successfully reproduced the observed As(III) and Fe(II) removal trends in the column experiments. The modeling results showed that the top 20 cm aerobic layer of the column played a primary role in the microbial oxidation of Fe(II) and As(III). The model calibration identified the hydraulic residence time as the most significant process parameter for the removal of Fe and As in the column. The developed model can effectively predict As concentrations in the effluent and provide design guidelines for the biological treatment of As. The model would also be useful for understanding the biogeochemical behavior of Fe and As under aerobic conditions. Image 1 • Oxidation and co-precipitation of As(III) and Fe(II) by iron oxidizing bacteria. • Efficient removal (>98%) of As(III) and Fe(II) achieved in biological column. • A reactive transport model successfully simulated the biological As(III) removals. • As(III) and Fe(II) oxidation was mediated in BioPhase. • Metabolic products, i.e., Fe(OH) 3 and As(V), co-precipitated in the matrix phase. Biological column containing coconut husk media is able to remove As(III) to below 10 μg/L through biological oxidation and co-precipitation process. The reactive transport model successfully reproduced the observed As(III) and Fe(II) removal trends of the column experiments. [ABSTRACT FROM AUTHOR]

The ceramic filter amended with iron (Fe) has proven to be a potential low‐cost method for arsenic (As) removal from groundwater. The presence of Fe, phosphate (P), and silicate (Si) significantly affects the As removal efficiency of the ceramic filter, which has not been passably investigated. The present research aimed to examine the effect of Fe, P, and (or) Si presence as single or in combination on As (III) removal from synthetics groundwater by a low‐cost iron amended ceramic filter (IACF). Laboratory‐scale filtration experiments at different compositions of Fe, P, Si, and As (III) were conducted by the IACF fabricated with a ceramic candle and iron netting box. Fe (II) in synthetic groundwater positively impacted As (III) removal. At a concentration of 2 mg/L of Fe (II), the As levels in the effluent decreased to less than the maximum contamination level (MCL) of 50 μg/L. Groundwater P concentration needed less than 3 mg/L or Si concentrations required less than 35 mg/L to effectively reduce As (III) to below the MCL at 5 mg/L of groundwater Fe (II). The cumulative effect of P and Si on As removal was found to be more significant than distinct contributions. The presence of 2 mg/L P and 35 mg/L or higher Si in the groundwater cumulatively reduced the As removal performance from 92% to 63%, and the MCL was not met. The negative impact of P and Si on As (III) removal followed the order of (P + Si) > P > Si. P competed with As for adsorption sites during the process, while Si inhibited the Fe release and floc formation, significantly reducing As removal performance. The study findings can potentially contribute to optimizing IACF as a low‐cost method for As removal from groundwater. [ABSTRACT FROM AUTHOR]