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Start Over Author "Fukuoka, Asuka" Topic aryl group
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1. Nickel-Catalyzed Dimerization and Alkylarylation of 1,3-Dienes with Alkyl Fluorides and Aryl Grignard Reagents.

Author

Iwasaki, Takanori, Min, Xin, Fukuoka, Asuka, Kuniyasu, Hitoshi, and Kambe, Nobuaki

Subjects
ALKYL fluorides, DIMERIZATION, NICKEL catalysts, GRIGNARD reagents, ARYL group
Abstract

In the presence of a nickel catalyst, 1,3-butadiene undergoes selective dimerization and alkylarylation with alkyl fluorides and aryl Grignard reagents to give 1,6-octadienes with alkyl and aryl groups at the 3- and 8-positions, respectively, by the consecutive formation of three carbon-carbon bonds. The formation of an anionic nickel complex plays an important role in forming Cāˆ’C bonds with alkyl fluorides. [ABSTRACT FROM AUTHOR]

Published
2016
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