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1. Highly active and selective catalysts for the formation of alpha-aryl ketones.

Author

Fox, Joseph M. and Xiaohua Huang

Subjects
*CATALYSTS, *LIGANDS (Chemistry), *KETONES, *ARYLATION, *REACTIVITY (Chemistry), *BIOSYNTHESIS
Abstract

Investigates the utility of electron-rich phosphine ligands as catalysts for the alpha-arylation of ketones. Effectivity of ligands to catalyze the reaction of ketones with aryl chlorides and aryl bromides; Effectivity of ligands BINAP and Xantphos compared to biphenyl-based ligands.

Published
2000
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