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Highlights • Spectral parameters of the Ceres's Occator quadrangle are mapped. • Band depths of hydrated and ammoniated materials correlate. • The Occator crater includes two bright, carbonate-rich faculae. • The two spectral types of Occator ejecta probably have a different history. • Spectral variations of tali suggest a different physical state. Abstract We present an analysis of the areal distribution of spectral parameters derived from the VIR imaging spectrometer on board NASA/Dawn spacecraft. Specifically we studied the Occator quadrangle of Ceres, which is bounded by latitudes 22°S to 22°N and longitudes 214°E to 288°E, as part of the overall study of Ceres' surface composition reported in this special publication. The spectral parameters used are the photometrically corrected reflectance at 1.2 µm, the infrared spectral slope (1.1–1.9 µm), and depths of the absorption bands at 2.7 µm and 3.1 µm that are ascribed to hydrated and ammoniated materials, respectively. We find an overall correlation between 2.7 µm and 3.1 µm band depths, in agreement with Ceres global behavior, and band depths are shallower and the spectral slope is flatter for younger craters, probably due to physical properties of regolith such as grain size. Spectral variations correlated with the tali geological unit also suggest differences in physical properties. The deepest band, indicating enrichment of ammoniated phyllosilicates, are associated with ejecta generated by impacts that occurred in southern quadrangles. The most peculiar region of this quadrangle is the Occator crater (20°N 240°E). The internal crater area contains two faculae, which are the brightest areas on Ceres due to exposure of sodium carbonates, and by two types of ejecta, dark and bright, with different spectral properties, probably due to different formation, evolution or age. [ABSTRACT FROM AUTHOR]

NASA's Dawn mission was launched in September 2007 and orbited asteroids Vesta (2011−2012) and Ceres (2015–2018). Vesta shows surface dark units that have been suggested to be linked to exogenous materials and are therefore useful to understand the initial stages of the Solar System. This work takes advantage of the newly calibrated data of the VIR spectrometer, which are characterized by a better signal to noise (S/N) ratio, giving us the opportunity to search for spectral features that were never seen before due to noise. Considering that hydroxyl has been shown to be present in every dark unit on Vesta and also in carbonaceous chondrites, the goals of this work are the search for and characterization of carbonates that are present in carbonaceous chondrites, i.e., the supposed darkening agents of Vesta. The estimate of the abundances of carbonates is fundamental to identify which carbonaceous chondrite fell on Vesta; this can be crucial for the definition of an evolutionary history of Vesta and the Solar System. The study of a possible feature at 3.9 μm related to the presence of carbonates was analyzed and found to be noise-induced. Although spectral features related to carbonates were not observed, the 3.4 μm absorption band was analyzed anyway in order to fix an upper limit to the abundance of carbonates in carbonaceous chondrites on Vesta. This value is consistent with petrochemical analyses, i.e., no more than 0.2% of carbonates in carbonaceous chondrites. • Study of newly calibrated Dawn VIR data of Vesta. • Search for carbonates signatureon Vesta surface. • Identification of the 3.9 μm feature as related to noise level. • Definition of an upper limitto the abundance of carbonatespresent on Vesta. [ABSTRACT FROM AUTHOR]

Highlights • A photometric empirical model was applied to Ceres visible and NIR spectra. • Ceres behaves photometrically as a C-type asteroid even at large phase angles. • Similar steepness of bright Occator faculae and Ceres average's phase functions. • Larger 2.7 µm phase deepening and no phase reddening on Occator faculae. • Composition and roughness can explain the Occator's photometry. Abstract Spectral parameters of Ceres measured by the Dawn/VIR imaging spectrometer are studied as a function of illumination angles, by applying a semi-empirical method based on a statistical analysis of the VIR dataset acquired up to September 2016. The study also focuses on the photometry of the Occator faculae, i.e. the brightest spots of the Ceres surface, showing an albedo up to eight times the Ceres average. The considered semi-empirical approach takes into account the small extension (and hence small dataset) of this region and lays the groundwork to apply scattering models even on such a limited area. The behavior of Ceres visible and infrared reflectance with phase angle is similar to other asteroids belonging to its same spectral class, i.e. C-type. The depth of the bands at 2.7 µm (phyllosilicates), 3.1 µm (ammonium), 3.4 µm (magnesium carbonates) and the infrared spectral slope linearly increase with phase angle, showing analogies with other asteroids and occurrence of phase reddening. The different behavior of the 3.9 µm band depth (also due to Mg carbonates), independent of illumination angles, could indicate that other carriers contribute to the 3.4 µm band and play a more important role in photometry outside the carbonate deposits. The phase function of the Occator faculae is much steeper than expected from its high albedo. Mixture of bright and dark material and larger roughness can be at the basis of this result. The phyllosilicate bands show a steeper increase with phase angle with respect to the Ceres average, due to the lower presence of dark materials, and/or again larger roughness. The absence of trends with phase angles of the two carbonate bands and of the spectral slope suggests that carbonates do not produce phase reddening. [ABSTRACT FROM AUTHOR]

Highlights • Spectral parameters of Urvara and Yalode quadrangles are mapped. • Band depths at 2.7 and 3.1 µm are shallower than western latitudes. • Correlation between geology and mineralogy arises only in the Yalode quadrangle. • The central peak of Urvara crater is enriched in ammonium. • Hummocky crater floors are darker because of their different roughness. Abstract We studied the distribution in the Urvara–Yalode region of Ceres (latitudes 21–66°S, longitudes 180–360°E) of main spectral parameters derived from the VIR imaging spectrometer onboard the NASA/Dawn spacecraft, as an overall study of Ceres mineralogy reported in this special issue. In particular, we analyzed the distribution of reflectance at 1.2 µm, band depth at 2.7 and 3.1 µm, ascribed to magnesium and ammoniated phyllosilicates, respectively. Whereas the average band depths of this region are lower than eastern longitudes, reflecting the E-W dichotomy of abundance of phyllosilicates on Ceres, spectral variations inside this region are observed in the following units: (a) the central peak of the Urvara crater (45.9°S, 249.2°E, 170 km in diameter), showing a deep 3.1 µm band depth, indicating an ammonium enrichment; (b) the cratered terrain westwards of the Yalode basin (42.3°S, 293.6°E, 260 km in diameter), where absorption bands are deeper, probably due to absence of phyllosilicates depletion following the Yalode impact; (c) the hummocky cratered floor of Yalode and Besua (42.4°S, 300.2°E) craters, characterized by lower albedo and band depths, probably due to different roughness; (d) Consus (21°S 200°E) and Tawals (39.1°S, 238°E) craters, whose albedo and band depths decreasing could be associated to different grain size or abundance of dark materials. Twenty-two small scale (i.e., lower than 400 m) bright spots are observed: because their composition is similar to the Ceres average, a strong mixing may have occurred since their formation. [ABSTRACT FROM AUTHOR]

Highlights • Local composition varies within Fejokoo quadrangle associated with 20–30-km craters. • Spectral maps show stratigraphic differences in phyllosilicate and carbonate minerals. • Presence of carbonates is associated with bright material surrounding craters. Abstract This paper focuses on the identification and distribution of compositional units and their stratigraphic relationships in the Fejokoo quadrangle of Ceres (Ac-5) located between 21–66°N and 270–360°E and named after one of its prominent and well-preserved impact craters, Fejokoo (centered at 26°N and 312°E). In this quadrangle, we observed that hydroxylated- (OH-rich) and ammoniated- (NH 4 -rich) phyllosilicates are present everywhere, in various abundances; low abundance is observed on bright terrains and higher abundances are observed on lobate materials associated with craters. Carbonates are mostly correlated with the high-albedo areas surrounding Oxo (359.7°E, 42.2°N) and other major craters, and are mixed with Ceres' most common surface composition type (i.e. low albedo, phyllosilicate-rich material). There are a few locations where carbonates and phyllosilicates co-exist, indicating a range of geological or chemical processes produced them in co-existence. No correlation between the surface composition and the age of the craters was found. Instead, the composition observed on impact craters depends on the size of the impact and the composition of the different stratigraphic layers excavated. The compositional interpretation inferred from Dawn's visible-infrared spectrometer data of the Fejokoo quadrangle is consistent with the presence of an internal ocean that produced carbonates and phyllosilicates via aqueous alteration of minerals. [ABSTRACT FROM AUTHOR]