Search

Binaries are known to play a key role in the mass loss and dynamical environments of evolved stars. Stellar and substellar companion interactions produce complex wind morphologies including rotating/expanding disks, bipolar outflows, and spiral wind patterns; however, the connection between these many structures and the gas-phase chemistry they harbor is not well constrained. To expand the sample of chemical inventories in interacting systems, we present a detailed spectroscopic case study of the binary C-rich asymptotic giant branch (AGB) star V Hya. Using spatially resolved Atacama Large Millimeter/submillimeter Array observations at Bands 3, 6, and 7, we characterize the rotational emission lines and distributions of molecules in its surrounding disk undergoing dynamical expansion (DUDE). We detect emission from over 15 molecules and isotopologues toward this source, and present resolved maps for the brightest tracers of carbonaceous chemistry (e.g., CCH, C4H, HC5N, HNC, and CH 3 CN ). Employing LTE and non-LTE models of emission from the DUDE, we estimate the abundance distributions for optically thin species, and compare them with prototypical carbon-rich AGB envelopes. We find that the average abundances of detected species are within a factor of ∼5 from sources with similar mass-loss rates; however, the distribution of daughter species in V Hya is much more compact, with carbon chain species (CCH, C4H, and HC3N) appearing with abundances >10−7 even in the innermost sampled regions (200 au) of the disk. [ABSTRACT FROM AUTHOR]

Context. A lower-than-solar elemental nitrogen content has been demonstrated for several comets, including 1P/Halley and 67P/Churyumov-Gerasimenko (67P/C-G) with independent in situ measurements of volatile and refractory budgets. The recently discovered semi-refractory ammonium salts in 67P/C-G are thought to be the missing nitrogen reservoir in comets. Aims. The thermal desorption of ammonium salts from cometary dust particles leads to their decomposition into ammonia (NH3) and a corresponding acid. The NH3/H2O ratio is expected to increase with decreasing heliocentric distance with evidence for this in near-infrared observations. NH3 has been claimed to be more extended than expected for a nuclear source. Here, the aim is to constrain the NH3/H2O ratio in comet C/2020 F3 (NEOWISE) during its July 2020 passage. Methods. OH emission from comet C/2020 F3 (NEOWISE) was monitored for 2 months with the Nançay Radio Telescope (NRT) and observed from the Green Bank Telescope (GBT) on 24 July and 11 August 2020. Contemporaneously with the 24 July 2020 OH observations, the NH3 hyperfine lines were targeted with GBT. From the data, the OH and NH3 production rates were derived directly, and the H2O production rate was derived indirectly from the OH. Results. The concurrent GBT and NRT observations allowed the OH quenching radius to be determined at (5.96 ± 0.10) × 104 km on 24 July 2020, which is important for accurately deriving Q(OH). C/2020 F3 (NEOWISE) was a highly active comet with Q(H2O) ≈ 2 × 1030 mol s−1 one day before perihelion. The 3σ upper limit for QNH3 / QH2O is < 0.29% at 0.7 au from the Sun. Conclusions. The obtained NH3/H2O ratio is a factor of a few lower than measurements for other comets at such heliocentric distances. The abundance of NH3 may vary strongly with time depending on the amount of water-poor dust in the coma. Lifted dust can be heated, fragmented, and super-heated; whereby, ammonium salts, if present, can rapidly thermally disintegrate and modify the NH3/H2O ratio. [ABSTRACT FROM AUTHOR]

Amide molecules produced in space could play a key role in the formation of biomolecules on a young planetary object. However, the formation and chemical network of amide molecules in space is not well understood. In this work, Atacama Large Millimeter/submillimeter Array observations are used to study a number of amide(-like) molecules toward the high-mass star-forming region NGC 6334I. The first detections of cyanamide (NH2CN), acetamide (CH3C(O)NH2), and N-methylformamide (CH3NHCHO) are presented for this source. These are combined with analyses of isocyanic acid (HNCO) and formamide (NH2CHO), and a tentative detection of urea (carbamide; NH2C(O)NH2). Abundance correlations show that most amides are likely formed in related reactions occurring in ices on interstellar dust grains in NGC 6334I. However, in an expanded sample of sources, large abundance variations are seen for NH2CN that seem to depend on the source type, which suggests that the physical conditions within the source heavily influence the production of this species. The rich amide inventory of NGC 6334I strengthens the case that interstellar molecules can contribute to the emergence of biomolecules on planets. [ABSTRACT FROM AUTHOR]

We report a search for the diatomic hydrides SiH, PH, and FeH along the line of sight toward the chemically rich circumstellar envelopes of IRC+10216 and VY Canis Majoris. These molecules are thought to form in high-temperature regions near the photospheres of those stars, and may then further react via gas-phase and dust-grain interactions leading to more complex species, but have yet to be constrained by observation. We used the German Receiver for Astronomy at Terahertz Frequencies spectrometer on the Stratospheric Observatory for Infrared Astronomy to search for rotational emission lines of these molecules in four spectral windows ranging from 600 to 1500 GHz. Although none of the targeted species was detected in our search, we report their upper limit abundances in each source and discuss how they influence the current understanding of hydride chemistry in dense circumstellar media. We attribute the nondetections of these hydrides to their compact source sizes, high barriers of formation, and proclivity to react with other molecules in the winds. [ABSTRACT FROM AUTHOR]

Bell et al. reported the first detection of the cyanopolyyne HC11N towards the cold dark cloud TMC-1; no subsequent detections have been reported towards any source. Additional observations of cyanopolyynes and other carbon-chain molecules towards TMC-1 have shown a log-linear trend between molecule size and column density, and in an effort to further explore the underlying chemical processes driving this trend, we have analysed Green Bank Telescope observations of HC9N and HC11N towards TMC-1. Although we find an HC9N column density consistent with previous values, HC11N is not detected and we derive an upper limit column density significantly below that reported in Bell et al. Using a state-of-the-art chemical model, we have investigated possible explanations of non-linearity in the column density trend. Despite updating the chemical model to better account for ion-dipole interactions, we are not able to explain the non-detection of HC11N, and we interpret this as evidence of previously unknown carbon-chain chemistry. We propose that cyclization reactions may be responsible for the depleted HC11N abundance, and that products of these cyclization reactions should be investigated as candidate interstellar molecules. [ABSTRACT FROM AUTHOR]

We present a 30-50 GHz survey of Sagittarius B2(N) conducted with the Australia Telescope Compact Array with ~5-10 arcsec resolution. This work releases the survey data and demonstrates the utility of scripts that perform automated spectral line fitting on broad-band line data. We describe the line-fitting procedure, evaluate the performance of the method, and provide access to all data and scripts. The scripts are used to characterize the spectra at the positions of three H II regions, each with recombination line emission and molecular line absorption. Towards the most line-dense of the three regions characterized in this work, we detect ~500 spectral line components of which ~90 percent are confidently assigned to H and He recombination lines and to 53 molecular species and their isotopologues. The data reveal extremely sub-thermally excited molecular gas absorbing against the continuum background at two primary velocity components. Based on the line radiation over the full spectra, the molecular abundances and line excitation in the absorbing components appear to vary substantially towards the different positions, possibly indicating that the two gas clouds are located proximate to the star-forming cores instead of within the envelope of Sgr B2. Furthermore, the spatial distributions of species including CS, OCS, SiO, and HNCO indicate that the absorbing gas components likely have high UV-flux. Finally, the data contain line-of-sight absorption by ~15 molecules observed in translucent gas in the Galactic Centre, bar, and intervening spiral arm clouds, revealing the complex chemistry and clumpy structure of this gas. Formamide (NH2CHO) is detected for the first time in a translucent cloud. [ABSTRACT FROM AUTHOR]

The results of a Caltech Submillimeter Observatory (CSO) search for l-C3H+, first detected by Pety et al. in observations towards the Horsehead photodissociation region (PDR), are presented. A total of 39 sources were observed in the 1 mm window. Evidence of emission from l-C3H+ is found in only a single source – the Orion Bar PDR region – which shows a rotational temperature of 178(13) K and a column density of 7(2) × 1011 cm−2. In the remaining sources, upper limits of ∼1011–1013 cm−2 are found. These results are discussed in the context of guiding future observational searches for this species. [ABSTRACT FROM PUBLISHER]

Pety et al. have reported the detection of eight transitions of a closed-shell, linear molecule (B11244) in observations toward the Horsehead photodissociation region (PDR), which they attribute to the l-C3H+ cation. Recent high-level ab initio calculations have called this assignment into question; the anionic C3H– molecule has been suggested as a more likely candidate. Here, we examine observations of the Horsehead PDR, Sgr B2(N), TMC-1, and IRC+10216 in the context of both l-C3H+ and C3H–. We find no observational evidence of Ka = 1 lines, which should be present were the carrier indeed C3H–. Additionally, we find a strong anticorrelation between the presence of known molecular anions and B11244 in these regions. Finally, we discuss the formation and destruction chemistry of C3H– in the context of the physical conditions in the regions. Based on these results, we conclude there is little evidence to support the claim that the carrier is C3H–. [ABSTRACT FROM AUTHOR]

Pety et al. recently reported the detection of several transitions of an unknown carrier in the Horsehead PDR and attribute them to l-C3H+. Here, we have tested the predictive power of their fit by searching for, and identifying, the previously unobserved J = 1-0 and J = 2-1 transitions of the unknown carrier (B11244) toward Sgr B2(N) in data from the publicly available PRIMOS project. Also presented here are observations of the J = 6-5 and J = 7-6 transitions toward Sgr B2(N) and Sgr B2(OH) using the Barry E. Turner Legacy Survey and results from the Kaifu et al. survey of TMC-1. We calculate an excitation temperature and column density of B11244 of ~10 K and ~1013 cm-2 in Sgr B2(N) and ~79 K with an upper limit of ⩽1.5 × 1013 cm-2 in Sgr B2(OH) and find trace evidence for the cation's presence in TMC-1. Finally, we present spectra of the neutral species in both Sgr B2(N) and TMC-1, and comment on the robustness of the assignment of the detected signals to l-C3H+. [ABSTRACT FROM AUTHOR]

In this paper, we present the results of an observational search for gas phase urea [(NH2)2CO] observed toward the Sgr B2(N-LMH) region. We show data covering urea transitions from ∼100 GHz to 250 GHz from five different observational facilities: the Berkeley-Illinois-Maryland-Association (BIMA) Array, the Combined Array for Research in Millimeter-wave Astronomy (CARMA), the NRAO 12 m telescope, the IRAM 30 m telescope, and the Swedish-ESO Submillimeter Telescope (SEST). The results show that the features ascribed to urea can be reproduced across the entire observed bandwidth and all facilities by best-fit column density, temperature, and source size parameters which vary by less than a factor of two between observations merely by adjusting for telescope-specific parameters. Interferometric observations show that the emission arising from these transitions is cospatial and compact, consistent with the derived source sizes and emission from a single species. Despite this evidence, the spectral complexity of both (NH2)2CO and of Sgr B2(N) makes the definitive identification of this molecule challenging. We present observational spectra, laboratory data, and models, and discuss our results in the context of a possible molecular detection of urea. [ABSTRACT FROM AUTHOR]

The rotational spectrum of the higher-energy trans-conformational isomer of methyl formate has been assigned for the first time using several pulsed-jet Fourier transform microwave spectrometers in the 6-60 GHz frequency range. This species has also been sought toward the Sagittarius B2(N) molecular cloud using the publicly available PRIMOS survey from the Green Bank Telescope. We detect seven absorption features in the survey that coincide with laboratory transitions of trans-methyl formate, from which we derive a column density of 3.1 (+2.6, –1.2) × 1013 cm–2 and a rotational temperature of 7.6 ± 1.5 K. This excitation temperature is significantly lower than that of the more stable cis conformer in the same source but is consistent with that of other complex molecular species recently detected in Sgr B2(N). The difference in the rotational temperatures of the two conformers suggests that they have different spatial distributions in this source. As the abundance of trans-methyl formate is far higher than would be expected if the cis and trans conformers are in thermodynamic equilibrium, processes that could preferentially form trans-methyl formate in this region are discussed. We also discuss measurements that could be performed to make this detection more certain. This manuscript demonstrates how publicly available broadband radio astronomical surveys of chemically rich molecular clouds can be used in conjunction with laboratory rotational spectroscopy to search for new molecules in the interstellar medium. [ABSTRACT FROM AUTHOR]

Observations of 14 rotational transitions of hydroxylamine (NH2OH) using the NRAO 12 m telescope on Kitt Peak are reported toward IRC+10216, Orion KL, Orion S, Sgr B2(N), Sgr B2(OH), W3IRS5, and W51M. Although recent models suggest the presence of NH2OH in high abundance, these observations resulted in non-detection. Upper limits are calculated to be as much as six orders of magnitude lower than those predicted by models. Possible explanations for the lower-than-expected abundance are explored. [ABSTRACT FROM AUTHOR]