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The formation and evolution pathway for the directly imaged multiplanetary system HR 8799 remains mysterious. Accurate constraints on the chemical composition of the planetary atmosphere(s) are key to solving the mystery. We perform a detailed atmospheric retrieval on HR 8799 c to infer the chemical abundances and abundance ratios using a combination of photometric data along with low- and high-resolution spectroscopic data (R ∼ 20-35,000). We specifically retrieve [C/H], [O/H], and C/O and find them to be 0.55 − 0.39 + 0.36 , 0.47 − 0.32 + 0.31 , and 0.67 − 0.15 + 0.12 at 68% confidence. The superstellar C and O abundances, yet a stellar C/O ratio, reveal a potential formation pathway for HR 8799 c. Planet c, and likely the other gas giant planets in the system, formed early on (likely within ∼1 Myr), followed by further atmospheric enrichment in C and O through the accretion of solids beyond the CO ice line. The enrichment either preceded or took place during the early phase of the inward migration to the current planet locations.

Direct imaging studies have mainly used low-resolution spectroscopy (R ∼ 20-100) to study the atmospheres of giant exoplanets and brown dwarf companions, but the presence of clouds has often led to degeneracies in the retrieved atmospheric abundances (e.g., carbon-to-oxygen ratio, metallicity). This precludes clear insights into the formation mechanisms of these companions. The Keck Planet Imager and Characterizer (KPIC) uses adaptive optics and single-mode fibers to transport light into NIRSPEC (R ∼ 35,000 in the K band), and aims to address these challenges with high-resolution spectroscopy. Using an atmospheric retrieval framework based on petitRADTRANS, we analyze the KPIC high-resolution spectrum (2.29-2.49 μm) and the archival low-resolution spectrum (1-2.2 μm) of the benchmark brown dwarf HD 4747 B (m = 67.2 ± 1.8 M Jup, a = 10.0 ± 0.2 au, T eff ≈ 1400 K). We find that our measured C/O and metallicity for the companion from the KPIC high-resolution spectrum agree with those of its host star within 1σ-2σ. The retrieved parameters from the K-band high-resolution spectrum are also independent of our choice of cloud model. In contrast, the retrieved parameters from the low-resolution spectrum are highly sensitive to our chosen cloud model. Finally, we detect CO, H2O, and CH4 (volume-mixing ratio of log(CH4) = −4.82 ± 0.23) in this L/T transition companion with the KPIC data. The relative molecular abundances allow us to constrain the degree of chemical disequilibrium in the atmosphere of HD 4747 B, and infer a vertical diffusion coefficient that is at the upper limit predicted from mixing length theory.

A benchmark brown dwarf (BD) is a BD whose properties (e.g., mass and chemical composition) are precisely and independently measured. Benchmark BDs are valuable in testing theoretical evolutionary tracks, spectral synthesis, and atmospheric retrievals for substellar objects. Here, we report results of atmospheric retrieval on a synthetic spectrum and a benchmark BD, HR 7672 B, with petitRADTRANS. First, we test the retrieval framework on a synthetic PHOENIX BT-Settl spectrum with a solar composition. We show that the retrieved C and O abundances are consistent with solar values, but the retrieved C/O is overestimated by 0.13-0.18, which is about four times higher than the formal error bar. Second, we perform retrieval on HR 7672 B using high spectral-resolution data (R = 35,000) from the Keck Planet Imager and Characterizer and near-infrared photometry. We retrieve [C/H], [O/H], and C/O to be -0.24 ± 0.05, -0.19 ± 0.04, and 0.52 ± 0.02. These values are consistent with those of HR 7672 A within 1.5σ. As such, HR 7672 B is among only a few benchmark BDs (along with Gl 570 D and HD 3651 B) that have been demonstrated to have consistent elemental abundances with their primary stars. Our work provides a practical procedure of testing and performing atmospheric retrieval, and sheds light on potential systematics of future retrievals using high- and low-resolution data.

Using the Keck Planet Imager and Characterizer, we obtained high-resolution (R ∼ 35,000) K-band spectra of the four planets orbiting HR 8799. We clearly detected H2O and CO in the atmospheres of HR 8799 c, d, and e, and tentatively detected a combination of CO and H2O in b. These are the most challenging directly imaged exoplanets that have been observed at high spectral resolution to date when considering both their angular separations and flux ratios. We developed a forward-modeling framework that allows us to jointly fit the spectra of the planets and the diffracted starlight simultaneously in a likelihood-based approach and obtained posterior probabilities on their effective temperatures, surface gravities, radial velocities, and spins. We measured v sin (i) values of 10.1-2.7+2.8km s-1 for HR 8799 d and 15.0-2.6+2.3 km s-1 for HR 8799 e, and placed an upper limit of