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Mid-infrared spectra of 65 T Tauri stars (TTS) taken with the Infrared Spectrograph (IRS) on board the Spitzer Space Telescope are modeled using dust at two temperatures to probe the radial variation in dust composition in the uppermost layers of protoplanetary disks. Most spectra indicating crystalline silicates require Mg-rich minerals and silica, but a few suggest otherwise. Spectra indicating abundant enstatite at higher temperatures also require crystalline silicates at temperatures lower than those required for spectra showing high abundance of other crystalline silicates. A few spectra show 10 micron complexes of very small equivalent width. They are fit well using abundant crystalline silicates but very few large grains, inconsistent with the expectation that low peak-to-continuum ratio of the 10 micron complex always indicates grain growth. Most spectra in our sample are fit well without using the opacities of large crystalline silicate grains. If large grains grow by agglomeration of submicron grains of all dust types, the amorphous silicate components of these aggregates must typically be more abundant than the crystalline silicate components. Crystalline silicate abundances correlate positively with other such abundances, suggesting that crystalline silicates are processed directly from amorphous silicates and that neither forsterite, enstatite, nor silica are intermediate steps when producing either of the other two. Disks with more dust settling typically have greater crystalline abundances. Large-grain abundance is somewhat correlated with greater settling of disks. The lack of strong correlation is interpreted to mean that settling of large grains is sensitive to individual disk properties. Lower-mass stars have higher abundances of large grains in their inner regions., Comment: 84 pages, 27 figures, submitted to the Astrophysical Journal on 7 November, 2008

Mid-infrared spectra of a few T Tauri stars (TTS) taken with the Infrared Spectrograph (IRS) on board the Spitzer Space Telescope show prominent narrow emission features indicating silica (crystalline silicon dioxide). Silica is not a major constituent of the interstellar medium; therefore, any silica present in the circumstellar protoplanetary disks of TTS must be largely the result of processing of primitive dust material in the disks surrouding these stars. We model the silica emission features in our spectra using the opacities of various polymorphs of silica and their amorphous versions computed from earth-based laboratory measurements. This modeling indicates that the two polymorphs of silica, tridymite and cristobalite, which form at successively higher temperatures and low pressures, are the dominant forms of silica in the TTS of our sample. These high temperature, low pressure polymorphs of silica present in protoplanetary disks are consistent with a grain composed mostly of tridymite named Ada found in the cometary dust samples collected from the STARDUST mission to Comet 81P/Wild 2. The silica in these protoplanetary disks may arise from incongruent melting of enstatite or from incongruent melting of amorphous pyroxene, the latter being analogous to the former. The high temperatures of 1200K-1300K and rapid cooling required to crystallize tridymite or cristobalite set constraints on the mechanisms that could have formed the silica in these protoplanetary disks, suggestive of processing of these grains during the transient heating events hypothesized to create chondrules., Comment: 47 pages, 9 figures, to appear in the 1 January, 2009 issue of the Astrophysical Journal

Here we present the Spitzer IRS spectrum of CVSO 224, the sole transitional disk located within the ~10 Myr old 25 Orionis group in Orion OB1a. A model fit to the spectral energy distribution of this object indicates a ~7 AU inner disk hole that contains a small amount of optically thin dust. In previous studies, CVSO 224 had been classified as a weak-line T Tauri star based on its Halpha equivalent width, but here we find an accretion rate of 7x10^-11 Msun/yr based on high-resolution Hectochelle data. CVSO 224's low mass accretion rate is in line with photoevaporative clearing theories. However, the Spitzer IRS spectrum of CVSO 224 has a substantial mid-infrared excess beyond 20microns which indicates that it is surrounded by a massive outer disk. Millimeter measurements are necessary to constrain the mass of the outer disk around CVSO 224 in order to confirm that photoevaporation is not the mechanism behind creating its inner disk hole., Comment: 4 pages, accepted to ApJL

We present spectra of a sample of Herbig Ae and Be (HAeBe) stars obtained with the Infrared Spectrograph on the Spitzer Space Telescope. All but one of the Herbig stars show emission from polycyclic aromatic hydrocarbons (PAHs) and seven of the spectra show PAH emission, but no silicate emission at 10 microns. The central wavelengths of the 6.2, 7.7--8.2, and 11.3 micron emission features decrease with stellar temperature, indicating that the PAHs are less photo-processed in cooler radiation fields. The apparent low level of photo processing in HAeBe stars, relative to other PAH emission sources, implies that the PAHs are newly exposed to the UV-optical radiation fields from their host stars. HAeBe stars show a variety of PAH emission intensities and ionization fractions, but a narrow range of PAH spectral classifications based on positions of major PAH feature centers. This may indicate that, regardless of their locations relative to the stars, the PAH molecules are altered by the same physical processes in the proto-planetary disks of intermediate-mass stars. Analysis of the mid-IR spectral energy distributions indicates that our sample likely includes both radially flared and more flattened/settled disk systems, but we do not see the expected correlation of overall PAH emission with disk geometry. We suggest that the strength of PAH emission from HAeBe stars may depend not only on the degree of radial flaring, but also on the abundance of PAHs in illuminated regions of the disks and possibly on the vertical structure of the inner disk as well., Comment: 52 pages, 12 figures

Using SpeX at the NASA Infrared Telescope Facility and the Spitzer Infrared Spectrograph, we have obtained infrared spectra from 0.7 to 30um for three young brown dwarfs in the TW Hydra Association (~10 Myr), 2M J1207-3932, 2M J1139-3159, and SS J1102-3431. The spectral energy distribution for 2M J1139-3159 is consistent with a stellar photosphere for the entire wavelength range of our data while the other two objects exhibit significant excess emission at >5um. We are able to reproduce the excess emission from each brown dwarf using our models of irradiated accretion disks. According to our model fits, both disks have experienced a high degree of dust settling. We also find that silicate emission at 10 and 20um is absent from the spectra of these disks, indicating that grains in the upper disk layers have grown to sizes larger than ~5um. Both of these characteristics are consistent with previous observations of decreasing silicate emission with lower stellar masses and older ages. These trends suggest that either 1) the growth of dust grains, and perhaps planetesimal formation, occurs faster in disks around brown dwarfs than in disks around stars, or 2) the radii of the mid-IR-emitting regions of disks are smaller for brown dwarfs than for stars, and grains grow faster at smaller disk radii. Finally, we note the possible detection of an unexplained emission feature near 14um in the spectra of both of the disk-bearing brown dwarfs., Comment: accepted for publication in Astrophysical Journal Letters

HD 179821 is an evolved star of unknown progenitor mass range (either post-Asymptotic Giant Branch or post-Red Supergiant) exhibiting a double peaked spectral energy distribution (SED) with a sharp rise from $\sim8-20$ $\mu$m. Such features have been associated with ejected dust shells or inwardly truncated circumstellar discs. In order to compare SEDs from both systems, we employ a spherically symmetric radiative transfer code and compare it to a radiative, inwardly truncated disc code. As a case study, we model the broad-band SED of HD 179821 using both codes. Shortward of 40 $\mu$m, we find that both models produce equivalent fits to the data. However, longward of 40 $\mu$m, the radial density distribution and corresponding broad range of disc temperatures produce excess emission above our spherically symmetric solutions and the observations. For HD 179821, our best fit consists of a $T_{eff}=7000$ K central source characterized by $\tau_V\sim1.95$ and surrounded by a radiatively driven, spherically symmetric dust shell. The extinction of the central source reddens the broad-band colours so that they resemble a $T_{eff}=5750$ K photosphere. We believe that HD 179821 contains a hotter central star than previously thought. Our results provide an initial step towards a technique to distinguish geometric differences from spectral modeling., Comment: 18 pages, 4 figures, 3 tables; accepted to MNRAS

We present the Spitzer Infrared Spectrograph (IRS) spectrum of SR20, a 5--10 AU binary T Tauri system in the $\rho$ Ophiuchi star forming region. The spectrum has features consistent with the presence of a disk; however, the continuum slope is steeper than the $\lambda^{-4/3}$ slope of an infinite geometrically thin, optically thick disk, indicating that the disk is outwardly truncated. Comparison with photometry from the literature shows a large increase in the mid-infrared flux from 1993 to 1996. We model the spectral energy distribution and IRS spectrum with a wall + optically thick irradiated disk, yielding an outer radius of 0.39$_{+0.03}^{-0.01}$ AU, much smaller than predicted by models of binary orbits. Using a two temperature $\chi^2$ minimization model to fit the dust composition of the IRS spectrum, we find the disk has experienced significant grain growth: its spectrum is well-fit using opacities of grains larger than 1 $\mu$m. We conclude that the system experienced a significant gravitational perturbation in the 1990s., Comment: 4 pages, 4 figures, 1 table, accepted to ApJ Letters

We present Spitzer Infrared Spectrograph spectra of 28 Class I protostars in the Taurus star-forming region. The 5 to 36 micron spectra reveal excess emission from the inner regions of the envelope and accretion disk surrounding these predecessors of low-mass stars, as well as absorption features due to silicates and ices. Together with shorter- and longer-wavelength data from the literature, we construct spectral energy distributions and fit envelope models to 22 protostars of our sample, most of which are well-constrained due to the availability of the IRS spectra. We infer that the envelopes of the Class I objects in our sample cover a wide range in parameter space, particularly in density and centrifugal radius, implying different initial conditions for the collapse of protostellar cores., Comment: 46 pages, 29 figures; accepted for publication in ApJS

We present observations of a circumstellar disk that is inclined close to edge-on around a young brown dwarf in the Taurus star-forming region. Using data obtained with SpeX at the NASA Infrared Telescope Facility, we find that the slope of the 0.8-2.5 um spectrum of the brown dwarf 2MASS J04381486+2611399 cannot be reproduced with a photosphere reddened by normal extinction. Instead, the slope is consistent with scattered light, indicating that circumstellar material is occulting the brown dwarf. By combining the SpeX data with mid-IR photometry and spectroscopy from the Spitzer Space Telescope and previously published millimeter data from Scholz and coworkers, we construct the spectral energy distribution for 2MASS J04381486+2611399 and model it in terms of a young brown dwarf surrounded by an irradiated accretion disk. The presence of both silicate absorption at 10 um and silicate emission at 11 um constrains the inclination of the disk to be ~70 deg, i.e. ~20 deg from edge-on. Additional evidence of the high inclination of this disk is provided by our detection of asymmetric bipolar extended emission surrounding 2MASS J04381486+2611399 in high-resolution optical images obtained with the Hubble Space Telescope. According to our modeling for the SED and images of this system, the disk contains a large inner hole that is indicative of a transition disk (R_in~58 R_star~0.275 AU) and is somewhat larger than expected from embryo ejection models (R_out=20-40 AU vs. R_out<10-20 AU)., Comment: The Astrophysical Journal, in press

We have used the Infrared Spectrograph (IRS) on the Spitzer Space Telescope to obtain spectra of HD 100764, an apparently single carbon star with a circumstellar disk. The spectrum shows emission features from polycyclic aromatic hydrocarbons (PAHs) that are shifted to longer wavelengths than normally seen, as characteristic of ``class C'' systems in the classification scheme of Peeters et al. All seven of the known class C PAH sources are illuminated by radiation fields that are cooler than those which typically excite PAH emission features. The observed wavelength shifts are consistent with hydrocarbon mixtures containing both aromatic and aliphatic bonds. We propose that the class C PAH spectra are distinctive because the carbonaceous material has not been subjected to a strong ultraviolet radiation field, allowing relatively fragile aliphatic materials to survive., Comment: 11 pages (in emulateapj), 5 tables, 7 figures. Accepted for publication in ApJ

We present the mid-infrared spectrum, obtained with the Spitzer Infrared Spectrograph (IRS), of HD 98800, a quadruple star system located in the 10-Myr-old TW Hydrae association. It has a known mid-infrared excess that arises from a circumbinary disk around the B components of the system. The IRS spectrum confirms that the disk around HD 98800 B displays no excess emission below about 5.5 micron, implying an optically thick disk wall at 5.9 AU and an inner, cleared-out region; however, some optically thin dust, consisting mainly of 3-micron-sized silicate dust grains, orbits the binary in a ring between 1.5 and 2 AU. The peculiar structure and apparent lack of gas in the HD 98800 B disk suggests that this system is likely already at the debris disks stage, with a tidally truncated circumbinary disk of larger dust particles and an inner, second-generation dust ring, possibly held up by the resonances of a planet. The unusually large infrared excess can be explained by gravitational perturbations of the Aa+Ab pair puffing up the outer dust ring and causing frequent collisions among the larger particles., Comment: 10 pages, 8 figures

We characterize the crystalline silicate content and spatial distribution of small dust grains in a large sample of protoplanetary disks in the Taurus-Auriga young cluster, using Spitzer Space Telescope mid-infrared spectra. In turn we use the results to analyze the evolution of structure and composition of these 1-2 Myr-old disks around Solar- and later-type young stars, and test the standard models of dust processing which result in the conversion of originally amorphous dust into minerals. We find strong evidence of evolution of the dust crystalline mass fraction in parallel with that of the structure of the disks, in the sense that increasing crystalline mass fraction is strongly linked to dust settling to the disk midplane. We also confirm that the crystalline silicates are confined to small radii, r < 10 AU. However, we see no significant correlation of crystalline mass fraction with stellar mass or luminosity, stellar accretion rate, disk mass, or disk/star mass ratio, as would be expected in the standard models of dust processing based upon photo-evaporation and condensation close to the central star, accretion-heating-driven annealing at r < 1 AU, or spiral-shock heating at r < 10 AU, with or without effective radial mixing mechanisms. Either another grain-crystallizing mechanism dominates over these, or another process must be at work within the disks to erase the correlations they produce. We propose one of each sort that seem to be worth further investigation, namely X-ray heating and annealing of dust grains, and modulation of disk structure by giant-planetary formation and migration., Comment: 116 pages, including 11 figures and 4 tables

We present mid-infrared spectra of T Tauri stars in the Taurus star-forming region obtained with the Spitzer Infrared Spectrograph (IRS). For the first time, the 5-36 micron spectra of a large sample of T Tauri stars belonging to the same star-forming region is studied, revealing details of the mid-infrared excess due to dust in circumstellar disks. We analyze common features and differences in the mid-IR spectra based on disk structure, dust grain properties, and the presence of companions. Our analysis encompasses spectral energy distributions from the optical to the far-infrared, a morphological sequence based on the IRS spectra, and spectral indices in IRS wave bands representative of continuum emission. By comparing the observed spectra to a grid of accretion disk models, we infer some basic disk properties for our sample of T Tauri stars, and find additional evidence for dust settling., Comment: 51 pages, 15 figures

We present the first Spitzer Infrared Spectrograph (IRS; The IRS was a collaborative venture between Cornell University and Ball Aerospace Corporation funded by NASA through the Jet Propulsion Laboratory and the Ames Research Center.) observations of the disks around classical T Tauri stars: spectra in the 5.2-30 micron range of six stars. The spectra are dominated by emission features from amorphous silicate dust, and a continuous component from 5 to 8 microns that in most cases comprises an excess above the photosphere throughout our spectral range. There is considerable variation in the silicate feature/continuum ratio, which implies variations of inclination, disk flaring, and stellar mass accretion rate. In most of our stars, structure in the silicate feature suggests the presence of a crystalline component. In one, CoKu Tau/4, no excess above the photosphere appears at wavelengths shortward of the silicate features, similar to 10 Myr old TW Hya, Hen 3-600, and HR 4796A. This indicates the optically thick inner disk is largely absent. The silicate emission features with peaks at 9.7 and 18 microns indicate small dust grains are present. The extremely low 10-20 micron color temperature of the dust excess, 135 K, indicates these grains are located more than 10 AU from the star. These features are suggestive of gravitational influence by planets or close stellar companions and grain growth in the region within 10 AU of the star, somewhat surprising for a star this young (1 Myr)., Comment: AASTEX, 10 pages text, 2 figures, 1 table, published September 2004 in The Astrophysical Journal Supplement Series

The 8-14 micron emission spectra of 12 T Tauri stars in the Taurus/Auriga dark clouds and in the TW Hydrae association obtained with the Infrared Spectrograph (IRS; The IRS is a collaborative venture between Cornell University and Ball Aerospace Corporation funded by NASA through the Jet Propulsion Laboratory and the Ames Research Center.) on board Spitzer are analyzed. Assuming the 10 micron features originate from silicate grains in the optically thin surface layers of T Tauri disks, the 8-14 micron dust emissivity for each object is derived from its Spitzer spectrum. The emissivities are fit with the opacities of laboratory analogs of cosmic dust. The fits include small nonspherical grains of amorphous silicates (pyroxene and olivine), crystalline silicates (forsterite and pyroxene), and quartz, together with large fluffy amorphous silicate grains. A wide range in the fraction of crystalline silicate grains as well as large silicate grains among these stars are found. The dust in the transitional-disk objects CoKu Tau/4, GM Aur, and DM Tau has the simplest form of silicates, with almost no hint of crystalline components and modest amounts of large grains. This indicates that the dust grains in these objects have been modified little from their origin in the interstellar medium. Other stars show various amounts of crystalline silicates, similar to the wide dispersion of the degree of crystallinity reported for Herbig Ae/Be stars of mass <2.5 solar masses. Late spectral type, low-mass stars can have significant fractions of crystalline silicate grains. Higher quartz mass fractions often accompany low amorphous olivine-to-amorphous pyroxene ratios. It is also found that lower contrast of the 10 micron feature accompanies greater crystallinity., Comment: AASTEX, 39 pages text, 14 figures, 4 tables, scheduled to be published July 2006 in the Astrophysical Journal

We present 5-35 $\mu$m spectra, taken with the Infrared Spectrograph (IRS) on the Spitzer Space Telescope, of five FU Orionis objects: FU Ori, V1515 Cyg, V1057 Cyg, BBW 76, and V346 Nor. All but V346 Nor reveal amorphous silicate grains in emission at 10 $\mu$m and 20 $\mu$m, and show water-vapor absorption bands at 5.8 and 6.8 $\mu$m and SiO or possibly methane absorption at 8 $\mu$m. These absorption features closely match these bands in model stellar photospheres -- signs of the gaseous photospheres of the inner regions of these objects' accretion disks. The continuum emission at 5-8 $\mu$m is also consistent with such disks, and, for FU Orionis and BBW 76, longer-wavelength emission may be fit by a model which includes moderate disk flaring. V1057 Cyg and V1515 Cyg have much more emission at longer wavelengths than the others, perhaps evidence of substantial remnant of their natal, infalling envelopes., Comment: 30 pages, 8 figures, accepted by ApJ

We have obtained Spitzer Space Telescope IRS 5.5 - 35 micron spectra of 59 main sequence stars that possess IRAS 60 micron excess. The spectra of five objects possess spectral features that are well-modeled using micron-sized grains and silicates with crystalline mass fractions 0% - 80%, consistent with T-Tauri and Herbig AeBe stars. With the exception of eta Crv, these objects are young with ages <50 Myr. The spectra for the majority of objects are featureless, suggesting that the emitting grains probably have radii a > 10 micron. We have modeled the excess continua using a continuous disk with a uniform surface density distribution, expected if Poynting-Robertson and stellar wind drag are the dominant grain removal processes, and using a single temperature black body, expected if the dust is located in a narrow ring around the star. The IRS spectra of many objects are better modeled with a single temperature black body, suggesting that the disks possess inner holes. The distribution of grain temperatures, based on our black body fits, peaks at Tgr = 110 - 130 K. Since the timescale for ice sublimation of micron-sized grains with Tgr > 110 K is a fraction of a Myr, the lack of warmer material may be explained if the grains are icy. If planets dynamically clear the central portions of debris disks, then the frequency of planets around other stars is probably high. We estimate that the majority of debris disk systems possess parent body masses, MPB < 1 Mearth. The low inferred parent body masses suggest that planet formation is an efficient process. (abridged abstract), Comment: 66 pages, 18 figures (including 12 color figures), ApJS, in press

We report spectra obtained with the Spitzer Space Telescope in the 5 to 35 micron range of HD 233517, an evolved K2 III giant with circumstellar dust. At wavelengths longer than 13 microns, the flux is a smooth continuum that varies approximately as frequency to the -5/3 power. For wavelengths shorter than 13 microns, although the star is oxygen-rich, PAH features produced by carbon-rich species at 6.3 microns, 8.2 microns, 11.3 microns and 12.7 microns are detected along with likely broad silicate emission near 20 microns. These results can be explained if there is a passive, flared disk orbiting HD 233517. Our data support the hypothesis that organic molecules in orbiting disks may be synthesized in situ as well as being incorporated from the interstellar medium., Comment: 11 pages, 2 figures, ApJ Letters, in press

Silicates are an important component of interstellar dust and the structure of these grains -- amorphous versus crystalline -- is sensitive to the local physical conditions. We have studied the infrared spectra of a sample of ultra-luminous infrared galaxies. Here, we report the discovery of weak, narrow absorption features at 11, 16, 19, 23, and 28 microns, characteristic of crystalline silicates, superimposed on the broad absorption bands at 10 and 18 microns due to amorphous silicates in a subset of this sample. These features betray the presence of forsterite (Mg_2SiO_4), the magnesium-rich end member of the olivines. Previously, crystalline silicates have only been observed in circumstellar environments. The derived fraction of forsterite to amorphous silicates is typically 0.1 in these ULIRGs. This is much larger than the upper limit for this ratio in the interstellar medium of the Milky Way, 0.01. These results suggest that the timescale for injection of crystalline silicates into the ISM is short in a merger-driven starburst environment (e.g., as compared to the total time to dissipate the gas), pointing towards massive stars as a prominent source of crystalline silicates. Furthermore, amorphization due to cosmic rays, which is thought to be of prime importance for the local ISM, lags in vigorous starburst environments., Comment: 7 pages, 5 figures, accepted for publication in ApJ

We present spectra of four Herbig AeBe stars obtained with the Infrared Spectrograph (IRS). on the Spitzer Space Telescope. All four of the sources show strong emission from polycyclic aromatic hydrocarbons (PAHs), with the 6.2 um emission feature shifted to 6.3 um and the strongest C-C skeletal-mode feature occuring at 7.9 um instead of at 7.7 um as is often seen. Remarkably, none of the four stars have silicate emission. The strength of the 7.9 um feature varies with respect to the 11.3 um feature among the sources, indicating that we have observed PAHs with a range of ionization fractions. The ionization fraction is higher for systems with hotter and brighter central stars. Two sources, HD 34282 and HD 169142, show emission features from aliphatic hydrocarbons at 6.85 and 7.25 um. The spectrum of HD 141569 shows a previously undetected emission feature at 12.4 um which may be related to the 12.7 um PAH feature. The spectrum of HD 135344, the coolest star in our sample, shows an unusual profile in the 7-9 um region, with the peak emission to the red of 8.0 um and no 8.6 um PAH feature., Comment: Accepted by ApJ 23 June, 2005, 8 pages (emulateapj), 5 figures (3 in color)

We report the spectroscopic detection of silicate emission at 10 and 18 microns in five PG quasars, the first detection of these two features in galaxies outside the Local Group. This finding is consistent with the unification model for Active Galactic Nuclei (AGNs), which predicts that an AGN torus seen pole-on should show a silicate emission feature in the mid-infrared. The strengths of the detected silicate emission features range from 0.12 to 1.25 times the continuum at 10 microns and from 0.20 to 0.79 times the continuum at 18 microns. The silicate grain temperatures inferred from the ratio of 18-to-10 micron silicate features under the assumption of optically thin emission range from 140 to 220K., Comment: 4 pages, including 2 tables and 3 figures. Accepted by ApJL

We have used the Spitzer Infrared Spectrograph to observe seven members of the TW Hya association, the nearest stellar association whose age ($\sim$ 10 Myr) is similar to the timescales thought to apply to planet formation and disk dissipation. Only two of the seven targets display infrared excess emission, indicating that substantial amounts of dust still exist closer to the stars than is characteristic of debris disks; however, in both objects we confirm an abrupt short-wavelength edge to the excess, as is seen in disks with cleared-out central regions. The mid-infrared excesses in the spectra of Hen 3-600 and TW Hya include crystalline silicate emission features, indicating that the grains have undergone significant thermal processing. We offer a detailed comparison between the spectra of TW Hya and Hen 3-600, and a model that corroborates the spectral shape and our previous understanding of the radial structure of these protoplanetary disks., Comment: To appear in the Spitzer special issue of ApJS; 12 pages, 2 figures

We report spectra obtained with the Spitzer Space Telescope in the wavelength range between 14 microns and 35 microns of 19 nearby main-sequence stars with infrared excesses. The six stars with strong dust emission show no recognizable spectral features, suggesting that the bulk of the emitting particles have diameters larger than 10 microns. If the observed dust results from collisional grinding of larger solids, we infer minimum masses of the parent body population between 0.004 of the Earth's mass and 0.06 of the Earth's mass. We estimate grain production rates of 10 Gg/s around lambda Boo and HR 1570; selective accretion of this matter may help explain their peculiar surface abundances. There appear to be inner truncations in the dust clouds at 48 AU, 11 AU, 52 AU and 54 AU around HR 333, HR 506, HR 1082 and HR 3927, respectively., Comment: 11 pages, 1 figure, ApJ Supplement, Spitzer special issue, in press