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The flux of gases between the atmosphere and the oceans can be calculated from the product of the concentration difference across the sea surface and a kinetic term, often called a transfer velocity. The transfer velocity is frequently parameterized in terms of wind speed, although the actual exchange process is also affected by waves, bubbles, wind fetch, and less certainly by surfactants and chemical reactivity. There is currently an uncertainty of about a factor of two in using the wind speed parameterization. In view of the windiness of the Southern Ocean, transfer velocities will often be high, although there are few published in situ measurements of transfer rates made in the region. Data for gas concentration fields in the Southern Ocean are generally sparse compared to other better studied oceanic areas. In this paper we discuss what is known for the region for carbon dioxide, including the oceanic sink for man-made inputs to the atmosphere; dimethyl sulphide, where there appears to be a substantial source, which has the potential for a significant climatic effect due to the low particulate loading in the region; and organo-halogen and alkyl nitrate gases, where marine emissions may play an important role in controlling the oxidation capacity of the Antarctic atmosphere.

It is well known that iron fertilization can increase primary production and hence CO 2 drawdown over a significant fraction of the oceans. What is less well established is the extent to which this leads to long-term sequestration of carbon to the deep oceans, and to feedbacks to the atmosphere arising from increased biological activity. In this note results for changes in trace gas concentrations during an iron addition experiment in the Southern Ocean are presented. They demonstrate that a complex situation exists; some gases (DMS, CH 3 I, CHBr 2 Cl) show increases in concentration following fertilization with iron while others show no change (CH 3 ONO 2 , CH 2 ClI) or even a decrease (CHBr 3 ). The concomitant effects on air–sea fluxes of these gases are potentially important for climate and atmospheric composition. DOI: 10.1111/j.1600-0889.2005.00141.x

[1] During a west to east crossing of the tropical Atlantic Ocean in October–November 2002 on R/V Meteor (M55), carbon monoxide (CO) and ozone were continuously monitored, and pressurized air samples were collected and later analyzed in the laboratory for various volatile organic compounds. A sequence of alternating CO and propane rich events were observed over the east Atlantic, the events of enhanced carbon monoxide being out of phase with those observed for propane. A combined study of air mass origin (back trajectories and backward emission sensitivity calculations) and source region distribution comparison (CO satellite data from MOPITT and propane emission data from the EDGAR database) showed that the CO events were due to African biomass burning emissions, whereas the propane events were due to industrial emissions from areas of northern Africa. Both events were associated with elevated ozone. A comparison of the measured concentrations of CO and propane with those simulated by the global Model of Atmospheric Transport and Chemistry-Max Planck Institute for Chemistry (MATCH-MPIC) shows that the model reproduces the general longitudinal gradient observed for both compounds and simulates elevated CO concentrations during the pollution events. However, it systematically overestimates the CO mixing ratios. It is suggested that the northern African biomass burning emissions used in the model are not distributed correctly (incorrect timing) and, in particular, that too high emissions from the region “northern Sudan-Sahel” are used for this period. The model does not capture the influence from industrial emissions from northern Africa, which may be caused by too strong diffusion of the plume.