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The Liupan Mountain (LPM) area is located on the northeast margin of the Qinghai–Tibet Plateau, which is the western part of the second ladder of China's terrain. It is also an intersection area of two air currents, which are caused by the combined action of the Qinghai–Tibet Plateau, the middle and lower levels of the westerly belt and the edge of the monsoon area. LPM is one of the main air water vapour transport pathways in Northwest China as well as a main water conservation area for nearly ten million people. Research on atmospheric precipitable water vapour (PWV) variation characteristics in LPM is beneficial for understanding the mechanisms of orographic precipitation and improving the effects of weather modification. Based on the data from 10 Global Navigation Satellite System Meteorology (GNSS/MET) stations for 6 years and the data of automatic weather stations in the LPM, the temporal and spatial variation characteristics of PWV in the LPM were analysed, and the differences in PWV in the 24 h before and after precipitation were compared in this study. The results showed that the hourly, monthly and seasonal variations in PWV displayed obvious patterns. PWV increased rapidly 10 h ahead of precipitation, while it decreased rapidly within 10 h after precipitation, which was slower than that before precipitation. In terms of spatial distribution, PWV was larger in the south than in the north and larger in the east than in the west. Although the precipitation on the LPM peak was the highest in the whole LPM area, its PWV was always the lowest, indicating that the PWV was obviously affected by the air temperature. This showed that under the same water vapour condition, precipitation was more likely to form in the area with low temperature, and the precipitation was larger, which also provided a train of thought for improving the method of artificial precipitation enhancement by using the condensation catalyst. [ABSTRACT FROM AUTHOR]