1. Infrared optical properties of amorphous and nanocrystalline Ta2O5 thin films.
- Author
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Bright, T. J., Watjen, J. I., Zhang, Z. M., Muratore, C., Voevodin, A. A., Koukis, D. I., Tanner, D. B., and Arenas, D. J.
- Subjects
TANTALUM oxide ,MAGNETRON sputtering ,X-ray diffraction ,WAVELENGTHS ,ATOMIC force microscopy ,PHONONS - Abstract
The optical constants of tantalum pentoxide (Ta2O5) are determined in a broad spectral region from the visible to the far infrared. Ta2O5 films of various thicknesses from approximately 170 to 1600 nm are deposited using reactive magnetron sputtering on Si substrates. X-ray diffraction shows that the as-deposited films are amorphous, and annealing in air at 800 °C results in the formation of nanocrystalline Ta2O5. Ellipsometry is used to obtain the dispersion in the visible and near-infrared. Two Fourier-transform infrared spectrometers are used to measure the transmittance and reflectance at wavelengths from 1 to 1000 μm. The surface topography and microstructure of the samples are examined using atomic force microscopy, confocal microscopy, and scanning electron microscopy. Classical Lorentz oscillators are employed to model the absorption bands due to phonons and impurities. A simple model is introduced to account for light scattering in the annealed films, which contain micro-cracks. For the unannealed samples, an effective-medium approximation is used to take into account the adsorbed moisture in the film and a Drude free-electron term is also added to model the broad background absorption. [ABSTRACT FROM AUTHOR]
- Published
- 2013
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