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Photons carrying a well-defined orbital angular momentum have been proven to modify spectroscopic selection rules in atomic matter. Excitation profiles of electric quadrupole transitions have been measured with single trapped $^{40}$Ca$^+$ ions for varying polarizations. We further develop the photo-absorption formalism to study the case of arbitrary alignment of the beam's optical axis with respect to the ion's quantization axis and mixed multipolarity. Thus, predictions for M1-dominated $^{40}Ar^{13+}$, E3-driven $^{171}Yb^+$ and $^{172}Yb^+$, and B-like $^{20}Ne^{5+}$ are presented. The latter case displays novel effects, coming from the presence of a strong photon -- magnetic dipole coupling., 10 pages, 5 figures, 1 table

Inter-band photo-excitation of electron states with the twisted photons in GaAs, a direct band-gap bulk semiconductor, is considered theoretically. Assuming linearity of the quantum transition amplitudes and applying Wigner-Eckart theorem, we derive a plane-wave expansion of twisted-photon amplitudes and obtain relative probabilities for magnetic sub-level population of the photo-electrons in conduction band. The approach for calculating the position dependent electron polarization, resulting from photo-absorption of twisted light, is described for vertical transitions in the $\Gamma$ - point. Theoretical predictions for GaAs show the interplay of spin and orbital angular momentum of the twisted photons that alters the magnitude and the sign of photoelectron polarization in the region near photon's phase singularity., Comment: 9 pages, 4 figures