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The crust of Venus is composed of the low lying volcanic planitiae and the elevated, deformed tesserae. It is thought that the tesserae may be composed of silicic igneous rocks and that it may resemble proto-continental crust. The initial development of terrestrial continental crust is likely due to melting and deformation of primitive mafic crust via mantle-plume upwelling and collisional plate processes. Unlike Earth, the lithosphere of Venus is not divided into plates and therefore evolved continental crust, if present, developed primarily by melting of pre-existing mafic crust. Here, we report the results of high pressure equilibrium partial melting experiments using a parental composition similar to the basalt measured at the Venera 14 landing site in order to determine if silicic melts can be generated. It was found that at pressures of 1.5 GPa and 2.0 GPa and temperatures of 1080 °C, 1090 °C, and 1285 °C that tonalitic and granodioritic melts can be generated. The experimental results indicate that silicic rocks may be able to form in the crust of Venus providing the thermal regime is suitable and that the lower crust is basaltic. The implication is that the older, thicker regions of Venusian crust may be partially composed of silicic igneous rocks. [ABSTRACT FROM AUTHOR]

A geochemical study was undertaken on basaltic lava flows intercalated with Oligocene to Miocene strata in the Sabzevar region, northern Iran, to examine their petrogenesis in a regional tectonic framework. The lavas are either aphyric or have phenocrysts and micro-phenocrysts of olivine and, to a lesser extent, clinopyroxene. Geochemically, the lavas are silica-undersaturated alkali basalts characterized by relatively high Mg# (~ 57–66) and Na2O/K2O (~ 2.0–6.7). They have distinctive trace element patterns characterized by strong rare-earth element fractionation, negative Nb–Ta and Zr-Hf anomalies and a positive Sr anomaly. Significant contamination by crustal materials either in the magma source or during ascent is ruled out on the basis of trace element compositions and Sr–Nd isotopic compositions (87Sr/86Sr = 0.7037–0.7048 and 143Nd/144Nd = 0.5128–0.5130), both of which differ markedly from continental crustal rocks. Phenocryst assemblage, analysis of multiple saturation points in lherzolite systems, and covariations of La/Yb with MgO of the studied lavas are generally consistent with an origin involving high-pressure fractionation of peridotite-derived melts. Primary magma compositions calculated by reversed fractionation of clinopyroxene and olivine for the relatively primitive samples (> 9 wt.% MgO), however, do not plot on the lherzolite multiple saturation points. Also, high-pressure fractionation predicts increasing trends of silica undersaturation and alkalinitiy with differentiation, and such trends are not indicated by the geochemical data. We suggest that the mixed trends shown by the data might be related to melt generation from both peridotite and silica-deficient pyroxenite sources, superimposed by variable degrees of high-pressure fractionation. The role of pyroxenite in magma genesis is indicated not only by the positive Sr anomaly shown by the trace element patterns, but also first-row transition element systematics of the studied lavas. The silica-deficient pyroxenites contributing to melt generation might have been transformed from mafic–ultramafic cumulates in subducted, lower oceanic crust, or might have formed in the lower crust or mantle lithosphere under continents during earlier magmatic episodes. [ABSTRACT FROM AUTHOR]

Profiles of a total of 23 plagioclase crystals erupted within the 1982-1991 and 1993 flows of the Coaxial segment of the Juan de Fuca ridge, the 1996 flow of the North Gorda ridge, and from the Western Volcanic Zone of the ultra-slow spreading Gakkel Ridge, have been studied for variations in major and trace element concentrations. We derive equilibration times for the relatively rapidly diffusing Sr in mid-ocean ridge basalt (MORB) plagioclase crystals of the order of months to a few years in each case. All crystals preserve diffusive disequilibria of strontium and barium. Crystal residence times at MORB magmatic temperatures are thus significantly shorter, of the order of days to a few months at most, precluding prolonged crystal storage in axial magma chambers and instead pointing to rapid crystal growth (up to ~10 cm s) and cooling (up to ~1°C h) shortly prior to eruption of these samples. Growth of these crystals is therefore inferred to occur almost entirely within oceanic layer 2 during dike injection. Crystals that grew at lower crustal levels or earlier in the differentiation sequence appear to have been excluded from the erupted magmas, as might occur if most of the gabbroic rocks in oceanic layer 3 formed an interlocking crystal framework, with viscosities that are too high to carry earlier formed crystals with the melt. The vertical extent of eruptible, crystal-poor melt lenses within the gabbroic zone is constrained to ~1 m or less by considering the width of local equilibrium growth zones, equilibration times, and crystal settling velocities. This lengthscale is consistent with field evidence from ophiolites. Finally, crystal aggregates within the Gakkel ridge sample studied here are the result of synneusis within the propagating dike during melt ascent. [ABSTRACT FROM AUTHOR]

Abstract: Residence times of olivine and plagioclase phenocrysts and xenocrysts in mid-ocean ridge (MOR) basaltic melts have been studied since the mid 1980s using geospeedometric techniques (i.e. using diffusion of major and trace elements) in order to constrain the processes of melt ascent and differentiation in this important magmatic setting. Residence times range from a few hours to several years, but potential links between these timescales and specific tectonomagmatic variables such as spreading rate and relative locations of eruption site and ridge axis have remained elusive. Here we demonstrate how incomplete chemical diffusion of Sr within plagioclase crystals from MOR basalts erupted in on- and off-axis settings on a number of ridges with variable spreading rates provide geospeedometric constraints. We combine electron probe microanalytical crystal maps with detailed laser ablation profiles of almost 70 plagioclase crystals from the fast spreading East Pacific Rise (EPR) at 9–10°N, the intermediate spreading Gorda and Juan de Fuca (JdF) ridges, and the ultraslow spreading Gakkel ridge to calculate crystal residence times. These range from a few days to several months. The scarcity of residence times exceeding years corroborates previous data indicating that most of the growth of plagioclase phenocrysts occurs within the conduit at the onset of and during eruption on the sea floor, and extends this result to the fast-spreading EPR. Further, statistical analysis is employed to show for the first time that residence times are systematically longer at slower spreading rates, in off-axis samples, and samples sourced from laterally distal axial melt lenses. Plagioclase textures and residence time variations appear to be linked to differences in the dynamics of late-stage, pre-eruptive magma storage and ascent in the different tectonomagmatic settings investigated. In the future, geospeedometric work on MOR samples will be required to assess if the effect of spreading rate on crystallization timescales are globally applicable, and to investigate potential variations in magma plumbing systems within individual ridge segments. [Copyright &y& Elsevier]

Abstract: The source of intraplate basalts has long been a controversial topic, particularly in continental settings where ambiguity increases because both crustal contamination and crystal fractionation may mask important source characteristics. We present geochemical data to constrain the source and the chemical evolution of the continental intraplate magmas from the Aleppo Plateau and vicinity, NW Syria. New 40Ar/39Ar ages, coupled with published 40Ar/39Ar and K–Ar ages, reveal two discrete Miocene volcanic phases, ~19–18Ma (Phase 1) and ~13.5–12Ma (Phase 2), in the studied area. New chemical and isotopic compositions [87Sr/86Sr=0.7036–0.7051, εNd=+4.5 to +1.1 and (187Os/188Os)t =0.151–0.453] of the lavas reflect the unequivocal influence of crustal assimilation and fractional crystallisation (AFC). Despite the effects of the AFC processes, there still appear to be some differences between the most-primitive, least contaminated magmas of the two volcanic phases, interpreted as a result of source heterogeneity. Whereas the Phase 1 lavas, with relatively high Si, low Ti and trace-element contents, are consistent with partial melting of a largely peridotitic mantle source, the origin of the Phase 2 lavas is more complicated. The latter are characterised by a source component depleted in Si and enriched in Ti, Fe, Ca, P, alkalis, light and middle rare earth elements (REEs) relative to heavy REEs and with sub-chondritic Th–(U)/Nb, Pb/Ce and Zr/Sm. They approach compositions of experimental melts of amphibole-rich metasomatic veins. The compositional variations among the most primitive Phase 2 lavas are difficult to reconcile with varying degrees of partial melting of either the metasomatic veins or peridotite, but could be explained if partial melts of both lithologies were variably mixed, a scenario that could be sensibly envisioned as ascending (peridotitic) plume/asthenosphere derived melts assimilating highly fusible metasomatic veins during their traverse through the lithosphere. This process can be loosely quantified by trace-element forward partial melting modelling that suggests mixing of up to 80% metasomatic melts derived from ~40% melting of amphibole-rich metasomatic veins (which themselves were inevitably compositionally and mineralogically heterogeneous) with 20% plume/asthenospheric melts derived from ~7% melting of a garnet peridotite. Within the compressional framework of northern Arabia, invocation of diapiric material reasonably accounts for the generation of the intraplate basalts in Syria. Derivation of the Phase 2 hybrid melts was probably triggered by lateral flow of this diapiric material beneath the lithosphere subsequent to its arrival, with the migrating flow-front controlling the locus of volcanism. The increase in degree of Si-undersaturation with time for the Phase 1 and Phase 2 lavas is best explained by decreasing temperatures of this flow-front that resulted in less melt contribution from the diapiric mantle while the amphibole-rich veins within the lithosphere continued to be easily fusible, although we cannot totally exclude the possibility that the Phase 2 volcanism tapped a vein-richer domain which formed subsequent to the Phase 1 volcanism. [Copyright &y& Elsevier]