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The recent literature indicates that, depending on the feedstocks and pyrolysis temperature, biochar can be a good source of nutrients. On the contrary, some biochars are not good sources of available carbon and other nutrients, but their porous structure seems to be a suitable microenvironment for microbial colonization. We investigated the response of soil biological parameters, microbial biomass carbon and nitrogen (MBC and MBN), in relation to mobile N species. Five different biochars were produced at different temperatures (300, 350, 400, 450, and 500 °C) from the same feedstock (woodchips). The physicochemical and morphological characteristics of the individual biochar samples were described, and incubation was carried out with the application of 2% biochar to two different soil types (luvisol and fluvisol). The addition of 2% biochar did not change the pH in the slightly acid soils used in the experiment, in spite of the alkaline character of biochar. The increasing amounts of total and nitrate-available nitrogen during the experiment are probably related to changes in soil microbial activity. The amount of soluble carbon was constant during the experiment, confirming its stability in the soil, most likely because of the high amount of lignin in the feedstock. The influence of biochar on the soil microbiome was determined on the basis of the concentrations of MBC and MBN. Microbial biomass was increased in both soils treated with biochar produced at lower temperatures. The physicochemical characteristics of the biochar as well as the sorption behavior of N-NO3− and N-NH4+ indicate that at a pyrolysis temperature of 400 °C, biochar properties change substantially. However, these findings are only valid for biochar produced from woodchips, and the long-term effects of biochar application on soil properties need to be investigated in further studies.

The effects of biochar on soil properties including nutrients have been reported in previous studies, but few studies targeted on soil nitrogen. Moreover, there remains a lack of studies considering the liberation of ammonia during the ammonium (N-NH4+) adsorption process. Our study aimed to fill this research gap. A pot incubation experiment was conducted for 84 days, with ten different soils and four rates of wood chip-based biochar (0.5, 2, 4, and 8%). Biochar's effect on soil ammonium was inconsistent and insignificant in most of the incubated soils at all biochar rates. This finding contradicted our Langmuir model, which estimated maximum ammonium adsorption capacity of biochar as 6.66 mg of N-NH4+ per g of biochar. Soil response in nitrate (N-NO3−) and dissolved organic carbon (DOC) followed a similar declining trend in all soils in both incubation periods, with the effect boosted according to the biochar application rate. The Langmuir isotherm estimated the maximum N-NO3− adsorption capacity of our biochar as 11.3 mg g−1. Soil original properties determined amount of nitrate and DOC reduction after biochar addition. Our result also indicated poor estimation of ammonium adsorption by biochar due to the liberation of ammonia. As a result, we strongly recommend that ammonia liberation should be considered during adsorption experiments and more studies in this field.

The majority of biochar studies use soils with only a narrow range of properties making generalizations about the effects of biochar on soils difficult. In this study, we aimed to identify soil properties that determine the performance of biochar produced at high temperature (700 °C) on soil pH, cation exchange capacity (CEC), and exchangeable base cation (Ca2+, K+, and Mg2+) content across a wide range of soil physicochemical properties. Ten distinct soils with varying physicochemical properties were incubated for 12 weeks with four rates of biochar application (0.5, 2, 4, and 8% w/w). Soil pH, CEC, and exchangeable base cations (Ca2+, K+, and Mg2+) were determined on the 7th and 84th day of incubation. Our results indicate that the highest biochar application rate (8%) was more effective at altering soil properties than lower biochar rates. Application of 8% biochar increased pH significantly in all incubated soils, with the increment ranging up to 1.17 pH unit. Biochar induced both an increment and a decline in soil CEC ranging up to 35.4 and 7.9%, respectively, at a biochar application rate of 8%. Similarly, biochar induced increments in exchangeable Ca2+ up to 38.6% and declines up to 11.4%, at an 8% biochar application rate. The increment in CEC and exchangeable Ca2+ content was found in soils with lower starting exchangeable Ca2+ contents than the biochar added, while decreases were observed in soils with higher exchangeable Ca2+ contents than the biochar. The original pH, CEC, exchangeable Ca2+, and texture of the soils represented the most crucial factors for determining the amount of change in soil pH, CEC, and exchangeable Ca2+ content. Our findings clearly demonstrate that application of a uniform biochar to a range of soils under equivalent environmental conditions induced two contradicting effects on soil properties including soil CEC and exchangeable Ca2+ content. Therefore, knowledge of both biochar and soil properties will substantially improve prediction of biochar application efficiency to improve soil properties. Among important soil properties, soil exchangeable Ca2+ content is the primary factor controlling the direction of biochar-induced change in soil CEC and exchangeable Ca2+ content. Generally, biochar can induce changes in soil pH, CEC, and exchangeable Ca2+, K+, and Mg2+ with the effectiveness and magnitude of change closely related to the soil’s original properties.

The purpose of the study was to understand the mechanisms of biochar-induced changes in the available content of aluminum (Al), cadmium (Cd), zinc (Zn), copper (Cu), and manganese (Mn) in a wide range of soils. Five soils from different regions of the Czech Republic were incubated for 12 weeks with four rates of biochar (0.5%, 2%, 4%, and 8% w/w). The available concentrations of Al, Cd, Zn, Cu, and Mn were determined on the 7th and 84th day of incubation. There was a significant decline in the available content of Al, Zn, Cu, Mn, and Cd except in the available content of Al in one soil, which is characterized by very low Al content, higher cation exchange capacity (CEC), and neutral pH = 7.0. The decline in the mobile contents of Al, Zn, Cu, Mn, and Cd was significant in all cases of 8% biochar rate. The decline in the content of Al, Zn, Cu, Mn, and Cd was mainly due to the increment in soil pH and increment in CEC, decline in dissolved organic carbon (DOC), and the release of exchangeable Ca2+ and K+ from biochar. The application of high amounts of biochar to soil could increase the available content of some metals like Al. On the other hand, biochar could efficiently reduce the mobility of Al, Zn, Cu, Mn, and Cd in soil, while the decline is mainly caused by biochar-induced changes in soil pH, CEC, DOC, and exchangeable Ca2+ and K+ content of treated soils.