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1. The acid catalyzed cyclization of citral

Author

B.C. Clark, C.C. Powell, and T. Radford

Subjects
chemistry.chemical_compound, Aqueous solution, chemistry, Acid catalyzed, Organic Chemistry, Drug Discovery, Organic chemistry, Citral, Biochemistry
Abstract

Fourteen compounds have been identified as products of the acid catalyzed cyclization of citral under mild aqueous acid conditions. Three major products of the reaction, 1,8-epoxy-p-menth-2-ene (11) and trans- and cis-p-menth-2-ene-1,8-diol (16 and 18) are reported here for the first time as products from citral. Possible mechanistic pathways leading to the products are discussed.

Published
1977

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