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1. Stereocomplexed PLA nanocomposites: From in situ polymerization to materials properties.

Author

Re, Giada Lo, Benali, Samira, Habibi, Youssef, Raquez, Jean-Marie, and Dubois, Philippe

Subjects
*POLYLACTIC acid, *POLYMERIC nanocomposites, *POLYMERIZATION, *STEREOISOMERS, *THERMAL properties of polymers, *MELTING
Abstract

Highlights: [•] Stereoisomers of PLLA and PDLA grafted directly at clay surface via metal-free ROP. [•] These nanohybrids were melt-processed with commercial PLA to obtain nanocomposite. [•] Grafting from approach enables to design full stereocomplex by solvent-free melting. [•] Grafting from and stereocomplexation improve rigidity and thermal properties of PLA. [•] Nanocomposites obtained show a significant improvement in oxygen-barrier properties. [ABSTRACT FROM AUTHOR]

Published
2014
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