Search

Tungsten is an important alloying component for the production of different materials. Its efficient extraction from different sustainable resources is necessary to meet the growing demand in the future. In this context, an attempt has been made to recover it from a goldmine overburden sample using the fungal bioleaching technique. The sample contains 0.023% of WO3 in the form of scheelite. The prospect of bioleaching for tungsten recovery from the sample was evaluated by varying pulp density from 1 to 7% (w/v). The leaching rate of tungsten decreased with the increase of pulp density. The maximum tungsten recovery of 86.8% (w/w) could be achieved at the condition of pulp density, 1% (w/v); pH, 6.8; temperature, 32 °C; speed, 120 rpm; contact time, 10 days. Growth of the fungal strain Aspergillus niger in terms of organic acids production was evaluated during the bioleaching experiment and found to be maximum at the pulp density of 1% (w/v). The leaching kinetics of tungsten followed the chemical control model. [ABSTRACT FROM AUTHOR]

Dumping of poor but metal containing industrial waste is associated with several environmental issues. Exposure of these wastes to the natural environment offers serious concerns for the mineral processing industries to utilize them for metal recovery and check environmental pollution. In the present study, a novel sequential bioreduction–bioleaching and bioreduction–chemical leaching route as a hybrid process is compared and discussed for the enhanced recovery of copper from an industrial concentrator plant ball milling unit rejected sample. A mixed consortium of metal reducing bacteria (DMRB) initially adapted to high Fe(III) concentrations was found to cause mineralogical/matrix alteration (possibly silicate weathering) including Fe(III) bioreduction in the sample and dissolute 29.73% copper during the first 35 days under facultative anaerobic conditions. Sequential leaching of the bioreduced waste sample (generated from the first step) using a mixed meso-acidophilic bacterial consortium predominantly Acidithiobacillus ferrooxidans showed additional 28.72% copper dissolution within 2 days using 1 gL − 1 Fe(II). On the other hand, a comparative chemical leaching of the same bioreduced sample using 0.5 M H 2 SO 4 yielded additional 32.17% copper within 4 days of leaching and indicated better performance than the bioleaching tests. [ABSTRACT FROM AUTHOR]

Dumping of low-grade chalcopyrite encompasses several environmental problems. Despite slow dissolution rate, meso-acidophilic bioleaching is preferred for the extraction of copper from such ores. In the present study, meso-acidophilic bioleaching of a low-grade chalcopyrite in the presence of an acid-processed waste newspaper (PWp) is discussed for the first time. The study illustrated a strong catalytic response of PWp with enhanced bio-recovery of copper from acid-conditioned chalcopyrite. A maximum of 99.13% copper recovery (0.36% Cu dissolution/day) was obtained in 6 days of bioleaching in the presence of 2 gL − 1 PWp in contrast to only 5.7% copper in its absence. FTIR analysis of bioleached residues revealed similar spectral patterns to the original acid-conditioned ore in the presence of PWp, thus indicating less development of passivation layer which was also confirmed through a complementary Raman characterization of the bioleached residues. Further, a reaction mechanism (chemistry) was proposed suggesting the possible role of PWp as the electron donor under oxygen limiting conditions which facilitated microbial reduction of Fe (III). The resulting biochemical changes provided an energy source for the bacteria, thus allowing free flow of electrons through the ore surface, thus contributing towards enhanced bioleaching of copper. [ABSTRACT FROM AUTHOR]