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Furan derivatives, such as 5-hydroxymethylfurfural (HMF) and furfural, obtained from renewable feedstocks are sustainable alternatives to petroleum-based building blocks for the manufacture of chemical products. This study shows for the first time the applicability of the catalytic fast pyrolysis (CFP) of glucose over tailored zeolites for the production of HMF and furfural. In particular, we demonstrate that Lewis-acid-containing faujasite zeolites attained by alkali metal-cation exchange exhibit combined yields to these platform molecules of 17 %. Despite the fact that further research is required on the process assessment at a larger scale and under more realistic conditions, CFP has potential for the production of biomass-derived commodity chemicals. [ABSTRACT FROM AUTHOR]

The industrial viability of heterogeneous catalysts for the gas-phase conversion of lactic acid to acrylic acid will strongly depend on their selectivity and durability. Here, we initially screened various aluminum-rich zeolites confirming that NaY is the most efficient catalyst for this reaction. This material was modified by sequential dealumination and alkaline treatment attaining a solid featuring a hierarchical distribution of micro- and mesopores, reduced Lewis acidity, and increased basicity owing to the presence of well-dispersed sodium ions interacting with external siloxy groups, as evidenced by in-depth characterization. These properties were crucial for determining higher selectivity (75 %) and minimizing the activity loss in a 6 h run. Remarkably, the catalyst gained in selectivity and stability upon reuse in consecutive cycles. This was ascribed to the depletion of the stronger basic sites and the clustering of sodium into oxidic particles upon the intermediate calcination. [ABSTRACT FROM AUTHOR]

The Cover shows how rENewable ‐ based processes challENge existing oil ‐ based routes for a more sustainable manufacture of consumer products. The establishmENt of alternative technologies is contingENt upon the idENtification of effective heterogENeous catalysts and suitable feedstocks. In their Full Paper, G.   M. Lari, B. Puértolas et   al. describe the design of a zeolite ‐ based catalyst for the gas ‐ phase transformation of lactic acid, a versatile platform easily obtained from glycerol or sugars, into acrylic acid, a commodity chemical used in paints, plastics, glues, and superabsorbENts. Simple and scalable acid and alkaline treatmENts ENable the introduction of basicity and mesoporosity and the reduction of Lewis acidity in a commercial aluminosilicate, gENerating a material that shows superior selectivity and remarkably ENhanced stability. More information can be found in the Full Paper by G.   M. Lari, B. Puértolas et   al. on page   1507 in Issue 8, 2016 (DOI: 10.1002/cctc.201600102). [ABSTRACT FROM AUTHOR]