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The Indochina biomass burning (BB) season in springtime has a substantial environmental impact on the surrounding areas in Asia. In this study, we evaluated the environmental impact of a major long-range BB transport event on 19 March 2018 (a flight of the High Altitude and Long Range Research Aircraft (HALO; https://www.halo-spp.de , last access: 14 February 2023) research aircraft, flight F0319) preceded by a minor event on 17 March 2018 (flight F0317). Aircraft data obtained during the campaign in Asia of the Effect of Megacities on the transport and transformation of pollutants on the Regional to Global scales (EMeRGe) were available between 12 March and 7 April 2018. In F0319, results of 1 min mean carbon monoxide (CO), ozone (O 3) , acetone (ACE), acetonitrile (ACN), organic aerosol (OA), and black carbon aerosol (BC) concentrations were up to 312.0, 79.0, 3.0, and 0.6 ppb and 6.4 and 2.5 µ g m -3 , respectively, during the flight, which passed through the BB plume transport layer (BPTL) between the elevation of 2000–4000 m over the East China Sea (ECS). During F0319, the CO, O 3 , ACE, ACN, OA, and BC maximum of the 1 min average concentrations were higher in the BPTL by 109.0, 8.0, 1.0, and 0.3 ppb and 3.0 and 1.3 µ g m -3 compared to flight F0317, respectively. Sulfate aerosol, rather than OA, showed the highest concentration at low altitudes (<1000 m) in both flights F0317 and F0319 resulting from the continental outflow in the ECS. The transport of BB aerosols from Indochina and its impacts on the downstream area were evaluated using a Weather Research Forecasting with Chemistry (WRF-Chem) model. The modeling results tended to overestimate the concentration of the species, with examples being CO (64 ppb), OA (0.3 µ g m -3) , BC (0.2 µ g m -3) , and O 3 (12.5 ppb) in the BPTL. Over the ECS, the simulated BB contribution demonstrated an increasing trend from the lowest values on 17 March 2018 to the highest values on 18 and 19 March 2018 for CO, fine particulate matter (PM 2.5) , OA, BC, hydroxyl radicals (OH), nitrogen oxides (NO x) , total reactive nitrogen (NO y) , and O 3 ; by contrast, the variation of J(O1D) decreased as the BB plume's contribution increased over the ECS. In the lower boundary layer (<1000 m), the BB plume's contribution to most species in the remote downstream areas was <20 %. However, at the BPTL, the contribution of the long-range transported BB plume was as high as 30 %–80 % for most of the species (NO y , NO x , PM 2.5 , BC, OH, O 3 , and CO) over southern China (SC), Taiwan, and the ECS. BB aerosols were identified as a potential source of cloud condensation nuclei, and the simulation results indicated that the transported BB plume had an effect on cloud water formation over SC and the ECS on 19 March 2018. The combination of BB aerosol enhancement with cloud water resulted in a reduction of incoming shortwave radiation at the surface in SC and the ECS by 5 %–7 % and 2 %–4 %, respectively, which potentially has significant regional climate implications. [ABSTRACT FROM AUTHOR]

Arsenic (As) has long been recognized as a toxic element of mainly anthropogenic origins, having adverse effects on human health. However, there is insufficient understanding regarding As released into atmosphere from biomass burning (BB). To this end, daily airborne As concentrations in total particulate matter (TSP) were determined at Mount Hehuan (24.16° N, 121.29° E, 3001ma.s.l.), Taiwan from September 2011 to September 2012. During the sampling period, As concentrations varied from 0.02 to 5.9 ngm-3 with a mean value of 0.5±.0 ngm-3. Significantly seasonal variations of As were found over the subtropical free troposphere, and higher As concentrations were observed in the southern (S) and southeastern (SE) Asian BB seasons (from January to May). Principal component analysis (PCA) results showed that BB activities seemed to be a major source of As during the S and SE Asian BB periods, which were very distinct from the major source of coal-fired power plant during the periods between July and December. Based on backward trajectory analyses and WRF-Chem model simulations, we found that the high As concentrations during the BB periods were attributed to the biomass burning activities over S Asia where groundwater, soil and crops are severely contaminated by arsenic. A strong correlation (r = 0:73 p < 0:05) between As and potassium ion (KC, a chemical tracer of BB activities) in S Asian BB events also supported this hypothesis. During the S Asian BB events, the high As = Pb ratios (> 0:2) were also observed, indicating that burning crops contaminated by lead arsenate might be a crucial candidate for high As concentrations at Mount Hehuan. Nevertheless, the net influence of S Asian BB activities on airborne As concentrations has been estimated by comparing the differences of As concentrations on BB and non-BB days. On average, the difference in As concentrations was 1.0 ngm-3, which accounted for 63% of the average As concentration on BB days. Moreover, a ratio of 1As=1CO (~ 0:00001) in the S Asian BB events was obtained. Using this value, arsenic emissions from S Asian BB activities were estimated to be 0.17 tons yr-1 , resulting in high airborne As concentrations over the subtropical free troposphere and impacting As cycles on a regional scale in the S and SE Asian BB seasons. [ABSTRACT FROM AUTHOR]

Biomass burning produces aerosols and air pollutants during springtime in Southeast Asia. At the Lulin Atmospheric Background Station (LABS) (elevation 2862 m) in central Taiwan, the concentrations of carbon monoxide (CO), ozone (O3) and particulate matter with a diameter less than 10 µm (PM10) were found to be 135-200 ppb, 40-56 ppb and 13-26 µg/m³, respectively, in the springtime (February-April) between 2006 and 2009, which are 2-3 times higher than those in other seasons. Simulation results indicate that higher concentrations during springtime are related to biomass-burning plumes transported from the Indochinese peninsula of Southeast Asia. The spatial distribution of high aerosol optical depth (AOD) was identified by satellite measurement and Aerosol Robotic Network (AERONET) ground observation, and could be reasonably captured by the WRF-Chem model during the study period of 15-18 March 2008. Simulated AOD reached as high as 0.8-1.2 in Indochina situated between 10-22°N and 95-107°E. According to the simulation results, 34% of the AOD was attributed to organic carbon over Indochina, while the contribution of black carbon to AOD was about 4%. During the study period, biomass-burning aerosols over Indochina have a net negative effect (-26.85 W·m-2) at ground surface, a positive effect (22.11 W·m-2) in the atmosphere and a negative forcing (-4.74 W·m-2) at the top of atmosphere. Under the influence of biomass-burning aerosol plume transported by strong wind, there is a NE-SW zone stretching from southern China to Taiwan with reduction in shortwave radiation of about 20 W·m-2 at ground surface. Such significant reduction in radiation attributed to biomass-burning aerosols and their impact on the regional climate in East Asia merit attention. [ABSTRACT FROM AUTHOR]

Abstract: Surface ozone (O3) and carbon monoxide (CO) mixing ratios were measured at Mei-Feng (24.05 °N, 120.10 °E, 2269 m above sea level) remote mountain site between March 2009 and September 2010 to investigate the impact of regional pollution on O3 and CO. The results showed that the maximum values of both O3 and CO were found in the springtime. Backward trajectory analysis, combined with MODIS fire spots suggested that the enhanced O3 and CO in springtime could be attributed to biomass burning (BB) activities over Southeast (SE) Asia. Thirteen BB events were identified by backward trajectory analysis, MODIS fires, NCEP weather data sets and CO concentrations. Good correlation between O3 and CO was found during the BB plumes. Using the linear regression, the slope (ΔO3/ΔCO) was calculated to be 0.18 ± 0.08 (mean ± 1σ). This value was in agreement with that of 0.2 observed over the west Pacific region during the TRACE-P campaign, but was higher than those (0.11–0.14) of Canadian and Siberian fires. Moreover, significant enhanced O3 productivity was also found in aged BB plumes and that mixed with urban emissions from SE coastal China. To assess the net influence of SE Asian BB, the air masses from SE Asia and SE China were divided in two groups: those that passed over the fire regions (PF) and those that did not (NP). The result showed that the maximum differences between PF and NP were estimated in March with 8 ppb for O3 and 45 ppb for CO, respectively, accounting for 23% of both CO and O3 levels at Mei-Feng. Although uncertainties existed in the estimations, the significant discrepancies of O3 and CO in the two air groups suggested the air pollutants emitted by SE Asian BB could be transported and influence the air quality over subtropical Taiwan in springtime. [Copyright &y& Elsevier]

The Tibetan Plateau is one of the highest regions in the world, exerting profound influence on the large-scale atmospheric circulation of Asia and the global climate. Here we report ambient concentrations of black carbon (BC), aerosol mass (PM and PM) and associated carbonaceous species and water-soluble inorganic ions from a remote mountain site in the southeastern part of the Tibetan Plateau during spring, in order to characterize the major sources contributing to the ambient aerosol in the background atmosphere of Southeast Asia. Significant build-up of aerosol and BC concentrations was observed during a dry period, accompanied by the occurrence of fires and transport of pollution from the nearby regions of Southeast Asia and the northern part of the Indian Peninsula. The concentrations of BC, PM and PM mass reached maximum hourly values of 1470 ng m, 107 and 117 μg m, respectively. Organic carbon (OC), elemental carbon (EC) and sulfate were the predominant aerosol components. OC showed strong correlations with EC ( R= 0.93 for PM and 0.74 for PM) and non-sea-salt potassium, especially in fine aerosol ( R= 0.95). In addition, the relative change rates of K against OC reached characteristically high values, highlighting the important contributions of biomass-burning smoke. [ABSTRACT FROM AUTHOR]

To analyze the physicochemical mechanisms affecting the variation in fine suspended particulate matter (PM 2.5) concentrations in Taichung City, the largest city in central Taiwan (the second largest city in Taiwan), during a high-pollution event from November 3 to 6, 2021, we applied the sulfur tracking method (STM) and integrated source apportionment method (ISAM) of the WRF/CMAQ model to simulate the impacts of various emission sources. The sources of pollution in Taichung City are very similar, which shows that the impacts of point, line, and area sources should not be neglected in addition to the boundary conditions. SO 4 2− is mainly generated from point emissions and the production of H 2 O 2 , Fe, Mn, and O 3. NO 3 − is also mainly generated from point sources in Taichung City, with HNO 3 being the main source at noon and ANO 3 at other times of the day. NH 4 + is mainly generated from area sources in Taichung City. OM is more complex, mainly originating from line sources in Taichung City and other sources, such as point/area emissions in Taichung City and other emissions from Changhua County. The most important mechanism is low-volatility/semivolatile oxidized combustion of OC at noon, followed by low-volatility/semivolatile POA, which is produced in the morning or evening. EC mainly originates from line sources in Taichung City and Changhua County. In other nearby counties, EC is dominated by local emission sources. In addition, when the concentration of PM 2.5 is high, the Neutralization Ratio (NR) is high and PM 2.5 is relatively neutral or slightly alkaline. On the contrary, when the concentration of PM 2.5 is low, the NR is lower than 1 and the aerosol is acidic. Besides, this study used positive matrix factorization (PMF), which indicates that the PM 2.5 at the UAPRS originated from eight kinds of pollution, namely, windblown dust, oil cracking, iron and steel industry, sea salt, transport, Cl− containing exhaust, biomass burning, fossil combustion containing abundant SO 4 2− and the heavy oil refining and coal combustion industry. The direction of the source of pollution can be traced by a conditional bivariate probability function (CBPF). Overall, fossil fuel combustion, mainly involving sulfate, is the largest source of pollution, with the heavy oil refining and coal combustion industry contributing less, and the remaining factors contribute relatively evenly. [Display omitted] • WRF/CMAQ modeling applies the ISAM to simulate the impacts of various emission sources. • WRF/CMAQ modeling applies the STM to provide information on the sulfur budget. • SO 4 2−, NO 3 −, OM, and EC are analyzed in central Taiwan. • PMF at the UAPRS reveals eight kinds of pollutants. • The CBPF is applied to explain the locations of potential sources for the UAPRS. [ABSTRACT FROM AUTHOR]

In the winter and spring times, the cold continental airs not only often outflow to Taiwan, but also bring air pollutants and dusts. Moreover, springtime happens to be the biomass burning season in Indochina. Under favor weather conditions, the products of biomass burning pollutants could be transported easily to Taiwan and even East Asia. Due to the unique geographic location of Taiwan, that allows us to receive more than just one source in spring. Actually, the complex interactions of these air pollutants and aerosols features in the boundary layer and aloft have resulted in complex characteristics of air pollutants and aerosols distributions in the lower troposphere over Taiwan and East Asia. The impacts are also essential and complex. The project "Effect of Megacities on the transport and transformation of pollutants on the Regional and Global scales (EMeRGe)" aims to improve our knowledge and prediction of the transport and transformation patterns of European and Asian megacities pollutant outflows. In EMeRGe Asia, the composition of the plumes of pollution entering and leaving Asia measured by the new High Altitude and LOng Range (HALO) aircraft research platform. The HALO aircraft performing optimized transects and vertical profiling in Asia during 12 March and 7 April in 2018. To design the measurement of aircraft flight paths and elevations, a high resolution, 9 km, numerical prediction by Weather Research Forecast (WRF) and WRF-Chem models were joined and performed during the campaigns. The EMeRGe Asia has successfully finished more than 10 missions during study period. Model performances and preliminary results will discuss in this meeting. Overall, this series of studies significantly fill the gap of our understanding on air pollutants transformation and transport to Taiwan and East Asia, and show the potential directions of future studies. [ABSTRACT FROM AUTHOR]

Abstract: Intensive measurements of aerosol (PM10) and associated water-soluble ionic and carbonaceous species were conducted in Guangzhou, a mega city of China, during summer 2006. Elevated levels of most chemical species were observed especially at nighttime during two episodes, characterized by dramatic build-up of the biomass burning tracers levoglucosan and non-sea-salt potassium, when the prevailing wind direction had changed due to two approaching tropical cyclones. High-resolution air mass back trajectories based on the MM5 model revealed that air masses with high concentrations of levoglucosan (43–473 ng m−3) and non-sea-salt potassium (0.83–3.2 μg m−3) had passed over rural regions of the Pearl River Delta and Guangdong Province, where agricultural activities and field burning of crop residues are common practices. The relative contributions of biomass burning smoke to organic carbon in PM10 were estimated from levoglucosan data to be on average 7.0 and 14% at daytime and nighttime, respectively, with maxima of 9.7 and 32% during the episodic transport events, indicating that biomass and biofuel burning activities in the rural parts of the Pearl River Delta and neighboring regions could have a significant impact on ambient urban aerosol levels. [Copyright &y& Elsevier]