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This study aimed to evaluate the bleaching efficacy, pH, and temperature of 35% hydrogen peroxide (HP) gel used alone or associated with violet LED.Sixty bovine crowns were sectioned (5 × 5 × 2mm). After staining with black tea, the specimens were randomized into four groups (n = 10) according to the bleaching protocol: HP35R: 3 × 15 min 35% HP; HP35: 1 × 45 min 35% HP; HP35VR: 3 × 8min 35% HP + Violet LED; HP35V: 1 × 24 min + Violet LED. Two bleaching sessions were performed for all the groups. Color change was evaluated before, 24h after each session, 7 days and 15 days after the last session. The variables ∆EHP35VR and HP35V the most noticeable color change(p 0.05). The final values of pH were lower than the initial ones, but with no difference between the groups (p 0.05). Groups HP35VR and HP35V showed an increase in temperature in relation to HP35R (p 0.05).Violet LED improved the bleaching efficacy of 35% HP in a time-saving manner without negatively affecting the pH and temperature of 35% HP. The renewal of HP did not influence the outcomes.