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The purification and densification of wastewater play an important role in water recycling, especially if the materials used in water recycling are other types of recycled waste. Therefore, considering this view in this study, the biosynthesis of silver-decorated chromium oxide nanoparticles utilizing a wasted Allium sativum (garlic) peel extract is investigated. The aqueous extract of garlic peel (GPE) was treated with silver nitrate, chromium nitrate, and a mixture of silver nitrate and chromium nitrate to synthesize silver nanoparticles (Ag-garlic), chromium oxide nanoparticles (Cr2O3-garlic), and silver-decorated chromium oxide nanoparticles (Ag@Cr2O3-garlic), respectively. The synthesized nanoparticles were elucidated via thermal gravimetric analysis (TGA), infrared spectra (FT-IR), absorption spectra (UV-Vis), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). Antimicrobial activity studies were conducted against waterborne germs, bacterial strains (Bacillus subtilis, Enterococcus faecium, Escherichia coli, and Pseudomonas aeruginosa), and fungal strains (Alternaria porri, Aspergillus flavus, Aspergillus niger, Fuserium oxysporum, and Trichoderma longibrachiatum) and showed significant levels of antimicrobial activity. The results revealed that Ag@Cr2O3 significantly improved antimicrobial activity due to their synergistic effect. The photocatalytic activity of nanoparticles was assessed using Rhodamine B dye (5 ppm) under solar irradiation. Cr2O3-garlic exhibited the best activity as a photocatalyst among the studied nanoparticles, with 97.5% degradation efficiency under optimal conditions. [ABSTRACT FROM AUTHOR]

The nano-metal complexes are found to be more impregnable than their parent drugs, therefore this study was aimed to synthesize Ag-nanocomplex of paracetamol (Para) by novel biosynthesis method. Paracetamol Ag-nanocomplex with the formula [Ag(Para)2(NO3)2] has been characterized and synthesized on the basis of elemental analysis, thermal (TGA), conductivity, 1H, 13C NMR and electronic spectral studies. Verticillium wilt, caused by Verticillium dahliae is considered one of the most serious diseases in olives. The use of Ag-nanocomplex as antifungal with different concentration (25, 50, 100 and 150 mg/ml) led to significant reductions of forming colonies of Verticillium wilt pathogenic fungi, with efficiencies reaching to 79.4, 82.9 and 81.8%, respectively at (100 mg/ml) against "V. dahliae, Fusarium acuminatum and Alternaria brassicae" LD50 was also evaluated, while no changes in physical activity were detected, so this research opens outlooks for more study of fungal biogenic nanoparticles, indicating their use for controlling an agricultural pests [ABSTRACT FROM AUTHOR]