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Novel blue-emitting KBaGdSi2O7:Eu2+ phosphors were designed and synthesized through solid-state reaction method. The structural properties, concentration, and temperature-dependent luminescence behaviors of these phosphors were investigated in detail in this paper. Studies revealed that KBaGdSi2O7:Eu2+ phosphors have an intense absorption in the broad wavelength ranging from 250 to 400 nm that is suitable for the commercial near-UV LED, and give out intense blue light peaked at 475 nm with a full-width half-maximum of 75 nm. The crystallographic information of KBaGdSi2O7 phase is revealed from XRD pattern by Rietveld refinement. Band gap is derived to be 3.93 eV through diffuse reflection spectra through Kubelka Munk function. The concentration quenching mechanism is identified as the dipole–dipole interaction. Moreover, the thermal quenching experiment was also conducted and the activation energy is calculated as 0.3069 eV, which indicates this novel KBaGdSi2O7:Eu2+ phosphor has good thermal stability. These properties exhibit its potential commercial application for near-UV white-light LEDs (w-LEDs). [ABSTRACT FROM AUTHOR]

Phosphor layer are essential in the application of phosphor-converted white light emitting diodes (pc-WLEDs). However, the conventional structure of red–green–blue (RGB) phosphor layers can cause severe re-absorption of blue light, resulting in low luminous efficiency and colour rendering index (CRI). In this paper, we fabricated a new WLEDs phosphor layer, which consisted of patterned RGB phosphor pixel arrays in a planar configuration, by the stencil printing technique. Optical simulation based on Monte-Carlo theory has been applied to assist designing the optimal pattern of the phosphor pixel arrays. By tuning the layout of the pixel arrays and the size of phosphor pixels, we achieved uniform output white light with high luminous intensity of 1.47 × 109 cd and CRI of 95.6, which are superior compared with the intensity of 1.11 × 109 cd and CRI of 93.5 obtained from WLEDs with conventional dispensing phosphor layer. Our newly-designed phosphor pixel-array layer possesses great potential for applications in advanced lighting and display devices with vast implications for industrial improvement in these research areas. [ABSTRACT FROM AUTHOR]