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Capping water body sediments with a thin layer of sand is an effective technique to decrease nutrient concentrations in the water column and accelerate ecological restoration of eutrophic water bodies. However, long-term effects of thin-layer sand capping in shallow lakes are reported less often. Using clean fine sand and geotextile mats as capping materials for sediments collected from Wuhan Donghu Lake in China, we designed a 290-day tank experiment with 3 cm of sand capping at four percentages of sediment coverage from 25 to 100% and a control (no capping). We monitored total nitrogen (TN), total phosphorus (TP), nitrate (NO3−), ammonia (NH4+), and soluble reactive phosphorus (SRP) in the overlying water every 7 days. Mean TN and NO3− concentrations were significantly the lowest (P < 0.05) at 50% coverage. Further increase in coverage kept them slightly fluctuating. NH4+ concentration was significantly lowest (P < 0.05) at 75% coverage. The relation between coverage and mean TP and SRP concentrations indicated that 75% coverage significantly decreased (P < 0.05) them, and increasing coverage to 100% decreased them even more. The fluxes of TN and TP estimated between sediments and overlying water showed that the thin fine-sand layer significantly increased the function of sediments as a sink of TN from overlying water and the potential of a sand layer to block release of TP from sediments (P < 0.05). Our results suggested that if thin-layer sand capping were applied to Wuhan Donghu Lake, more than 50% coverage is required to decrease nutrients in the lake's water. [ABSTRACT FROM AUTHOR]

• Procedures to determine available acid consumption capacity (AACC) were developed. • Variation magnitude of AACC depended significantly on labile acid-soluble minerals. • Sediment AACC in the Yangtze River Basin had high regional variability. • Sediment AACC six water bodies were divided into Ca-Mg type and Fe-Al type. Acid-base reactivity is a fundamental property of sediments and is responsible for sediments' multiple roles in aquatic ecosystems. However, little information currently exists about the composition, magnitude, and change of the available acid consumption capacity (AACC) of sediments. To optimize reaction conditions, we developed operational procedures to determine AACC using base titration to recover surplus acid in suspensions. We characterized the sediment AACC of Dianchi Lake (DL), Daduhe River (DR), Tuojiang River (TR), Honghu Lake (HL), Wuhan Donghu Lake (DhL), and Taihu Lake (TL) in the Yangtze River Basin, China. The procedure demonstrated that reacting 40 mL 0.1 M HCl with fresh sediments equivalent to 1.0 g dry weight for 4 h and recovering surplus acid in the suspension by NaOH titration to an endpoint pH of 3.0 could determine sediment AACC. Sediment AACC in the Yangtze River Basin had high regional variability. The mean magnitude of AACC among sites was ranked DL > DR > DhL > TR > HL > TL, which is extremely similar to their geographical location from the upper to lower reaches of the Yangtze River Basin. Qualitative results from acid titration curves showed that more components contributed to AACC in DL, DR, TR, and DhL sediments than to those in HL and TL sediments. The correlation between AACC and the total amount of multivalent cations released indicated that AACC depended significantly on labile acid-soluble minerals that contain multivalent cations (Fe3+, Fe2+, Ca2+, Al3+, Mg2+, and Mn2+) (p < 0.01). Based on the contribution percentages of multivalent cations to AACC, sediment AACC of six water bodies were divided into two types: Ca-Mg dominated (DL, DR, and TR) and Fe-Al dominated (HL, DhL, and TL). We suggest that sediment AACC complexing with pH can contribute to a better description of the acid-base characteristics of sediments. [Display omitted] [ABSTRACT FROM AUTHOR]

• LISST can well applied to monitor the mean cell size and colony size of cyanoHABs. • Cell density of algae can be estimated reliably based on total and mean cell biovolume. • The protocol for in-situ tracking migration of cyanoHABs was validated in the tank. • The 3D section views of cyanoHABs in Dianchi lake were well obtained by LISST-HAB. Cyanobacterial harmful algal blooms (cyanoHABs) are becoming increasingly common in aquatic ecosystems worldwide. However, their heterogeneous distributions make it difficult to accurately estimate the total algae biomass and forecast the occurrence of surface cyanoHABs by using traditional monitoring methods. Although various optical instruments and remote sensing methods have been employed to monitor the dynamics of cyanoHABs at the water surface (i.e., bloom area, chlorophyll a), there is no effective in-situ methodology to monitor the dynamic change of cell density and integrated biovolume of algae throughout the water column. In this study, we propose a quantitative protocol for simultaneously measurements of multiple indicators (i.e., biovolume concentration, size distribution, cell density, and column-integrated biovolume) of cyanoHABs in water bodies by using the laser in-situ scattering and transmissometry (LISST) instrument. The accuracy of measurements of the biovolume and colony size of algae was evaluated and exceeded 95% when the water bloom was dominated by cyanobacteria. Furthermore, the cell density of cyanobacteria was well estimated based on total biovolume and mean cell volume measured by the instrument. Therefore, this methodology has the potential to be used for broader applications, not only to monitor the spatial and temporal distribution of algal biovolume concentration but also monitor the vertical distribution of cell density, biomass and their relationship with size distribution patterns. This provides new technical means for the monitoring and analysis of algae migration and early warning of the formation of cyanoHABs in lakes and reservoirs. [Display omitted] [ABSTRACT FROM AUTHOR]

Terrestrial silicon (Si) from biogeochemically weathered rocks and soils into oceans must pass through several water bodies, resulting in some Si immobilized. Hence, the knowledge on Si distribution characteristics in different water bodies at a basin scale is helpful to understand Si immobilization. A total of 65 surface sediments and corresponding overlying water samples were sampled from six water bodies (Dianchi Lake, DL; Dadu River, DR; Tuojiang River, TR; Honghu Lake, HL; Donghu Lake, DhL; Taihu Lake, TL) in the Yangtze River Basin of China, total dissolved Si (TDSi) in overlying water and exchangeable Si (Ex-Si), active non-biogenic Si (NBSi), and total acid dissolved Si (TADSi) in sediments were analyzed. Water chemical parameters (pH, EC, and TDP) and sediment components (LOI, TN, TP, and TADFe) showed that the water environment characteristics of six water bodies differed. TDSi differed among regions and between lakes and rivers, significantly higher in water bodies in the upper reaches and rivers than the middle or lower reaches and lakes (p < 0.05), respectively. Ex-Si in sediments in the upper reaches was significantly higher than in the middle or lower reaches (p < 0.05), except for DhL, whose Ex-Si was the highest. Mean TADSi and active NBSi were significantly higher in lakes than rivers (p < 0.05). Oxidation of sediments significantly increased TDSi in overlying water and active NBSi in sediments (p < 0.01). Si forms in six water bodies significantly depended on components of the sediments (e.g. active Ca2+, Mg2+, Fe, and Al3+) and water chemical parameters (p < 0.05). Our results suggest that immobilization of Si in water bodies in the Yangtze River Basin depends on the types of water bodies and sediments, lakes and Fe–Al dominated sediments have a high potential to immobilize Si, but anthropogenic interference should not be ignored. • TDSi in overlying water in upper reaches was higher than middle or lower reaches. • Exchangeable Si in upper reaches sediments was higher than middle or lower reaches. • TADSi and active non-biogenic Si in sediments in lake were higher than river. • Ca–Mg-dominated sediments had lower capacity to immobilize Si than Fe–Al-dominated. [ABSTRACT FROM AUTHOR]