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Your search keyword '"Hakamata, Tomohiro"' showing total 1 results
Start Over Author "Hakamata, Tomohiro" Topic boranes
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1. Enantiomeric Resolution of Intramolecular Amine-Borane Complex with a Chiral Boron Center.

Author

Toyota, Shinji, Hakamata, Tomohiro, Nitta, Naoya, and Ito, Fumiko

Subjects
ENANTIOMERS, OPTICAL isomers, CHIRALITY, CHIRAL drugs, BORANES
Abstract

The enantiomers of [2-(dimethylaminomethyl)phenyl]-(pentafluoropropionyloxy)phenylborane were successfully resolved by chiral HPLC as a new type of intramolecular amine-borane complex with a chiral center at the tetrahedral boron atom. The X-ray structure, the barrier to racemization, and the chiroptical properties are reported. [ABSTRACT FROM AUTHOR]

Published
2004
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