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The spectra of brown dwarfs are key to exploring the chemistry and physics that take place in their atmospheres. Late-T dwarf spectra are particularly diagnostic, due to their relatively cloud-free atmospheres and deep molecular bands. With the use of powerful atmospheric retrieval tools applied to the spectra of these objects, direct constraints on molecular/atomic abundances, gravity, and vertical thermal profiles can be obtained, enabling a broad exploration of the chemical/physical mechanisms operating in their atmospheres. We present a uniform retrieval analysis on low-resolution Infrared Telescope Facility SpeX near-infrared spectra for a sample of 50 T dwarfs, including new observations as part of a recent volume-limited survey. This analysis more than quadruples the sample of T dwarfs with retrieved temperature profiles and abundances (H2O, CH4, NH3, K, and subsequent C/O and metallicities). We are generally able to constrain the effective temperatures to within 50 K, the volume mixing ratios for major species to within 0.25 dex, the atmospheric metallicities [M/H] to within 0.2, and the C/O ratios to within 0.2. We compare our retrieved constraints on the thermal structures, chemistry, and gravities of these objects with predictions from self-consistent radiative-convective equilibrium models and find, in general, though with substantial scatter, consistency with solar composition chemistry and the thermal profiles of the neighboring stellar FGK population. Objects with notable discrepancies between the two modeling techniques and potential mechanisms for their differences, be they related to the modeling approach or physically motivated, are discussed more thoroughly in the text. [ABSTRACT FROM AUTHOR]

Ultra-cool brown dwarfs offer a unique window into understanding substellar atmospheric physics and chemistry. Their strong molecular absorption bands at infrared wavelengths, Jupiter-like radii, cool temperatures, and lack of complicating stellar irradiation make them ideal test beds for understanding Jovian-like atmospheres. Here, we report the findings of a uniform atmospheric retrieval analysis on a set of 14 Y- and T-type dwarfs observed with the Hubble Space Telescope Wide Field Camera 3 instrument. From our retrieval analysis, we find the temperature structures to be largely consistent with radiative-convective equilibrium in most objects. We also determine the abundances of water, methane, and ammonia, as well as upper limits on the alkali metals sodium and potassium. The constraints on water and methane are consistent with predictions from chemical equilibrium models, while those of ammonia may be affected by vertical disequilibrium mixing, consistent with previous works. Our key result stems from the constraints on the alkali metal abundances where we find their continued depletion with decreasing effective temperature, consistent with the trend identified in a previous retrieval analysis on a sample of slightly warmer late T-dwarfs in Line et al. (2017). These constraints show that the previously observed Y–J color trend across the T/Y transition is most likely due to the depletion of these metals, in accordance with predictions from equilibrium condensate rainout chemistry. Finally, we simulate future James Webb Space Telescope observations of ultra-cool dwarfs and find that the Near Infrared Spectrometer (NIRSpec) PRISM offers the best chance at developing high-precision constraints on fundamental atmospheric characteristics. [ABSTRACT FROM AUTHOR]