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This work introduces an external loop to a bubble column and presents enhanced gas exchange in the heterogeneous flow regime. Gas exchange experiments under the same amount of gas input were carried out with varying gas velocity to understand the difference of bubble characteristic between the bubble column (BCR) and the bubble column with an external loop (BCR-EL). The observation of rise and descending velocity of bubbles in the BCR-EL showed that the fraction of bubbles passing the downcomer continuously increases with the incremental superficial gas velocity. A gas molecule in the liquid phase is desorbed by another gas molecule, and this gas exchange was assumed to be a phenomenon that a reactant in the liquid phase is converted to a product. To test the validity of the assumed gas exchange as a reaction in the experiments with the BCR-EL, a modeling study was performed using Fisher-Tropsch synthesis. It prevailed that the syngas conversion was higher in the BCR at the homogeneous flow regime, while the BCR-EL at the heterogeneous flow regime (above 0.08 m/s) had higher syngas conversion than the BCR due to higher gas recycle to the downcomer.

Industrial bubble columns mainly operate in a heterogeneous flow regime and identifying transition from homogeneous to heterogeneous flow is important. This work addresses the determination of flow regimes with gas–liquid systems in a bubble column. Various parameters of gas holdup, volumetric mass transfer coefficient, drift flux, and pressure standard deviations were investigated to precisely determine the superficial gas velocity at the transition regime. For a column aspect ratio (H/D: static liquid height to column diameter ratio) of 2.5 to 5, the transitional superficial gas velocity generally became higher with lower liquid height. However, the reverse trend was observed with a low density gas system due to the difference in force balance acting around the bubble. The weak body force and drag force in a lower axial position interrupted the mass transfer process. The experimental results showed similar ranges of the transitional superficial gas velocity regardless of the choice of parameter for detecting it. Because there is no precise correlation about transition regime properties, we proposed new correlations to predict both transition regime superficial gas velocity and gas holdup by taking the intersection of the two regimes. The correlations precisely captured the transition regime properties within 15% deviations even in gas–liquid systems that are not tested in this work.

This work addressed the gas–liquid (G/L) mass transfer limitation coming from the increasing liquid height and the circumvention of the limitation by introducing a sieve tray in a bubble column. Either monoethylene glycol (MEG) solution or n-hexane was adopted as a liquid phase and argon was used as a gas phase in the bubble column. The gas holdup and the mass transfer coefficient became lowered by the static liquid height increase due to the increase of bubble size. The loss of mass transfer was overcome by installing a sieve tray inside the column. The two sieve trays with different hole sizes were employed and both bubble diameter and standard deviation of pressure were investigated to understand the effect of the sieve tray on the mass transfer. With a smaller size hole sieve (1 mm), the mass transfer deteriorated in both liquid systems (MEG and n-hexane) due to the formation of gas cap below the sieve while with a larger hole sieve (3 mm), it was enhanced because of the reduction of bubble diameters without any gas cap formation. However, it was found that the sieve tray effect was weakened when the flow regime changes from homogeneous to heterogeneous.