1. Tunable nonlinear optical responses and carrier dynamics of two-dimensional antimonene nanosheets
- Author
-
Tao-Tao Dong, Zi-Zhen Chen, Shah Fahad, Qi-Wei Song, Ze-Qi Zhang, Qiang Wang, Hao-Ran Wu, Xin-Ping Zhai, Li-Chuan Chen, Rui-Tong Liu, Xian Fei, Hao-Li Zhang, Xiang-Yang Li, Yong Peng, Zhe-Ji Wang, Chun-Lin Sun, and Lei Zhang
- Subjects
Materials science ,business.industry ,Exciton ,Relaxation (NMR) ,Saturable absorption ,02 engineering and technology ,Nanosecond ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Exfoliation joint ,0104 chemical sciences ,Ultrafast laser spectroscopy ,Optoelectronics ,General Materials Science ,0210 nano-technology ,business ,Ultrashort pulse ,Nanosheet - Abstract
Sb nanosheets, also known as antimonene, have received ever-growing consideration as a promising new type of two-dimensional (2D) material due to their many attractive properties. However, how their nonlinear optical (NLO) properties are affected by their nanosheet structure and measurement conditions remains unclear. Herein, we report a successful size-selective production method for Sb nanosheets, which is based on a combination of lithium ion intercalation, solvent exfoliation and size selection centrifugation. This high-yield and size-selective preparation method enables fundamental investigation on the relation of the intrinsic optical properties of Sb nanosheets. Nanosecond Z-scan measurements revealed a unique size-dependent broadband NLO response. When the average size is reduced from 3 micrometers to 50 nanometers, the Sb nanosheets exhibit a clear transition from saturable absorption to reversed saturable absorption. Ultrafast transient absorption spectroscopic investigation indicated that exciton cooling is significantly faster in a small nanosheet than in large ones, revealing that the different exciton relaxation dynamic plays key roles in the distinct size-tunable nonlinear optical response. This work paves new ways towards the mass production and practical application of antimonene.
- Published
- 2020
- Full Text
- View/download PDF