1. Effect of multi-armed triphenylamine-based hole transporting materials for high performance perovskite solar cells
- Author
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Jin Young Kim, Tae Sub Jung, Kyungwon Kwak, Sungmin Park, Min Jae Ko, Cheol Hong Cheon, Sang Hyuk Im, Hae Jung Son, Jae Hoon Yun, and Jin Hyuck Heo
- Subjects
Materials science ,business.industry ,Photovoltaic system ,Perovskite solar cell ,02 engineering and technology ,General Chemistry ,Conductivity ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Triphenylamine ,01 natural sciences ,0104 chemical sciences ,law.invention ,chemistry.chemical_compound ,Solar cell efficiency ,chemistry ,law ,Solar cell ,Optoelectronics ,0210 nano-technology ,business ,Perovskite (structure) - Abstract
A series of hole-transporting materials (HTMs) based on [2,2]paracyclophane and triphenyl-amine (TPA) was synthesized. We studied the effect of the chemical structure of the HTM on the photovoltaic performance of perovskite solar cells by varying the number of TPA charge transporting components in the HTM. Tetra-TPA, in which four TPAs are incorporated into the [2,2]paracyclophane core, exhibited better hole transport properties than di-TPA and tri-TPA, which contain two and three TPAs, respectively. In particular, incorporation of the TPA group with a multi-armed structure effectively enhanced the conductivity of the HTM layer in the out-of-plane direction in the solar cell device. Due to the improved charge transport and appropriate molecular energy levels of tetra-TPA, the perovskite solar cell based on the tetra-TPA HTM achieved higher Jsc and FF values than the devices based on di-TPA and tri-TPA HTMs, with a high solar cell efficiency (17.9%).
- Published
- 2016
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