1. Exploring the Ruddlesden–Popper layered organic–inorganic hybrid semiconducting perovskite for visible-blind ultraviolet photodetection
- Author
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Yuyin Wang, Guoming Lin, Bin Su, Cheng-Yang Yue, Huiru Lou, Xiao-Wu Lei, and Shouxin Wang
- Subjects
Materials science ,business.industry ,Band gap ,Photoconductivity ,Photodetector ,General Chemistry ,Photodetection ,Photoelectric effect ,Condensed Matter Physics ,medicine.disease_cause ,medicine ,Optoelectronics ,General Materials Science ,business ,Ultraviolet ,Perovskite (structure) ,Visible spectrum - Abstract
Compared to the three-dimensional (3D) perovskite materials, the Ruddlesden−Popper (R-P) type two-dimensional (2D) organic-inorganic metal halide perovskites have indicated specific unique physical properties that include moisture-stable behaviours, exciton effects, and quantum confinements, making it a solid and potential candidate for optoelectronic applications. Nonetheless, while specific candidates have exhibited visible-blind ultraviolet (UV) photoelectric response, most R-P type 2D materials have been known to be photosensitive to visible light. In this study, an R-P type 2D lead bromide hybrid perovskite (C8H11FN)2PbBr4, (1, where C8H10FN is 4-Fluorophenethylamine) has been analyzed, which contained both inorganic frameworks and organic cations. Moreover, 1 exhibits a relatively wide optical bandgap of 3.30 eV, corresponding to that of the Br-based 2D R-P perovskites expected to exhibit selective photoresponse for the UV light. It is pertinent to note that the photodetectors based on the crystal of 1 exhibit spectral selective photoresponse for UV light with high detectivity up to ∼ 1.6×1011 Jones. Moreover, the trap density of 1 is estimated to be 1.34×1011 cm-3; the trap density of 1 was almost equal to that obtained in the high-quality 3D CH3NH3PbBr3 single crystals. Besides, under external environment, 1 illustrated excellent stability. The figures of merit for its photoconductivity make 1 a potential candidate for the visible-blind UV photodetection. This discovery opens up new vistas for the further development of optoelectric devices based on 2D R-P organic-inorganic hybrid perovskites.
- Published
- 2022
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