1. Syntheses, Structures and Optoelectronic Properties of Spiroconjugated Cyclic Ketones
- Author
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Jennifer Wilbuer, Birgit Esser, and Gregor Schnakenburg
- Subjects
010405 organic chemistry ,business.industry ,Hydrogen bond ,Chemistry ,Organic Chemistry ,Solid-state ,010402 general chemistry ,Electrochemistry ,01 natural sciences ,0104 chemical sciences ,Yield (chemistry) ,Optoelectronics ,Physical and Theoretical Chemistry ,business - Abstract
Synthetic investigations towards spiroconjugated ketones and derivatives thereof are presented. These studies led to the development of a short procedure for the synthesis of spiroconjugated tetraketone 1 in two steps with 10 % overall yield and the first-time synthesis of spirocyclic trindone 2. The optoelectronic properties of these compounds based on spectroscopic and electrochemical measurements in combination with DFT calculations as well as their molecular structures in the solid state are presented and discussed.
- Published
- 2016
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